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Electromagnetic properties and microwave absorption enhancement of Ba0.85RE0.15Co2Fe16O27-polyaniline composites: RE = Gd, Tb, Ho

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Abstract

The Gd-, Tb-, and Ho-doped W-type hexagonal ferrite Ba0.85RE0.15Co2Fe16O27 was fabricated by a facile route of low-temperature sol–gel self-propagating combustion. Furthermore, a combination of dielectric loss phase polyaniline and magnetic loss phase Ba0.85RE0.15Co2Fe16O27 as the microwave absorber in a core-shell architecture has been synthesized. The effect of different lanthanide ions Gd, Tb, and Ho on their microstructure, static magnetic properties, electromagnetic properties, and microwave reflection loss have been systematically studied. Our results show that the Ho-doped ferrite has the low microstructure parameters (a, c, and V) and high saturation magnetization (Ms) attributed to its ionic radius and magnetic moment. Moreover, it was found that the Ho-doped composite exhibited excellent microwave absorbing property with a minimum reflection loss (RL) of about −15.1 dB at 9.4 GHz. The reflection loss of composite increases up to almost triple upon the combination of polyaniline and doped ferrite. Such lightweight and highly effective absorbers via combining the organic and inorganic phase into a core-shell architecture are highly desirable for microwave absorber in various applications.

The synthesis and properties of the PANI/REBF composites

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Acknowledgments

This present work was financially supported by the key technology and equipment of efficient utilization of oil shale resources, No: OSR-5, and the National Science and Technology Major Projects, No: 2008ZX05018-005.

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130026, China

    Fengying Guo, Ruiqing Li & Shucai Gan

  2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun, 130022, China

    Jijing Xu

  3. Teaching Center of Basic Courses, Jilin University, Changchun, 130062, China

    Lianchun Zou

Authors
  1. Fengying Guo
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  2. Ruiqing Li
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  3. Jijing Xu
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  4. Lianchun Zou
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  5. Shucai Gan
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Correspondence to Lianchun Zou or Shucai Gan.

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Guo, F., Li, R., Xu, J. et al. Electromagnetic properties and microwave absorption enhancement of Ba0.85RE0.15Co2Fe16O27-polyaniline composites: RE = Gd, Tb, Ho. Colloid Polym Sci 292, 2173–2183 (2014). https://doi.org/10.1007/s00396-014-3234-8

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  • DOI: https://doi.org/10.1007/s00396-014-3234-8

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