Eu3+/Tb3+-co-doped CaWO4 phosphors were synthesized by a simple green co-precipitation process. The structure of the samples was investigated by X-ray diffraction. The photoluminescence spectra and fluorescence decay lifetimes of the samples were measured to investigate the luminescence properties. We analyzed the energy transfer process between Eu3+- and Tb3+-doped CaWO4. As the Tb3+ to Eu3+ energy transfer process was confirmed, Eu3+- and Tb3+-co-doped CaWO4 phosphors showed a color-tunable emission from green to red under a 365-nm UV lamp.
Similar content being viewed by others
References
Song, H. You, and Y. Huang, Inorg. Chem., 49, No. 24, Article ID 11499 (2010).
R. Maouche, S. Belaid, and B. Benmerad, Inorg. Chem., 60, No. 6, Article ID 3707 (2021).
R. L. Tranquilin, L. X. Lovisa, and C. Almeida, J. Phys. Chem. C, 123, Article ID 18536 (2019).
N. Guo, Y. H. Zheng, and G. Jia, J. Phys. Chem. C, 116, No. 1, Article ID 1329 (2011).
H. X. Jiang and S. C. Lü, Mater. Res. Bull., 135, Article ID 111123 (2020).
M. Laguna, N. O. Núñez, and F. J. Garcia, Eur. J. Inorg. Chem., 44, Article ID 5158 (2017).
Y. H. Zheng, Y. J. Huang, M. Yang, N. Guo, and H. Qiao, J. Lumin., 132, Article ID 362 (2012).
G. George, N. Shrivastava, and T. L. Moore, Opt. Mater., 126, Article ID 112130 (2022).
Q. Bai, Z. Wang, and P. Li, New. J. Chem., 39, No. 11, Article ID 8933 (2015).
Y. J. Liu, G. X. Zhang, J. B. Huang, X. M. Tao, G. H. Li, and G. M. Cai, Inorg. Chem., 60, Article ID 2279 (2021).
S. P. Culver and R. L. Brutchey, Dalton Trans., 45, Article ID 18069 (2016).
M. V. Nazarov, D. Y. Jeon, J. H. Kang, E. J. Popovici, L. E. Muresan, M. V. Zamoryanskaya, and B. S. Tsukerblat, Solid State Commun., 131, No. 5, Article ID 307 (2004).
Z. Piskuła, J. Czajka, K. Staninski, and S. Lis, J. Rare Earths, 32, No. 3, Article ID 221 (2014).
P. Kaur, A. Khanna, M. N. Singh, and A. K. Sinha, J. Alloys Compd., 834, Article ID 154804 (2014).
Y. Huang, H. You, and G. Jia, J. Phys. Chem. C, 114, No. 42, Article ID 18051 (2010).
J. R. Lakowicz, Principles of Fluorescence Spectroscopy, 3rd ed., Springer, New York (2006).
K. Li, R. van Deun, Dyes Pigments, 155, 258–264 (2018).
G. E. Malashkevich, G. I. Semkova, A. P. Stupak, et al., Phys. Solid State, 46, No. 8, 1425–1431 (2004).
Author information
Authors and Affiliations
Corresponding author
Additional information
Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 90, No. 6, p. 967, November–December, 2023.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zhang, L.H., Zhang, C.Y., Zhou, Y.B. et al. Energy Transfer and Colorful Emission of Eu3+- and Tb3+-Co-Doped CaWO4 Phosphors. J Appl Spectrosc 90, 1346–1351 (2024). https://doi.org/10.1007/s10812-024-01672-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-024-01672-5