Skip to main content
Log in

Eu3+ Doped CaWO4—A Potential Red Long Afterglow Phosphor

  • Published:
Applied Physics B Aims and scope Submit manuscript

Abstract

In this study, a series of Eu3+ doped CaWO4 phosphors were synthesized by the solid-state reaction method. Red long afterglow was observed after samples were excited with 254 nm. The main emission peaks were ascribed to the 5D07F J (J=0, 1, 2, 3, 4) transitions of Eu3+, and the duration of the optimal sample could last nearly 40 min in the dark seen with naked eyes. The effect of the doping concentration of Eu3+ and alkali metal charge compensators (Li, Na, K) on the luminescent properties of the products were investigated in detail. The proposed mechanism of this afterglow property is also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Y. Kojima, T. Toyama, J. Alloys Compd. 475, 524 (2009)

    Article  Google Scholar 

  2. C. Shi, Y. Fu, B. Liu, G. Zhang, Y. Chen, Z. Qi, X. Luo, J. Lumin. 122, 11 (2007)

    Article  Google Scholar 

  3. N. Suriamurthy, B.S. Panigrahi, J. Lumin. 128, 1809 (2008)

    Article  Google Scholar 

  4. V. Chernov, R. Melendrez, M. Pedroza-Montero, W.M. Yen, M. Barboza-Flores, Radiat. Meas. 43, 241 (2008)

    Article  Google Scholar 

  5. X. Zhang, J. Zhang, X. Zhang, L. Chen, S. Lu, X.J. Wang, J. Lumin. 122, 958 (2007)

    Article  Google Scholar 

  6. B. Grobelna, B. Lipowska, A.M. Klonkowski, J. Alloys Compd. 419, 191 (2006)

    Article  Google Scholar 

  7. M.V. Nazarov, B.S. Tsukerblat, E.-J. Popovici, D.Y. Jeon, Phys. Lett. A 330, 291 (2004)

    Article  ADS  Google Scholar 

  8. J. Liao, H. You, B. Qiu, H.-R. Wen, R. Hong, W. You, Z. Xie, Curr. Appl. Phys. 11, 503 (2011)

    Article  ADS  Google Scholar 

  9. S. Shi, J. Gao, J. Zhou, Opt. Mater. 30, 1616 (2008)

    Article  ADS  Google Scholar 

  10. G.S. Ofelt, J. Chem. Phys. 38, 2171 (1963)

    Article  ADS  Google Scholar 

  11. L.G. DeShazer, G.H. Dieke, J. Chem. Phys. 38, 2190 (1963)

    Article  ADS  Google Scholar 

  12. V.B. Mikhailik, H. Kraus, D. Wahl, Phys. Rev. B 69, 205110 (2004)

    Article  ADS  Google Scholar 

  13. C. Fu, Y. Hu, Y. Wang, H. Wu, X. Wang, J. Alloys Compd. 502, 423 (2010)

    Article  Google Scholar 

  14. Y.-j. Chen, F.-b. Cao, Y.-w. Tian, L.-j. Xiao, L.-k. Li, Physica B 405, 435 (2010)

    Article  ADS  Google Scholar 

  15. O. Chukova, S. Nedilko, V. Scherbatskyi, J. Lumin. 130, 1805 (2010)

    Article  Google Scholar 

  16. Y.L. Huang, W.L. Zhu, X.Q. Feng, Z.Y. Man, J. Solid State Chem. 17, 188 (2003)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21071034).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y. Hu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kang, F., Hu, Y., Chen, L. et al. Eu3+ Doped CaWO4—A Potential Red Long Afterglow Phosphor. Appl. Phys. B 107, 833–837 (2012). https://doi.org/10.1007/s00340-012-4957-1

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00340-012-4957-1

Keywords

Navigation