Abstract
Colloidal crystallization kinetics is studied in the shear flow of a suspension of colloidal silica spheres (110 nm in diameter), using a continuously-circulating type of stopped flow cell system. The crystallization rate from a suspension containing a small amount of nuclei and/or single crystals is high compared with that from a suspension containing no nuclei and/or single crystals. Crystal growth takes place at shear rates smaller than 3.4 s−1 and at sphere concentrations higher than a volume fraction of 0.004.
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Acknowledgements
The Frontier Research Project of the Japan Space Utilization Promotion Center is acknowledged for producing the measuring instruments. The Ministry of Education, Culture, Sports, Science and Technology, Japan is thanked for grants-in-aid for Scientific Research in Priority Area (A) (11167241). Drs. M. Komatsu and M. Hirai of Catalyst & Chemical Ind. Co. (Tokyo) are thanked deeply for providing the sample suspension of the colloidal silica spheres.
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Tsuchida, A., Takyo, E., Taguchi, K. et al. Kinetic analyses of colloidal crystallization in shear flow. Colloid Polym Sci 282, 1105–1110 (2004). https://doi.org/10.1007/s00396-003-1043-6
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DOI: https://doi.org/10.1007/s00396-003-1043-6