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Photochromic nanocellulose composite films with excellent anti-UV capacity

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Abstract

Recently, green and sustainable photochromic devices have attracted considerable attention in the research community. In this work, we report a novel ultraviolet (UV)-responsive nanocellulose film using ammonium molybdate as the photochromic dye. Meanwhile, trirthylene glycol (TEG) was incorporated to accelerate the light-responsive process. Therefore, the photochromic nanocellulose film exhibits a fast response photochromic ability and inherits the high transparency of the nanocellulose film. Moreover, the reversible photochromic of the film can be easily repeated. Importantly, the photochromic and fading processes can be precisely controlled and predicted by adjusting the outside temperature and the film composition. Interestingly, the photochromic cellulose films also have great UV blocking and biodegradability. In summary, this green nanocellulose based photochromic film has a giant potential for flexible light-memory devices.

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References

  1. J.K. Rad, A.R. Mahdavian, Preparation of fast photoresponsive cellulose and kinetic study of photoisomerization. J. Phys. Chem. C. 120, 9985–9991 (2016)

    Article  Google Scholar 

  2. Z. Zhang, Y. Wang, J. Wang, N. Wang, N. Han, X. Zhang, W. Li, Reversible photochromic nanofiber membrane containing comb-like poly(octadecyl acrylate) nanoparticles used for ultraviolet intensity indicator. Macromol Mater Eng. 304, 1438–7492 (2019)

    Article  Google Scholar 

  3. L. Sheng, M. Li, S. Zhu, H. Li, G. Xi, Y.G. Li, Y. Wang, Q. Li, S. Liang, K. Zhong, S.X. Zhang, Hydrochromic molecular switches for water-jet rewritable paper. Nat. Commun. 5, 3044 (2014)

    Article  ADS  Google Scholar 

  4. W. Wang, N. Xie, L. He, Y. Yin, Photocatalytic colour switching of redox dyes for ink-free light-printable rewritable paper. Nat. Commun. 5, 5459 (2014)

    Article  ADS  Google Scholar 

  5. M. Xu, W. Li, C. Ma, H. Yu, Y. Wu, Y. Wang, Z. Chen, J. Li, S. Liu, Multifunctional chiral nematic cellulose nanocrystals/glycerol structural colored nanocomposites for intelligent responsive films, photonic inks and iridescent coatings. J. Phys. Chem. C. 6, 5391–5400 (2018)

    Google Scholar 

  6. R. Pardo, M. Zayat, D. Levy, Photochromic organic-inorganic hybrid materials. Chem Soc Rev. 40, 672–687 (2011)

    Article  Google Scholar 

  7. R. Klajn, Spiropyran-based dynamic materials. Chem. Soc. Rev. 43, 148–184 (2014)

    Article  Google Scholar 

  8. X. Tian, B. Wang, J. Li, J. Zeng, K. Chen, Photochromic paper from wood pulp modification via layer-by-layer assembly of pulp fiber/chitosan/spiropyran. Carbohydr. Polym. 157, 704–710 (2017)

    Article  Google Scholar 

  9. S. Yamazaki, H. Ishida, D. Shimizu, K. Adachi, Photochromic properties of tungsten oxide/methylcellulose composite film containing dispersing agents. ACS Appl. Mater. Interfaces. 7, 26326–26332 (2015)

    Article  Google Scholar 

  10. M. Kathan, P. Kovaricek, C. Jurissek, A. Senf, A. Dallmann, A.F. Thunemann, S. Hecht, Control of imine exchange kinetics with photoswitches to modulate self-healing in polysiloxane networks by light illumination. Angew Chem Int Ed Engl. 55, 13882–13886 (2016)

    Article  Google Scholar 

  11. S. Omwoma, C.T. Gore, Y. Ji, C. Hu, Y.F. Song, Environmentally benign polyoxometalate materials. Coordin. Chem. Rev. 286, 17–29 (2015)

    Article  Google Scholar 

  12. J. Xu, H. Volfova, R.J. Mulder, L. Goerigk, G. Bryant, E. Riedle, C. Ritchie, Visible-light-driven “on”/“off” photochromism of a polyoxometalate diarylethene coordination complex. J. Am. Chem. Soc. 140, 10482–10487 (2018)

    Article  Google Scholar 

  13. Q. Han, C. He, M. Zhao, B. Qi, J. Niu, C. Duan, Engineering chiral polyoxometalate hybrid metal-organic frameworks for asymmetric dihydroxylation of olefins. J. Am. Chem. Soc. 135, 10186–10189 (2013)

    Article  Google Scholar 

  14. Y. Yang, J. Li, X. Li, L. Guan, Z. Gao, L. Duan, F. Jia, G. Gao, Easily prepared and reusable films for fast-response rewritable light printing. ACS Appl. Mater. Interfaces. 11, 14322–14328 (2019)

    Article  Google Scholar 

  15. H. Sun, N. Gao, J. Ren, X. Qu, Polyoxometalate-based rewritable paper. Chem. Mater. 27, 7573–7576 (2015)

    Article  Google Scholar 

  16. F. Liu, S. Song, D. Xue, H. Zhang, Folded structured graphene paper for high performance electrode materials. Adv. Mater. 24, 1089–1094 (2012)

    Article  Google Scholar 

  17. J. Hu, S. Wang, L. Wang, F. Li, B. Pingguan-Murphy, T.J. Lu, F. Xu, Advances in paper-based point-of-care diagnostics. Biosens Bioelectron. 54, 585–597 (2014)

    Article  Google Scholar 

  18. J. He, P. Xiao, J. Shi, Y. Liang, W. Lu, Y. Chen, W. Wang, P. Théato, S.W. Kuo, T. Chen, High performance humidity fluctuation sensor for wearable devices via a bioinspired atomic-precise tunable graphene-polymer heterogeneous sensing junction. Chem. Mater. 30, 4343–4354 (2018)

    Article  Google Scholar 

  19. H. Liu, H. Jiang, F. Du, D. Zhang, Z. Li, H. Zhou, Flexible and degradable paper-based strain sensor with low cost. ACS Sustain Chem Eng. 5, 10538–10543 (2017)

    Article  Google Scholar 

  20. I. Diez, P. Eronen, M. Osterberg, M.B. Linder, O. Ikkala, R.H. Ras, Functionalization of nanofibrillated cellulose with silver nanoclusters: fluorescence and antibacterial activity. Macromol Biosci. 11, 1185–1191 (2011)

    Article  Google Scholar 

  21. C.C. Hsu, C.S. Wu, Y.L. Liu, Multiple stimuli-responsive poly(vinylidene fluoride) (PVDF) membrane exhibiting high efficiency of membrane clean in protein separation. J. Membr. Sci 450, 257–264 (2014)

    Article  Google Scholar 

  22. H. Koga, M. Nogi, A. Isogai, Ionic liquid mediated dispersion and support of functional molecules on cellulose fibers for stimuli-responsive chromic paper devices. ACS Appl. Mater. Interfaces. 9, 40914–40920 (2017)

    Article  Google Scholar 

  23. H. Li, Y.J. Zhu, Y.Y. Jiang, Y.D. Yu, F. Chen, L.Y. Dong, J. Wu, Hierarchical assembly of monodisperse hydroxyapatite nanowires and construction of high-strength fire-resistant inorganic paper with high-temperature flexibility. Chem. Nano. Mat. 3, 259–268 (2017)

    Google Scholar 

  24. Z. Fang, H. Zhu, C. Preston, L. Hu, Development, application and commercialization of transparent paper. Trans. Mater. Res. 1, 015004 (2014)

    Article  Google Scholar 

  25. F. Rol, M.N. Belgacem, A. Gandini, J. Bras, Recent advances in surface-modified cellulose nanofibrils. Prog. Polym. Sci. 88, 241–264 (2019)

    Article  Google Scholar 

  26. J. Huang, H. Zhu, Y. Chen, C. Preston, K. Rohrbach, J. Cumings, L. Hu, Highly transparent and flexible nanopaper transistors. ACS Nano 7, 2106–2113 (2013)

    Article  Google Scholar 

  27. Y. Yang, L. Guan, G. Gao, Low-cost, rapidly responsive, controllable, and reversible photochromic hydrogel for display and storage. ACS Appl. Mater. Interfaces. 10, 13975–13984 (2018)

    Article  Google Scholar 

  28. H. Fudouzi, Y. Xia, Photonic papers and inks: color writing with colorless materials. Adv. Mater. 15, 892–896 (2003)

    Article  Google Scholar 

  29. K. Ahn, S. Zaccaron, N.S. Zwirchmayr, H. Hettegger, A. Hofinger, M. Bacher, U. Henniges, T. Hosoya, A. Potthast, T. Rosenau, Yellowing and brightness reversion of celluloses: CO or COOH, who is the culprit? Cellulose 26, 429–444 (2019)

    Article  Google Scholar 

  30. A. Du, H. Wang, B. Zhou, C. Zhang, X. Wu, Y. Ge, T. Niu, X. Ji, T. Zhang, Z. Zhang, G. Wu, J. Shen, Multifunctional silica nanotube aerogels inspired by polar bear hair for light management and thermal insulation. Chem. Mater. 30, 6849–6857 (2018)

    Article  Google Scholar 

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Acknowledgements

The authors are grateful to the National Key Research and Development Program of China (2017YFB0307900), National Natural Science Foundation of China (31971612), Scientific and Technological Innovation Funding of Fujian Agriculture and Forestry University (CXZX2017480, CXZX2017481, CXZX2018003, CXZX2019109).

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Correspondence to Yonghao Ni or Kai Liu.

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Guo, R., Hu, K., He, P. et al. Photochromic nanocellulose composite films with excellent anti-UV capacity. Appl. Phys. A 126, 812 (2020). https://doi.org/10.1007/s00339-020-03988-3

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