Abstract
The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA–montmorillonite leads to phase separation between polystyrene and the surfactant matrix.
Similar content being viewed by others
Author information
Authors and Affiliations
Additional information
Received: 14 April 2000/Accepted: 19 June 2000
Rights and permissions
About this article
Cite this article
Jung, M., German, A. & Fischer, H. Polymerisation in supported bilayers. Colloid Polym Sci 278, 1114–1118 (2000). https://doi.org/10.1007/s003960000378
Issue Date:
DOI: https://doi.org/10.1007/s003960000378