Abstract
In this study, a new method was developed to prepare temperature-sensitive poly(N-isopropylacrylamide) microgels by free radical precipitation polymerization using siloxane coupling agent as the new crosslinker. Ammonium persulfate acted as the initiator for the radical copolymerization as well as the catalyst for the hydrolysis/condensation of the siloxane groups. The particle diameter and polydispersity of the microgels were measured by photon correlation spectroscopy and the results display that the microgels are monodisperse. The microgels exhibit temperature sensitivity and the phase transition temperature is approximately 31 °C. Furthermore, the diameter of the microgels changes upon heating and cooling processes. These were observed to be reversible. The novel crosslinking method described herein is the condensation of siloxane groups, which is totally different from the traditional double-vinyl crosslinkers. This innovative approach offers an alternative path to prepare functional core–shell particles and inorganic/organic hybrid materials.
References
Heskins M, Guillet JE (1968) J Macromol Sci Chem A2:1441
Schild HG (1992) Prog Polym Sci 12:163
Zhang JT, Huang SW, Gao FZ, Zhuo RX (2005) Colloid Polym Sci 283:461
Zhang JT, Jandt KD (2008) Macromol Rapid Commun 29:593
Pelton R (2000) Adv Colloid Interface Sci 85:1
Saunders BR, Vincent B (1999) Adv Colloid Interface Sci 80:1
Ge H, Ding Y, Ma C, Zhang G (2006) J Phys Chem B 110:20635
Pelton RH, Chibante P (1986) Colloids Surf 20:247
Serpe MJ, Yarmey KA, Nolan CM, Lyon LA (2005) Biomacromolecules 6:408
Hellweg T, Dewhurst CD, Bruckner E, Kratz K, Eimer W (2000) Colloid Polym Sci 278:972
Huang G, Hu Z (2007) Macromolecules 40:3749
Dingenouts N, Norhausen C, Ballauff M (1998) Macromolecules 31:8912
Hellweg T, Dewhurst CD, Eimer W, Kratz K (2004) Langmuir 20:4330
Lu Y, Mei Y, Ballauff M, Drechsler M (2006) J Phys Chem B 110:3930
Nolan CM, Reyes CD, Debord JD, Garcia AJ, Lyon LA (2005) Biomacromolecules 6:2032
Vo CD, Kuckling D, Adler HJP, Schohoff M (2002) Colloid Polym Sci 280:400
Kuckling D, Vo CD, Adler HJP, Volkel A, Colfen H (2006) Macromolecules 39:1585
Wang YW, Yen CT, Chen WC (2005) Polymer 46:6959
Zhang JT, Huang SW, Zhuo RX (2005) Colloid Polym Sci 284:209
Kim WS, Kim MG, Ahn JH, Bae BS, Park CB (2007) Langmuir 23:4732
Wu X, Pelton RH, Hamielec AE, Woods DR, McPhee W (1994) Colloid Polym Sci 272:467
Mrkic J, Saunders BR (2000) J Colloid Interface Sci 222:75
Hu ZB, Xia XH (2004) Adv Mater 16:305
Keerl M, Richtering W (2007) Colloid Polym Sci 285:471
Crowther HM, Vincent B (1998) Colloid Polym Sci 276:46
Duracher D, Elaissari A, Pichot C (1999) Colloid Polym Sci 277:905
Acknowledgements
J.T. gratefully acknowledges the financial support in form of an Alexander-von-Humboldt Fellowship from the Alexander-von-Humboldt Foundation, Bonn, Germany. The authors also acknowledge the partial financial support of the BMBF for this work within the project “Innovations- und Gründerlabor für neue Werkstoffe (Biomaterialien) und Verfahren (IGWV) an der Friedrich-Schiller-Universität Jena” Förderkennzeichen: 03GL0026. J.T.Z. and K.D.J. are grateful to Karin Jandt for proofreading the manuscript.
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Zhang, JT., Liu, XL., Fahr, A. et al. A new strategy to prepare temperature-sensitive poly(N-isopropylacrylamide) microgels. Colloid Polym Sci 286, 1209–1213 (2008). https://doi.org/10.1007/s00396-008-1890-2
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DOI: https://doi.org/10.1007/s00396-008-1890-2