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Interactions and influence of α-cyclodextrin on the aggregation and interfacial properties of mixtures of nonionic and zwitterionic surfactants

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Abstract

The interactions of α-cyclodextrin (α-CD) with the nonionic surfactant decanoyl-N-methyl-glucamide (Mega-10) and the zwitterionic surfactant dimethyldodecylammoniopropanesulfonate (DPS) in their mixed system have been studied using interfacial tension, fluorescence, and nuclear magnetic resonance measurements. From the plots of interfacial tension vs. log of total surfactant concentration, we have obtained values of the surface excess of surfactant, the critical micellar concentration (cmc), the standard free energy of micelle formation, and association constant of surfactant/α-CD inclusion complexes (assuming a 1:1 stoichiometry). A comparison of the K a values obtained for the interaction between α-CD and DPS and Mega-10, respectively, shows that DPS interacts stronger with α-CD than Mega-10. The experimental mixed cmc was analyzed by the pseudophase separation model and regular solution theory for the evaluation of ideality or nonideality of the mixed micelle formation. The interaction parameters in the mixed micelle and the micelle composition at different mole fractions of DPS were also computed. The fluorescence anisotropy (r) values of rhodamine B decreases with the increase of α-CD concentrations.

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References

  1. Larsen KL (2002) J Incl Phenom Mol Recognit Chem 43:1

    Article  CAS  Google Scholar 

  2. Alami SA, Alami E, Eastoe J, Cosgrove T (2002) J Colloid Interface Sci 246:191

    Article  Google Scholar 

  3. Jiang BY, Du J, Cheng S, Pan J, Zeng X, Liu Y, Shunzo Y, Sueshi Y (2003) J Dispersion Sci Tech 24:63

    Article  CAS  Google Scholar 

  4. Harada H, Li J, Kamach M (1992) Nature 356:325

    Article  CAS  Google Scholar 

  5. Topchieva I, Karezin K (1999) J Colloid Interface Sci 213:29

    Article  CAS  Google Scholar 

  6. Cabrer PR, Parrilla EA, Meijide F, Seijas JA, Nunez ER, Tato JV (1999) Langmuir 15:5489

    Article  Google Scholar 

  7. Connors KA (1987) Binding constant. Wiley, New York, p 261 Chapter 8

    Google Scholar 

  8. Otzen DE, Oliveberg M (2001) J Mol Biol 313:479–483

    Article  CAS  Google Scholar 

  9. Junquera E, Tardajos G, Aicart E (1993) Langmuir 9:1213

    Article  CAS  Google Scholar 

  10. Okubo T, Kitano H, Ise N (1976) J Phys Chem 80:2661

    Article  CAS  Google Scholar 

  11. Okubo T, Maeda Y, Kitano H (1989) J Phys Chem 93:3721

    Article  CAS  Google Scholar 

  12. Du X, Chen X, Lu W, Hou J (2004) J Colloid Interface Sci 274, 645 and references therein

  13. Lu R, Hao J, Wang H, Tong L (1997) J Colloid Interface Sci 192:37 and references therein

    Google Scholar 

  14. Satake I, Ikenoue T, Takeshita T (1985) Bull Chem Soc Jpn 58:2746

    Article  CAS  Google Scholar 

  15. Sakaki KJ, Christian SD, Tucker EE (1990) J Colloid Interface Sci 134:412

    Article  Google Scholar 

  16. Funasaki N, Ishikawa S, Neya S (2004) J Phys Chem B 108:9563

    Google Scholar 

  17. Hashimoto S, Thomas JK (1985) J Am Chem Soc 107:4655

    Article  CAS  Google Scholar 

  18. Nelson SG, Warner IM (1989) Carbohydr Res 192:305

    Article  CAS  Google Scholar 

  19. Sehgal P, Sharma M, Wimmer R, Larsen KL, Otzen DE (2006) Colloid Polym Sci 284:916

    Article  CAS  Google Scholar 

  20. Sehgal P, Sharma M, Larsen KL, Wimmer R, Otzen DE, Doe H (2008) J Dispers Sci Technol 29:128

    Article  CAS  Google Scholar 

  21. Sehgal P, Sharma M, Larsen KL, Wimmer R, Doe H, Otzen DE J Dispers Sci Technol (2009, in press)

  22. Holland PM, Rubingh DN (1992) Mixed surfactant systems. ACS symposium series, Washington, DC

    Book  Google Scholar 

  23. Lange RK (1999) Surfactants a practical handbook. Hanser Publishers, Munich

    Google Scholar 

  24. Hierrezuelo JM, Aguiar J, Ruiz CC (2006) J. Colloid Interface Sci 294:449

    Article  CAS  Google Scholar 

  25. Hierrezuelo JM, Aguiar J, Ruiz CC (2004) Langmuir 20:10419

    Article  CAS  Google Scholar 

  26. Ribera R, Velazquez MM (1999) Langmuir 15:6686

    Article  CAS  Google Scholar 

  27. Rosen MJ (1989) Surfactants and interfacial phenomenon, 2nd edn. Wiley, New York

    Google Scholar 

  28. Ray GB, Chakraborty I, Ghosh S, Moulik SP (2007) J Colloid Interface Sci 307:543

    Article  CAS  Google Scholar 

  29. Yunus WMW, Tayæor J, Bloor DM, Hall DG, Jones EW (1992) J Phys Chem 96:8979

    Article  Google Scholar 

  30. Palepu R, Reinsborough VC (1988) Can J Chem 66:325

    Article  CAS  Google Scholar 

  31. Clint JH (1975) J Chem Soc Faraday Tran 71:1327

    Article  CAS  Google Scholar 

  32. Rubingh DN, Mittal KL (1979) Solution chemistry of surfactants, vol. 1. Plenum, New York, p 337

    Google Scholar 

  33. Jobe D, Verral RE (1990) Langmuir 6:1750

    Article  CAS  Google Scholar 

  34. Lakowicz JR (2006) In principles of fluorescence spectroscopy, 3rd edn. Springer, New York, p 353

    Google Scholar 

  35. DelaCruz JL, Blanchard GJ (2003) J Phys Chem B 107:7102

    Article  CAS  Google Scholar 

Download references

Acknowledgements

P.S. is thankful to Japan Society for the Promotion of Science (JSPS) for a postdoctoral award. We thank Dr. T. Nagasaki, Department of Bioapplied Chemistry, Osaka City University, Osaka, Japan for the fluorescence anisotropy measurements. R.W. acknowledges an OCU fellowship. We wish to thank Prof. Kinoshita for access to NMR equipment. D.E.O. was supported by the Danish Research Foundation (inSPIN) and the Villum Kann Rasmussen Foundation (BioNET).

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto Cho, Sumiyoshi-ku, Osaka, 558-8585, Japan

    Pankaj Sehgal, Tami Mizuki & Hidekazu Doe

  2. Department of Biotechnology, Chemistry and Environmental Engineering, Aalborg University, Sohngaardsholmsvej 49/57, 9000, Aalborg, Denmark

    Reinhard Wimmer & Kim Lambertsen Larsen

  3. Interdisciplinary Nanoscience Center (iNANO), Department of Molecular Biology, University of Aarhus, Gustav Wieds Vej 10 C, 8000, Aarhus C, Denmark

    Daniel E. Otzen

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  1. Pankaj Sehgal
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  2. Tami Mizuki
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  3. Hidekazu Doe
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Correspondence to Pankaj Sehgal.

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Sehgal, P., Mizuki, T., Doe, H. et al. Interactions and influence of α-cyclodextrin on the aggregation and interfacial properties of mixtures of nonionic and zwitterionic surfactants. Colloid Polym Sci 287, 1243–1252 (2009). https://doi.org/10.1007/s00396-009-2086-0

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  • DOI: https://doi.org/10.1007/s00396-009-2086-0

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