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Synthesis and nonlinear optical property of polycrystalline MnTeMoO6

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Abstract

Polycrystalline MnTeMoO6 powder has been synthesized by a new approach that MnO2 is used as the manganese source. The transformation mechanism of manganese ions in the new approach has been discussed. The nonlinear optical property of polycrystalline MnTeMoO6 has been investigated, and compared with single-crystalline samples. The transformation Mn4+ → Mn2+ may be formed directly without stable intermediates, and TeO2 may serve as catalyst. The SHG response of polycrystalline MnTeMoO6 powder is worse than that of single-crystalline powder in the same particle size distribution as its pseudo-size. The results indicate that it should pay special attention with the pseudo-size of polycrystalline powder when the potential nonlinear optical materials are screened by powder second harmonic generation measurements.

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Acknowledgements

This work was supported by the Scientific Research Key Project of Yibin University [No. 2015QD11] and Major Projects of Yibin City of China.

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Authors and Affiliations

  1. Key Laboratory of Computational Physics of Sichuan Province, Yibin University, Yibin, 644000, China

    Chengguo Jin

  2. School of Physics and Electronic Engineering, Yibin University, Yibin, 644000, China

    Chengguo Jin

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  1. Chengguo Jin
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Correspondence to Chengguo Jin.

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Jin, C. Synthesis and nonlinear optical property of polycrystalline MnTeMoO6 . Appl. Phys. A 123, 295 (2017). https://doi.org/10.1007/s00339-017-0930-5

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  • DOI: https://doi.org/10.1007/s00339-017-0930-5

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