Abstract.
Polarization-resolved femtosecond experiments are shown to yield valuable insight into transition-state dynamics associated with ultra-fast photodissociation reactions of triatomic species in liquid solution. After the fundamental act of bond fission is completed, such experiments reveal rotational dynamics of the fragments, which can be used to extract information regarding fragment rotational excitation in the asymptotic limit of the reaction.
Similar content being viewed by others
Author information
Authors and Affiliations
Additional information
Received: 4 October 1999 / Published online: 30 June 2000
Rights and permissions
About this article
Cite this article
Bürsing, H., Lindner, J., Hess, S. et al. Real-time probing of vectorial properties of ultra-fast photodissociations in liquids . Appl Phys B 71, 411–417 (2000). https://doi.org/10.1007/s003400000344
Published:
Issue Date:
DOI: https://doi.org/10.1007/s003400000344