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Poly(3,6-carbazolylmethylene)s with flourinated and nonflourinated tapered building side groups

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Summary

The syntheses of two different poly(3,6-carbazolymethylene)s are described. The polycondensation reaction proceeds without any crosslinking and the obtained polymers were characterised by elemental analysis 1H-NMR, 13C-NMR and 19F-NMR. DSC studies evidenced that one of the obtained polymers, i.e. poly[N-(3,4,5-tris(4-perflourooctylbutyl-1-yloxy)benzyl)carbazole] shows liquid crystalline behaviour and X-ray analysis pointed to a hexagonal columnar mesophase.

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Authors and Affiliations

  1. Institut für Makromolekulare Chemie „Hermann-Staudinger-Haus“, and Freiburger Materialforschungszentrum (FMF) der Universität, Stefan-Meier-Strasse 21, D-79104, Freiburg, Germany

    Michael Bolsinger & Hans Adam Schneider

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  1. Michael Bolsinger
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  2. Hans Adam Schneider
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Bolsinger, M., Schneider, H.A. Poly(3,6-carbazolylmethylene)s with flourinated and nonflourinated tapered building side groups. Polymer Bulletin 38, 117–124 (1997). https://doi.org/10.1007/s002890050027

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  • DOI: https://doi.org/10.1007/s002890050027

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