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Measurement of number densities in supersonic flows using a method based on laser-induced acetone fluorescence

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Abstract

A method that is based on laser-induced fluorescence (LIF) and that involves the use of acetone as a seed can be utilized for measurement of supersonic flows with high temporal and spatial resolutions. In the present study, the feasibility of using this method to measure the number density in supersonic flows at temperatures lower than the atmospheric temperature is investigated. An experiment in which low-temperature conditions are created by supersonic isentropic flows in a convergent–divergent nozzle is carried out. LIF is realized by exciting acetone with the fourth harmonic of a Nd:YAG laser, and the LIF signal is detected by a CCD camera with an image intensifier. In order to theoretically determine the LIF characteristics, a multistep decay model that can be used for temperatures of 300–900 K is extended so that it can be used in the low-temperature regime. The constant included in the model is redetermined by fitting the model to the present experimental data. The LIF calculated by using this extended model is found to agree very well with the experimental data. The model also indicates that the number density measured by the LIF method in the temperature range 170–290 K is insensitive to temperature.

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References

  • Anderson JD (1995) Computational fluid dynamic. McGraw-Hill, New York, pp 301–303

    Google Scholar 

  • Breuer GM, Lee EKC (1971) Fluorescence decay times of cyclic ketones, acetone, and butanal in the gas phase. J Phys Chem 75:989–990

    Article  Google Scholar 

  • Bryant RA, Donbar JM, Driscoll JF (2000) Acetone laser induced fluorescence for low pressure/low temperature flow visualization. Exp Fluids 28:471–476

    Article  Google Scholar 

  • Failor BH, Chantrenne S, Coleman PL, Levine JS, Song Y, Sze HM (2003) Proof-of-principle laser-induced fluorescence measurements of gas distributions from supersonic nozzles. Rev Sci Inst 74:1070–1076

    Article  Google Scholar 

  • Gierczak K, Burkholder JB, Bauerle S, Ravishankara AR (1998) Photochemistry of acetone under tropospheric conditions. Chem Phys 231:229–244

    Article  Google Scholar 

  • Grossmann F, Monkhouse PB, Ridder M, Sick V, Wolfrum J (1996) Temperature and pressure dependences of the laser-induced fluorescence of gas-phase acetone and 3-pentanone. Appl Phys B 62:249–253

    Article  Google Scholar 

  • Hansen DA, Lee EKC (1975) Radiative and nonradiative transitions in the first excited singlet state of symmetric methyl-substituted acetones. J Chem Phys 62:183–189

    Article  Google Scholar 

  • Hynes AJ, Kenyon EA, Pounds AJ, Wine PH (1992) Temperature dependent absorption cross-sections for acetone and n-butanone—implications for atmospheric lifetimes. Spectrochimica Acta 48:1235–1242

    Article  Google Scholar 

  • Koch JD, Hanson RK, Koban W, Schulz C (2004) Rayleigh-calibrated fluorescence quantum yield measurements of acetone and 3-pentanone. Appl Opt 43:5901–5910

    Article  Google Scholar 

  • Kychakoff G, Howe RD, Hanson RK (1984) Quantitative flow visualization technique for measurements in combustion gases. Appl Opt 23:704–712

    Article  Google Scholar 

  • Lozano A, Yip B, Hanson RK (1992) Acetone: a tracer for concentration measurements in gaseous flows by planar laser-induced fluorescence. Exp Fluids 13:369–376

    Article  Google Scholar 

  • Lozano A, Smith SH, Mungal MG, Hanson RK (1994) Concentration measurements in a transverse jet by planar laser-induced fluorescence of acetone. AIAA J 32:218–221

    Article  Google Scholar 

  • McMillin BK, Lee MP, Hanson RK (1992) Planar laser-induced fluorescence imaging of shock-tube flows with vibrational nonequilibrium. AIAA J 30:436–443

    Article  Google Scholar 

  • Ossler F, Aldén M (1997) Measurements of picosecond laser induced fluorescence from gas phase 3-pentanone and acetone: implications to combustion diagnostics. Appl Phys B 64:493–502

    Article  Google Scholar 

  • Roe PL (1981) Approximate Riemann solvers, parameter vectors, and difference schemes. J Comput Phys 43:357–372

    Article  MathSciNet  MATH  Google Scholar 

  • Rossmann T, Mungal MG, Hanson RK (2001) Acetone PLIF and schlieren imaging of high compressibility mixing layers. AIAA Paper 2001-0290, 39th Aerospace Sciences Meeting, Reno, NV

  • Rossmann T, Mungal MG, Hanson RK (2002) Evolution and growth of large-scale structures high compressible mixing layers. J Turbulence 3 Article No. 9

  • Shimanouchi T (1972) Tables of molecular vibrational frequencies, consolidated volume I. NSRDS-NBS 39

  • Shortridge RG, Rusbult CF, Lee EKC (1971) Fluorescence excitation study of cyclobutanone, cyclopentanone, and cyclohexanone in the gas phase. J Am Chem Soci 93:1863–1867

    Article  Google Scholar 

  • Thurber MC (1999) Acetone laser-induced fluorescence for temperature and multiparameter imaging in gaseous flows. Ph.D. Thesis Stanford University, TSD-120

  • Thurber MC, Hanson RK (1999) Pressure and composition dependences of acetone laser-induced fluorescence with excitation at 248, 266, and 308 nm. Appl Phys B 69:229–240

    Article  Google Scholar 

  • Thurber MC, Grisch F, Kirby BJ, Votsmeier M, Hanson RK (1998) Measurements and modeling of acetone laser-induced fluorescence with implications temperature imaging diagnostics. Appl Opt 37:4963–4978

    Article  Google Scholar 

  • Troe J (1977) Theory of thermal unimolecular reactions at low-pressure. 2. Strong collision rate constants—applications. J Chem Phys 66:4758–4775

    Article  Google Scholar 

  • Willcox DC (1988) Reassessment of the scale determining equation for advanced turbulence models. AIAA J 26:1299–1310

    Article  MathSciNet  Google Scholar 

  • Willcox DC (1992) Dilatation-dissipation corrections for advanced turbulence models. AIAA J 30:2639–2646

    Article  Google Scholar 

  • Yamamoto S, Daiguji H (1993) Higher-order-accurate upwind schemes for solving the compressible Euler and Navier-Stokes equations. Comput Fluids 22:259–270

    Article  MathSciNet  MATH  Google Scholar 

  • Yuen LS, Peters JE, Lucht RP (1997) Pressure dependence of laser-induced fluorescence from acetone. Appl Opt 36:3271–3277

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful to T. Masuda, K. Imamura, S. Mizuta, and Y. Ando for their assistance in experiments.

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Correspondence to Taro Handa.

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Handa, T., Masuda, M., Kashitani, M. et al. Measurement of number densities in supersonic flows using a method based on laser-induced acetone fluorescence. Exp Fluids 50, 1685–1694 (2011). https://doi.org/10.1007/s00348-010-1029-3

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  • DOI: https://doi.org/10.1007/s00348-010-1029-3

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