Abstract
In this study, the electronic structure, chemical composition, and magnetic properties of multilayer ultrathin films of epitaxial maghemite (γ-Fe2O3/MgO)N were investigated. The multilayer structures of the (γ-Fe2O3/MgO)N ultrathin films were grown by molecular beam epitaxy (MBE) under ultrahigh vacuum on magnesium oxide substrates with different numbers of layers (where the number of layers, N = 2, 4, and 6). X-ray photoemission measurement (XPS) showed that the multilayer oxide films possessed only a single phase of maghemite γ-Fe2O3 with full stoichiometry. The magnetic moment of all of the multilayer samples showed ferromagnetic behavior, with magnetizations close to the bulk value of γ-Fe2O3, which has not been previously observed or considered. Moreover, the magnetization increased as the number of layers increased. These findings show that the multilayer ultrathin γ-Fe2O3film possesses good magnetic properties that are close to those of the bulk of γ-Fe2O3, and will thus be useful in developing spintronic devices with good performance and other technological applications.
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J.A. Borchers, R.W. Erwin, S.D. Berry, D.M. Lind, J.F. Ankner, E. Lochner, K.A. Shaw, D. Hilton, Phys. Rev. B 51, 8276 (1995)
J.A. Borchers, M.J. Carey, R.W. Erwin, C.F. Majkrzak, A.E. Berkowitz, Phys. Rev. Lett. 70, 1878 (1993)
P.J. Van der Zaag, A.R. Ball, L.F. Feiner, R.M. Wolf, P.A.A. Van Der Heijden, J. Appl. Phys. 79, 5103 (1996)
P.A.A. Van der Heijden, P.J.H. Bloemen, J.M. Metselaar, R.M. Wolf, J.M. Gaines, J.T.W.M. Van Eemeren, P.J. Van der Zaag, W.J.M. De Jonge, Phys. Rev. B 55, 11569 (1997)
M.A. James, F.C. Voogt, L. Niesen, O.C. Rogojanu, T. Hibma, Surf. Sci. 402, 332 (1998)
G.J. Strijkers, J.T. Kohlhepp, P.A.A. Van der Heijden, H.J.M. Swagten, W.J. De Jonge, J.M. Gaines, J. Appl. Phys. 85, 5294 (1999)
C.L. Chang, G. Chern, Y.R. Chean, C.L. Chen, Appl. Surf. Sci. 161, 448 (2000)
P.A.A. Van der Heijden, P.J.H. Bloemen, J.M. Gaines, J.T.W.M. Van Eenneren, R.M. Wolf, P.J. Van der Zaag, W.J.M. De Jonge, J. Magn. Magn. Mater. 159, L293 (1996)
R.J.M. Van De Veerdonk, M.A.M. Gijs, P.A.A. Van Der Heijden, R.M. Wolf, W.J.M. De Jonge, MRS Online Proc. Libr. 401, 485 (1995)
P.A.A. Van der Heijden, M.G. Van Opstal, C.H.W. Swüste, P.H.J. Bloemen, J.M. Gaines, W.J.M. De Jonge, J. Magn. Magn. Mater. 182, 71 (1998)
Y. Ijiri, J. Phys. Condens. Matter 14(37), R947 (2002)
J.K. Vassiliou, V. Mehrotra, M.W. Russell, E.P. Giannelis, R.D. McMichael, R.D. Shull, R.F. Ziolo, J. Appl. Phys. 73, 5109 (1993)
G. Chern, Y.D. Yao, Y.Y. Chen, S.C. Lai, Y.R. Chean, IEEE Trans. Magn. 33, 3700 (1997)
S. Alraddadi, W. Hines, B. Sinkovic, IEEE Trans. Magn. 55(3), 1–5 (2019)
O. Mauit, K. Fleischer, C.Ó. Coileáin, B. Bulfin, D.S. Fox, C.M. Smith, D. Mullarkey, G. Sugurbekova, H. Zhang, I.V. Shvets, Phys. Rev. B 95(12), 125128 (2017)
N.E. Domracheva, V.E. Vorobeva, M.S. Gruzdev, A.V. Pyataev, J. Nanopart. Res. 17, 83 (2015)
R.F. Ziolo, E.P. Giannelis, B.A. Weinstein, M.P. O’Horo, B.N. Ganguly, V. Mehrotra, M.W. Russell, D.R. Huffman, Science 257, 219 (1992)
M. Mirza, K. Ali, A. Sarfraz, A. Ali, A. ul Haq, Mater. Chem. Phys. 164, 183 (2015)
S. Apte, S. Naik, R. Sonawane, B. Kale, J. Baeg, J. Am. Ceram. Soc. 90, 412 (2007)
A.C. Garade, M. Bharadwaj, S.V. Bhagwat, A.A. Athawale, C. Rode, Catal. Commun. 10, 485 (2009)
S.-W. Cao, Y.-J. Zhu, M.-Y. Ma, L. Li, L. Zhang, J. Phys. Chem. C 112, 1851 (2008)
H. Khurshid, S. Kim, M. Bonder, L. Colak, B. Ali, S. Shah, K.L. Kiick, G. Hadjipanayis, J. Appl. Phys. 105, 07B308 (2009)
M. Liong, J. Lu, M. Kovochich, T. Xia, S.G. Ruehm, A.E. Nel, F. Tamanoi, J.I. Zink, ACS Nano 2, 889 (2008)
Y.N. Wu, M. Zhou, S. Li, Z. Li, J. Li, B. Wu, G. Li, F. Li, X. Guan, Small 10, 2927 (2014)
Z. Jing, Y. Wang, S. Wu, Sens. Actuators B Chem. 113, 177 (2006)
Z. Jing, Mater. Lett. 60, 3315 (2006)
P.M. Rao, X. Zheng, Nano Lett. 11, 2390 (2011)
Q. Han, Z. Liu, Y. Xu, Z. Chen, T. Wang, H. Zhang, J. Phys. Chem. C 111, 5034 (2007)
H. Yanagihara, M. Hasegawa, E. Kita, Y. Wakabayashi, H. Sawa, K. Siratori, J. Phys. Soc. Jpn. 75, 054708 (2006)
T. Nozaki, T. Ohkubo, Y. Shiota, H. Kubota, A. Fukushima, K. Hono, Y. Suzuki, S. Yuasa, Appl. Phys. Express 6, 113004 (2013)
S. Alraddadi, W. Hines, T. Yilmaz, G.D. Gu, B. Sinkovic, J. Phys. Condens. Matter 28, 115402 (2016)
L. Baldrati, C. Schneider, T. Niizeki, R. Ramos, J. Cramer, A. Ross, E. Saitoh, M. Kläui, Phys. Rev. B 98, 014409 (2018)
C.S. Kuivila, J.B. Butt, P.C. Stair, Appl. Surf. Sci. 32, 99 (1988)
V. Stambouli, C. Palacio, H.J. Mathieu, D. Landolt, Appl. Surf. Sci. 70, 240 (1993)
P. Graat, M.A. Somers, Surf. Interface Anal. 26, 773 (1998)
J.S. Corneille, J.W. He, D.W. Goodman, Surf. Sci. 338, 211 (1995)
Y. Gao, Y.J. Kim, S.A. Chambers, G. Bai, J. Vaccum Sci. Technol. A 15, 332 (1997)
T. Yamashita, P. Hayes, Appl. Surf. Sci. 254(8), 2441 (2008)
T. Schedel-Niedrig, W. Weiss, R. Schlögl, Phys. Rev. B 52, 17449 (1985)
T. Fujii, F.M.F. De Groot, G.A. Sawatzky, F.C. Voogt, T. Hibma, K. Okada, Phys. Rev. B 59, 3195 (1999)
F.J. Morin, Phys. Rev. B 78, 819 (1950)
L. Suber, A.G. Santiago, D. Fiorani, P. Imperatori, A.M. Testa, M. Angiolini, J.L. Dormann, Appl. Organomet. Chem. 12, 347 (1998)
E.J.W. Verwey, Nature 144, 327 (1939)
D.D. Dung, W. Feng, D. Van Thiet, Y. Kim, S. Cho, Mater. Lett. 161, 343 (2015)
D.T. Margulies, F.T. Parker, F.E. Spada, R.S. Goldman, J. Li, R. Sinclair, A.E. Berkowitz, Phys. Rev. Lett. 79, 5162 (1997)
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We would like to acknowledge the technical support received from the Center of Nanotechnology at KAU.
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Alraddadi, S. Electronic structure and magnetic properties of (γ-Fe2O3/MgO)N multilayers. Appl. Phys. A 127, 53 (2021). https://doi.org/10.1007/s00339-020-04204-y
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DOI: https://doi.org/10.1007/s00339-020-04204-y