Abstract
CaBi4Ti4O15 (CBTi144) micro-plateaus were fabricated on Si wafers and Pt foils using a self-assembled monolayer (SAM) and a complex metal alkoxide solution. The micro-plateaus are delineated by metal masks, which are used for shadowing against the ultraviolet (UV) irradiation for decomposition of SAM to make the surface hydrophilic. The micro-plateaus crystallized to a ferroelectric phase with random orientation. The crystallization depended on the SAM-derived ultra thin layers at the surface of the substrates. The primitive PFM measurements without any top electrodes confirmed that the micro-plateaus exhibited the piezoresponse behaviors. The piezoelectric constant, d33, had some distribution, and the maximum d33 was confirmed as about 45 pm/V, which is identical to the d33 of the polar-axis oriented CBTi144 thin films.
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77.84.-s; 81.20.Fw; 77.65.-j
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Kato, K., Tanaka, K., Kayukawa, S. et al. Bottom-up fabrication and piezoelectric properties of CaBi4Ti4O15 micro-plateaus. Appl. Phys. A 88, 273–276 (2007). https://doi.org/10.1007/s00339-007-3985-x
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DOI: https://doi.org/10.1007/s00339-007-3985-x