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The role of H-plasma on aluminum-induced crystallization of amorphous silicon

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Abstract

We propose a technique to improve and accelerate aluminum-induced crystallization (AIC) by hydrogen plasma. Raman spectroscopy and secondary ion mass spectrometry of crystallized poly-silicon thin films show that hydrogen plasma radicals reduce the crystallization time of AIC. This technique shortens the annealing time from 10 to 4 h and increases the Hall mobility from 22 to 42 cm2/V s. The possible mechanism of AIC assisted by hydrogen radicals is also discussed.

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References

  1. M.A. Crowder, M. Moriguchi, Y. Mitani, A.T. Voutsas, Parametric investigation of SLS-processed poly-silicon thin films for TFT applications. Thin Solid Films 427, 101–107 (2003)

    Article  ADS  Google Scholar 

  2. L. Carnel, I. Gordon, D. Van Gestel, K. Van Nieuwenhuysen, G. Agostinelli, G. Beaucarne, J. Poortmans, Thin-film polycrystalline silicon solar cells on ceramic substrates with a Voc above 500 mV. Thin Solid Films 511, 21–25 (2006)

    Article  ADS  Google Scholar 

  3. G.J. Qi, S. Zhang, T.T. Tang, J.F. Li, X.W. Sun, X.T. Zeng, Experimental study of aluminum-induced crystallization of amorphous silicon thin films. Surf Coat Technol 198, 300–303 (2005)

    Article  Google Scholar 

  4. E. Pihan, A. Slaoui, C. Maurice, Growth kinetics and crystallographic properties of poly-silicon thin films formed by aluminium-induced crystallization. J Cryst Growth 305, 88–98 (2007)

    Article  ADS  Google Scholar 

  5. Andrey Sarikov, Jens Schneider, Martin Muske, Ina Sieber, Stefan Gall, A model of preferential (100) crystal orientation of Si grains grown by Aluminium-induced layer-exchange process. Thin Solid Films 515, 746 (2007)

    Article  Google Scholar 

  6. H. Sugimoto, M. Tajima, T. Eguchi, I. Yamaga, T. Saitoh Stefan, K. Estreicher, Photoluminescence analysis of intra-grain defects in cast-grown polycrystalline silicon wafers. Mater Sci Semicond Process 9, 102 (2006)

    Article  Google Scholar 

  7. G.J. Qi, S. Zhang, T.T. Tang, J.F. Li, X.W. Sun, X.T. Zeng, Experimental study of aluminum-induced crystallization of amorphous silicon thin films. Surf Coat Technol 198, 300–303 (2005)

    Google Scholar 

  8. S.K. Estreicher, Hydrogen-related defects in crystalline semiconductors: a theorist’s perspective. Mater Sci Eng R14, 319 (1995)

    Article  Google Scholar 

  9. H. Sugimoto, M. Tajima, T. Eguchi, I. Yamaga, T. Saitoh Stefan, K Estreicher, Photoluminescence analysis of intra-grain defects in cast-grown polycrystalline silicon wafers. Mater Sci Semicond Process 9, 102–106 (2006)

    Google Scholar 

  10. P. Lengsfeld, H. Norbert, Nickel structural and electronic properties of laser-crystallized poly-Si. Semicond Semimet 75, 119 (2003)

    Article  Google Scholar 

  11. J. Schneider, J Non-cryst Solids 338–340, 127 (2004)

    Article  Google Scholar 

  12. P. Rozenak, B. Ladna, H.K. Birnbaum, SIMS study of deuterium distribution in chemically charged aluminum containing oxide layer defects and trapping sites. USA J Alloys Compd 415, 134 (2006)

    Article  Google Scholar 

  13. J.I.N. Hao, K.J. Weber, Weitang Li, A.W. Blakers, Introduction of atomic H into Si3N4/SiO2/Si stacks. Rare Met 25, 150 (2006)

    Article  Google Scholar 

  14. C. Ornaghi, G. Beaucarne, J. Poortmans, J. Nijs, R. Mertens, Aluminum-induced crystallization of amorphous silicon: influence of materials characteristics on the reaction. Thin Solid Films 451–452, 476 (2003)

    Google Scholar 

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Acknowledgments

The authors would like to thank Prof. Helmut Fritzsche for his efforts in the revision of this paper. This research was jointly supported by the NSFC Project of China (Project No. 61076006) and the Flat-Panel Display Special Project of China’s 863 Plan (Project No. 2008AA03A335).

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Correspondence to Juan Li.

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Li, J., Luo, C. & Kwok, H.S. The role of H-plasma on aluminum-induced crystallization of amorphous silicon. Appl. Phys. A 116, 851–855 (2014). https://doi.org/10.1007/s00339-013-8180-7

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  • DOI: https://doi.org/10.1007/s00339-013-8180-7

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