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Influence of Mn substitution on structural, electrical, and magnetic properties of Li0.5Fe2.5-xO4

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Abstract

The influence of Mn inclusion on the structural, electrical, and magnetic parameters of Li0.5Fe2.5O4 wad analyzed. To procure nanoparticles of all the samples, a simple sol–gel self-combustion method was employed. In-depth, refinement of structural patterns reflects the ordered spinel phase (P4332) starts to demolish, and mixed-phase formation takes place with the replacement of Fe with Mn ions. FTIR gives similar findings, i.e., change of space group from P4332 to mixed phase with P4332 and Fd-3 m as the major characteristic absorptions and its shoulder bands start to smear out with the inclusion of Mn. FE-SEM images reflect that morphological tuning occurs through clustered nanoparticles’ agglomeration. The declining of electrical parameters dielectric constant, and loss tangent, indicates that electron hopping gets deterred through the inclusion of Mn. DC resistivity and activation energy are enhanced with the inclusion of Mn. The magnetic parameters also decline with Mn inclusion in the lithium ferrite lattice.

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Acknowledgements

This work was supported by the Korea Institute for Advancement of Technology (KIAT) grant funded by the Korea Government (Ministry of Trade, Industry, and Energy-MOTIE) (P0012770) and (N000OOOO).

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Author notes

  1. Swati D. Patil and Sagar M. Mane have contributed equally to this work.

Authors and Affiliations

  1. Department of Physics, Pratapsinh Mohite-Patil Mahavidyalaya, Karmala, Dist-Solapur, Maharashtra, India

    Swati D. Patil

  2. Department of Fiber System Engineering, Yeungnam University, Gyeongsan, Gyeongbuk, 38541, Republic of Korea

    Sagar M. Mane & Jaewoong Lee

  3. Independent Researcher, Nagpur, Maharashtra, 440008, India

    Nishant T. Tayade

  4. Department of Physics, Shrimant Babasaheb Deshmukh Mahavidyala, Atpadi, Dist-Sangli, Maharashtra, 415301, India

    Uttam E. Mote

  5. Department of Physics, Dr. Ganpatrao Deshmukh Mahavidyalaya, Sangola, Dist-Solapur, Maharashtra, 413307, India

    Shankar S. Dhasade

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  1. Swati D. Patil
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Contributions

SDP: Conceptualization, experimental, data creation and analysis, investigation, writing—original draft. SMM: Data creation and analysis, investigation, resources, writing—original draft, revision, and editing. NTT: Data curation, analysis, software, writing—original draft. UEM: Formal analysis, resources, visualization. JL: Formal analysis, supervision, validation, visualization, project administration. SSD: Conceptualization, formal analysis, resources, writing—original draft, validation.

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Correspondence to Jaewoong Lee or Shankar S. Dhasade.

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Patil, S.D., Mane, S.M., Tayade, N.T. et al. Influence of Mn substitution on structural, electrical, and magnetic properties of Li0.5Fe2.5-xO4. Appl. Phys. A 130, 183 (2024). https://doi.org/10.1007/s00339-024-07344-7

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