Abstract
In the present study, the effects of doping on the LTP-MnBi phase formation as well as on Mn to Bi ratio in the matrix were investigated. Structural- and magnetic properties of nanocrystalline Mn50−xBi50Crx (x = 0, 1.5, 3, 5) permanent magnet material, prepared by melt-spinning were studied and correlated with the thermal analysis. A more stabilized LTP-MnBi phase is formed with Cr doping. A large enhancement in the coercivity along with magnetization is observed with Cr doping. A magnetization of 54.2 emu/g and a coercivity value of 11.9 kOe were obtained for the composition Mn47Bi50Cr3 at room temperature, which increases to 17.5 kOe at 150 °C. An interesting correlation exists between the thermal as well as the structural- and magnetic properties of the compound. Also, a decrease in magnetic transition temperature is observed in Cr-doped samples, which has been studied in detail. This decrease in magnetic transition temperature helps in the decoupling of structural- and magnetic transition temperature, thereby leading to a formation of more stable LTP-MnBi compound.
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J.M.D. Coey, I.E.E.E. Trans, Magn. 47, 4671 (2011)
M.J. Kramer, R.W. McCallum, I.A. Anderson, S. Constantinides, J. Min. Met. Mater. Soc. 64, 752 (2012)
K. Anand, N. Christopher, J. Kumar, A. Gupta, N. Singh, J. Magn. Magn. Mater. 476, 29–34 (2019)
N. Singh, K. Anand, N. Christopher, A. Bhattacharya, A.K. Srivastava, J. Mater. Chem. C 5, 11832–11836 (2017)
N.R. Christopher, N. Singh, S.K. Singh, B. Gahtori, S.K. Mishra, A. Dhar, V.P.S. Awana, J. Supercond. Novel. Magn. 26(11), 3161–3165 (2013)
B.W. Roberts, Phys. Rev. 104, 607–616 (1956)
E. Adams, Rev. Modern Phys. 25, 1 (1953)
J.B. Yang, W.B. Yelon, W.J. James, Q. Cai, M. Kornecki, S. Roy, N. Ali, P. L’Heritier, J. Phys. Condens. Matter 14, 6509–6519 (2002)
T. Chen, W.E. Stutius, I.E.E.E. Trans, Magn. 10, 581 (1974)
X. Guo, X. Chen, Z. Altounian, J.O. Ström-Olsen, Phys. Rev. B 46, 14578 (1992)
A.F. Andresen, W. Halg, P. Fischer, E. Stoll, Acta Chem. Scand. 21, 1543 (1967)
P.W. Anderson, Phys. Rev. 115, 2 (1959)
R. Bandaru, T.D. Sands, D. Weller, E.E. Marinero, J. Appl. Phys. 86, 3 (1999)
T. Chen, J. Appl. Phys. 45, 2358 (1974)
R. Heikes, Phys. Rev. 99, 446 (1955)
J.B. Goodenough, Magnetism and the Chemical Bond (Wiley, New York, 1967)
A. West, Solid State Chemistry and Its Applications (Wiley, New York, 1984)
M. Venkataraman, J. P. Neumann, in Binary Alloy Phase Diagrams, edited by H. Okamoto and P. R. Subramanian ~ASM International, Materials Park, OH (1988)
H. Göbel, E. Wolfgang, H. Harms, Phys. Status Solidi A 34, 553 (1976)
K. Lee, J.C. Suits, G.B. Street, Appl. Phys. Lett. 26, 27 (1975)
P. Kharel, V.R. Shah, R. Skomski, J.E. Shield, D.J. Sellmyer, IEEE Trans. Magn. 49, 7 (2013)
P. Kharel, X. Li, S.R. Valloppilly, N.M. Al-Aqtash, K. Tarawneh, R.F. Sabirianov, R. Skomski, D.J. Sellmyer, J. Appl. Phys. 111, 07e326 (2012)
V.V. Ramakrishna, S. Kavita, R. Gautam, T. Ramesh, R. Gopalan, J. Magn. Magn. Mater. 458, 23–29 (2018)
P. Bandaru, T.D. Sands, Y. Kubota, E.E. Marinero, Appl. Phys. Lett. 72, 1 (1998)
R.F. Sabiryanov, S.S. Jaswal, J. Appl. Phys. 85(8), 15 (1999)
P. Kharel, R. Skomski, P. Lukashev, R. Sabirianov, J.D. Sellmyer, Phys. Rev. B 84, 014431 (2011)
A.R. West, Solid State Chemistry and its Applications (Wiley, New York, 1992)
S. Saha, R.T. Obermyer, B.J. Zande, V.K. Chandhok, S. Simizu, S.G. Sankar, J.A. Horton, J. Appl. Phys. 91(10), 8525–8527 (2002)
Y.B. Yang, X.G. Chen, S. Guo, A.R. Yan, Q.Z. Huang, M.M. Wu, D.F. Chen, Y.C. Yang, J.B. Yang, J. Magn. Magn. Mater. 330, 106–110 (2013)
S. Kim, H. Moon, H. Jung, S.-M. Kim, H.-S. Lee, H. Choi-Yim, W. Lee, J Alloy Compd 708, 1245–1249 (2017)
Y.B. Yang, X.G. Chen, R. Wu, J.Z. Wei, X.B. Ma, J.Z. Han, H.L. Du, S.Q. Liu, C.S. Wang, Y.C. Yang, Y. Zhang, J.B. Yang, J. Appl. Phys. 111, 07E312 (2012)
S. Saha, R.T. Obermyer, B.J. Zande, V.K. Chandhok, S. Simizu, S.G. Sankara, J.A. Horton, J. Appl. Phys. 91, 10 (2002)
X. Guo, A. Zaluska, Z. Altounian, J.O. Strom-Olsen, J. Mater. Res. 5, 2646 (1990)
X. Guo, A. Zaluska, Z. Altounian, J.O. Strom-Olsen, J. Appl. Phys. 69, 6067 (1991)
N.V. Rama-Rao, G.C. Hadjipanayis, J. Alloys Compd. 629, 80–83 (2015)
N.V. Rama-Rao, G.C. Hadjipanayis, J. Alloys Compd. 616, 319–322 (2014)
G.R. Gajula, L.R. Buddiga, K.N. Chidambara-Kumar, M. Dasari, J. Mater. Sci. Mater. Electron. 30(4), 3889–3898 (2018)
G.R. Gajula, L.R. Buddiga, J. Magn. Magn. Mater. 494, 165822 (2020)
D.T. Zhang, S. Cao, M. Yue, W.Q. Liu, J.X. Zhang, Y. Qiang, J. Appl. Phys. 109, 07A722 (2011)
Y. Yang, J.-W. Kim, P.-Z. Si, H.-D. Qian, Y. Shin, X. Wang, J. Park, O.L. Li, Q. Wu, H. Ge, C.-J. Choi, J. Alloys Compd. (2018).https://doi.org/10.1016/j.jallcom.2018.07.311
K. Koyama, T. Onogi, Y. Mitsui, Y. Nakamori, S. Orimo, K. Watanabe, Mater. Trans. 48(9), 2414–2418 (2007)
G.R. Gajulaa, L.R. Buddiga, K.N. Chidambara-Kumar, N. Vattikunta, M. Dasari, Physica B Phys. Condens. Mater. 560, 1–5 (2019)
Acknowledgements
This work was carried out under CSIR (India) Network Project PSC-0109. KA and NC acknowledge CSIR for financial assistance. Authors would like to thank Radhey Shyam and Naval Kishor for their technical support.
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Anand, K., Christopher, N. & Singh, N. Evaluation of structural and magnetic property of Cr-doped MnBi permanent magnet material. Appl. Phys. A 125, 870 (2019). https://doi.org/10.1007/s00339-019-3156-x
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DOI: https://doi.org/10.1007/s00339-019-3156-x