Abstract
The present study comprises the effects of some selected heavy metal oxides (PbO, Bi2O3, CdO, BaO) in binary phosphate glasses on the collective optical, photoluminescence, FTIR and ESR spectra with the presence of samarium ions before and after gamma irradiation (10 Mrad). The optical spectral results reveal the appearance of distinct UV absorption related to traces impurity of Fe3+ ions besides the additional presence of two rows of extending (visible–near IR) absorption due to sm3+ ions. The effects of heavy metal oxides and gamma irradiation show minor changes in the optical spectra. PL spectra show prominent emission and excitation peaks which are characteristic for trivalent samarium (Sm3+) ions. FTIR spectra reveal pronounced IR vibrational peaks due to the phosphate groups beside the sharing of mixed or interfering structural units of PbO4, BiO6–BiO3 or CdO4. ESR spectral data reveal similar signals with the different heavy metal oxide partner and confirming that the trivalent samarium is the dominant species as revealed by optical spectral measurements. The extra thermal expansion data are found to be comparable with limited variations due to the type of partner heavy metal oxide and its ability to share in forming some additional structural units. The overall results have been interpreted and evaluated.
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References
W. Vogel, Glass Chemistry (Springer, Berlin, 1994).
R.K. Brow, Review: the structure of simple phosphate glasses. J. Non-Cryst. Solids 263–264, 1–28 (2000)
J.E. Shelby, Introduction to Glass Science and Technology, 2nd edn. (The Royal Society of Chemistry, Cambridge, 2005).
J.D. Musgraves, J. Hu, L. Calvez (eds.), Springer Handbook of Glass (Springer Nature, Switzerland, 2019)
C.E. Smith, R.K. Brow, The properties and structure of zinc magnesium phosphate glasses. J. Non-Cryst. Solids 390, 51–58 (2014)
C. Mercier, G. Palavit, I. Montagne, C. Follet, Hocttemane Comptes Rendes Chimce, S(II) 693—703 (2000).
D. Ehrt, Review: Phosphate and fluoride phosphate optical glasses—properties, structure and applications. Phys. Chem. Glasses Eur. J. Glass Sci. Technol. B 56(6), 27–234 (2015)
D. Ehrt, Deep-UV materials. Adv. Opt. Technol. 7, 225–242 (2018)
H.B. George, C. Vera, C. Stehle, J. Mwyer, S. Evers, D. Hogan, S. Feller, M. Affatigato, A structural analysis of the physical properties of bismuth and lead based glasses. Phys. Chem. Glasses 40(6), 320–332 (1999)
H. Singh, K. Singh, L. Gerward, K. Singh, H.S. Sahota, R. Nathuram, ZnO–PbO–B2O3 glasses as gamma-ray shielding materials. Nucl. Instrum. Methods Phys. Res. B 207, 257–262 (2003)
G. Sharma, K. Singh, S. Mohan, H. Singh, S. Bindra, Effects of gamma irradiation on optical and structural properties of PbO–Bi2O3–B2O3 glasses. Rad. Phys. Chem. 75, 959–966 (2006)
F.H. ElBatal, M.A. Marzouk, A.M. Abdelghany, Gamma rays interaction with bismuth borate glasses doped by transition metal ions. J. Mater. Sci. 46, 5140–5152 (2011)
H.A. ElBatal, A.M. Abdelghany, F.H. ElBatal, F.M. EzzElD, Gamma rays interactions with WO3-doped lead borate glasses. Mater. Chem. Phys. 134, 542–548 (2012)
M.A. Marzouk, F.H. ElBatal, W.H. Eisa, N.A. Ghoneim, Comparative spectral and shielding studies of binary borate glasses with the heavy metal oxides SrO, CdO, BaO, PbO or Bi2O3 before and after gamma irradiation. J. Non-Cryst. Solids 387, 155–160 (2014)
R. Reisfeld, C.K. Jorgensen, Lasers and Excited States of Rare Earths (Springer, New York, 1977).
W.A. Pisarski, T. Goryczka, B. Wodecka-Duś, M. Płońska, J. Pisarska, Structure and properties of rare earth-doped lead borate glasses. Mater. Sci. Eng. B 122, 94–99 (2005)
A. Mohan Babu, B.C. Jamalaiah, T. Sasikala, S.A. Saleem, L. Rama Moorthy, Absorption and emission spectral studies of Sm3+-doped lead tungstate tellurite glasses. J. Alloys Comp. 509, 4743–4747 (2011)
M.A. Marzouk, Y.M. Hamdy, H.A. ElBatal, F.M. Ezz-ElDin, Photoluminescence and spectroscopic dependence of flurophosphate glasses on samarium ions concentrations and the induced defects by gamma irradiation. J. Lumin. 166, 295–303 (2015)
M.A. Marzouk, Y.M. Hamdy, H.A. ElBatal, F.M. Ezz-ElDin, Study on the reducing effect of γ-irradiation on Sm3+ doped LiAl fluorophosphate glasses through optical, structural and luminescence analysis. J. Mater. Sci. Mater. Electron. 29, 1399–1411 (2018)
M.A. Marzouk, A.M. Abdelghany, H.A. ElBatal, Bismuth silicate glass as host media for some selected rare-earth ions and effects of gamma irradiation. Philos. Mag. 93(19), 2465–2484 (2013)
J.A. Duffy, Charge transfer spectra of metal ions in glass. Phys. Chem. Glasses 38, 289–294 (1997)
D. Ehrt, P. Ebeling, U. Natura, UV Transmission and radiation-induced defects in phosphate and fluoride–phosphate glasses. J. Non-Cryst. Solids 263, 240–250 (2000)
D. Möncke, D. Ehrt, Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants. Opt. Mater. 25, 425–437 (2004)
F.H. El-Batal, M.A. Azooz, F.M. Ezz-Eldin, Thermal expansion and infrared studies of binary Bi2O3-B2O3 and ternary Bi2O3-B2O3-PbO glasses. Phys. Chem. Glasses 43(5), 260–266 (2002)
F.H. El Batal, A.A. El Kheshen, M.A. Azooz, S.M. Abo-Naf, Gamma ray interaction with lithium diborate glasses containing transition metals ions. Opt. Mater. 30, 881–891 (2008)
F.H. ElBatal, Y.M. Hamdy, S.Y. Marzouk, Gamma ray interactions with V2O5-doped sodium phosphate glasses. Mater. Chem. Phys. 112(3), 991–1000 (2008)
M.A. Ouis, H.A. ElBatal, A.M. Abdelghany, A.H. Hammad, Structural and optical properties of CuO in zinc phosphate glasses and effects of gamma irradiation. J. Mol. Struct. 1103, 224–231 (2016)
Y.M. Hamdy, F.H. ElBatal, F.M. Ezz-Eldin, H.A. ElBatal, Gamma rays interactions with transition metal doped-soda lime phosphate glasses evaluated by collective optical. FTIR Spectral Meas. Silicon 11(2), 673–684 (2019)
F.H. ElBatal, M.A. Ouis, R.M. Morsi, S.Y. Marzouk, Interactions of gamma rays with undoped and Mn-doped sodium phosphate glasses. Philos. Mag. 90(21), 2905–2924 (2010)
O. Sanz, E. Haro-Poniatowski, J. Gonzalo, J.M. Fernández Navarro, Influence of the melting conditions of heavy metal oxide glasses containing bismuth oxide on their optical absorption. J. Non-Cryst. Solids 352, 761–768 (2006)
A. Bishay, Radiation induced color centers in multicomponent glasses. J. Non-Cryst. Solids 3, 54–114 (1970)
E. J. Friebele, in Optical Properties of Glasses, eds. by D. R. Uhlmann, N. J. Kreidl (American Ceramic Society, Westerville, 1991) p. 205–262.
D. Möncke, D. Ehrt, Photoionization of Polyvalent Ions, in Horizons, Materials Science Research Horizons. ed. by H.P. Glick (Nova Science Publishers Inc, New York, 2007), pp. 1–56
D. Möncke, Photo-ionization of 3D-ions in fluoride-phosphate glasses. Int. J. Appl. Glass Sci. 6(3), 249–267 (2015)
M. Seshadri, K.V. Rao, J.L. Rao, Y.C. Ratnakaram, Spectroscopic and laser properties of Sm3+ doped different phosphate glasses. J. Alloys Compnd. 476, 263–270 (2009)
A. Mohan Babu, B.C. Jamalaiah, T. Sasikala, S.A. Saleem, L. Rama Moorthy, Absorption and emission spectral studies of Sm3+-doped lead tungstate tellurite glasses. J. Alloys Compnd. 509, 4743–4747 (2011)
M.R. Dosuti, S.K. Ghoshal, R.J. Amjad, M.R. Sahar, F. Nawaz, R. Arifin, Structural and optical study of samarium doped lead zinc phosphate glasses. Opt. Commun. 300, 204–209 (2013)
E. Malchukova, B. Boizot, Spectroscopic properties and luminescence decay behavior of pristine and β-irradiated Sm-doped borosilicate glasses. J. Lumin. 229, 117662 (2021)
Y.M. Hamdy, S. Bahammam, S. Abd El All, F.M. Ezz-Eldin, Spectroscopic properties and luminescence behavior of γ-irradiated Sm3+ doped oxy-fluoride phosphate glasses. Results Phys. 7, 1223–1229 (2017)
E. Malchukova, B. Boizot, G. Petite, D. Ghaleb, Optical properties and valence state of Sm ions in aluminoborosilicate glass under β-irradiation. J. Non-Cryst. Solids 353, 2397–2402 (2007)
B. Morrell, G. Okada, S. Vahedi, C. Koughia, A. Edgar, C. Varoy, G. Belev, T. Wysokinski, D. Chapman, R. Sammynaiken, S.O. Kasap, Optically erasable samarium-doped fluorophosphate glasses for high-dose measurements in microbeam radiation therapy. J. Appl. Phys. 115, 063107 (2014)
A. Abdel-Kader, A.A. Higazy, M.M. Elkholy, Compositional dependence of infrared absorption spectra studies for TeO2-P2O5 and TeO2-P2O5-Bi2O3 glasses. J. Mater. Sci Mater. Electron. 2, 157–163 (1991)
Y.M. Moustafa, K. El-Egili, Infrared spectra of sodium phosphate glasses. J. Non-Cryst. Solids 240, 144–153 (1998)
E. Metwalli, M. Karabulut, D.L. Sidebottom, M.M. Morsi, R.K. Brow, Properties and structure of copper ultraphosphate glasses. J. Non-Cryst. Solids 344, 128–134 (2004)
F.H. El-Batal, Gamma ray interaction with copper-doped sodium phosphate glasses. J. Mater. Sci. 43(3), 1070–1079 (2008)
M.A. Marzouk, F.H. ElBatal, K.M. ElBadry, H.A. ElBatal, Optical, structural and thermal properties of sodium metaphosphate glasses containing Bi2O3 with interactions of gamma rays. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 171, 454–460 (2017)
H. Rawson, Properties and Applications of Glasses (Elsevier, Amsterdam, 1980), p. 69
N.A. Ghoneim, K.M. ElBadry, Thermochim. Acta 60, 253–263 (1983)
N.A. Ghoneim, A.F. Abbas, Thermochim. Acta 66, 91–103 (1983)
H.A. ElBatal, N.A. Ghoneim, F.M. EzzElDin, Effect of thermal neutrons on thermal expansion of some ternary borate glasses. Nucl. Instrum. Methods Phys. Res. Sect. B 88, 411–417 (1994)
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Marzouk, M.A., Elbatal, H.A. Investigation of photoluminescence and spectroscopic properties of Sm3+-doped heavy phosphate glasses before and after gamma irradiation. Appl. Phys. A 127, 70 (2021). https://doi.org/10.1007/s00339-020-04215-9
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DOI: https://doi.org/10.1007/s00339-020-04215-9