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Structural, electrochemical and optical properties of 1,2,4-triazine derivative

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Abstract

Structural, optical and electrochemical properties of 4-amino-3-mercapto-6-(2-(2-thienyl)vinyl)-1,2,4-triazin-5(4H)-one donor (AMT) in powder and thin film forms are studied. The thermogravimetric curves (TGA and DTA) of AMT solid powder are performed for recognizing its thermal stability and thermal degradation kinetics. Integral method using Coats–Redfern and Horowitz–Metzger equations are applied in the dynamic thermal data analysis. The electrochemical reduction and oxidation potential of AMT organic material are investigated. AMT solid powder are characterized by means of optically diffused reflectance spectroscopy (DRS) based on the Kubelka–Munk model. Field emission scanning electron microscope image is characterized by the formation of nanostructure shape with average particle size 70 nm. The optical features of the AMT organic thin films are characterized by UV–Vis–NIR spectroscopy, Photoluminescence spectroscopy (PL) and Fourier transform infrared (FT-IR) spectroscopy. The optical properties such as absorption coefficient, optical gaps, refractive index, single effective oscillator energy (Eo) and dispersion energy (Ed) of the AMT organic thin films are estimated.

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Acknowledgements

Taif University Researchers Supporting Project number (TURSP-2020/04), Taif University, Taif, Saudi Arabia.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia

    T. Altalhi, A. A. Gobouri, Moamen S. Refat & Hosam A. Saad

  2. Department of Chemistry, Faculty of Science, Port Said University, Port Said, 42111, Egypt

    Moamen S. Refat

  3. Department of Physics, Faculty of Education, Ain Shams University, Roxy, Cairo, 11757, Egypt

    M. M. El-Nahass & A. A. Atta

  4. Department of Physics, College of Science and Humanities, Shaqra University, Al Quwaiiyah, Saudi Arabia

    A. M. Hassanien

  5. Department of Physics, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia

    A. A. Atta

  6. Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, 44511, Egypt

    Hosam A. Saad

  7. Research Chair for Tribology, Surface and Interface Sciences (TSIS), Department of Physics and Astronomy, College of Science, King Saud University, Riyadh, Saudi Arabia

    Abdulaziz N. Alhazaa

  8. King Abdullah Institute for Nanotechnology, King Saud University, Riyadh, 11451, Saudi Arabia

    Abdulaziz N. Alhazaa

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  1. T. Altalhi
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Altalhi, T., Gobouri, A.A., Refat, M.S. et al. Structural, electrochemical and optical properties of 1,2,4-triazine derivative. Appl. Phys. A 126, 815 (2020). https://doi.org/10.1007/s00339-020-03995-4

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