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Characterization of polyacrylamide gels as an elastic model for food gels

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Abstract

Serving as an elastic model system for food gels, characteristics of polyacrylamide (PAAm) gels were investigated using small amplitude and large deformation rheological tests. The PAAm gels displayed elastic or viscoelastic behavior depending on network crosslink density. For elastic PAAm gels, the rheological properties obeyed the theory of rubber elasticity; whereas for viscoelastic PAAm gels, shear modulus depended on temperature. The elastic PAAm gel fracture parameters did not change with deformation rate (0.2–5.5 s−1), indicating insignificant viscous flow during deformation. Fracture stress was correlated with gel monomer concentration, whereas the fracture strain remained constant regardless of the monomer concentration. In addition, the stress was linearly proportioned with strain up to fracture, indicating that PAAm gels did not experience finite network chain extensibility during large deformation. Consequently, the fracture of PAAm gels did not result from the extensional limitation of network chains, nor did gel fracture result from the nonlinear force–distance relationship between polymer connections. Purportedly, the fracture of PAAm gels was caused by external force overcoming the gel cohesive forces, and low strength of PAAm gels compared to rubbers caused fracture prior to experiencing nonlinear stress-strain deformation.

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Authors and Affiliations

  1. Department of Food Science, North Carolina State University, 130 Withers, 101 Lampe Drive, 7624, Raleigh, NC, 27695-7624, USA

    Junhua Zhang, Christopher R. Daubert & E. Allen Foegeding

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  1. Junhua Zhang
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  2. Christopher R. Daubert
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  3. E. Allen Foegeding
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Correspondence to Christopher R. Daubert.

Additional information

Paper No. FSR04-20 of the Journal Series of the North Carolina Agricultural Research Service, Raleigh, NC 27695-7643. The use of trade names does not imply endorsement by the North Carolina Agricultural Research Service of products named, nor criticisms of similar ones not mentioned.

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Zhang, J., Daubert, C.R. & Foegeding, E.A. Characterization of polyacrylamide gels as an elastic model for food gels. Rheol Acta 44, 622–630 (2005). https://doi.org/10.1007/s00397-005-0444-5

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  • DOI: https://doi.org/10.1007/s00397-005-0444-5

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