Abstract
Anisotropic polystyrene/poly(styrene-co-divinylbenzene) (PS/P(S-DVB)) protrusion particles with various morphologies such as eyeball-like, snowman-like, and raspberry-like were synthesized using a modified seeded polymerization method by dynamically controlling and stabilizing the phase separation. The effects of swelling agent, crosslinker, and monomer concentrations on the particle morphologies were studied. Using the PS/P(S-DVB) protrusion particles as templates, anisotropic silica (SiO2) hollow microspheres were fabricated facilely. The obtained anisotropic silica hollow spheres had a potential application in rapid waste removal and detoxification extraction with a very simple procedure.
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Acknowledgments
The authors acknowledge the National Key Basic Research Development Program of China (973 special preliminary study plan, 2012CB722705), the Natural Science Foundation of China (21344005, 21375069), the Fok Ying Tong Education Foundation (131045), the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry (20111568), and the Science and Technology Program of Qingdao (1314159jch) for financial support.
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Yu, B., Yuan, H., Wang, D. et al. Fabrication of anisotropic silica hollow microspheres using polymeric protrusion particles as templates. Colloid Polym Sci 292, 2361–2367 (2014). https://doi.org/10.1007/s00396-014-3269-x
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DOI: https://doi.org/10.1007/s00396-014-3269-x