Summary
Welan, purified as its sodium salt from unpasteurised culture broth, was analyzed by dilute aqueous viscometry. Measurements in water and at low ionic strength were carried out to evaluate the change effect on intrinsic viscosity. The value of intrinsic viscosity at low ionic strength, determined by the isoionic dilution method, is close to that obtained at higher salt concentrations. A comparison is made among the stiffness parameters determined by different treatment of experimental data. The results agree with previous reports on the weak polyelectrolyte character and high stiffness of the welan chain.
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O’Neill MA, Selvendran RR, Morris JV (1983) Carbohydr Res 124: 123.
Jansson PE, Lindberg B, Sandford PA (1983) Carbohydr Res 124: 135.
Jansson PE, Lindberg B, Widmalm G, Sandford PA (1985) Carbohydr Res 139: 217.
O’Neill MA, Selvendran RR, Morris VJ, Eagles J (1986) Carbohydr Res 147: 295.
Jansson PE, Lindberg B, Lindberg J., Maekawa E, Sandford PA (1986) Carbohydr Res 156: 157.
Jansson PE, Kumar NS, Lindberg B (1985) 156: 165.
Chowdhury TA, Lindberg B, Lindquist U, Baird J (1987) Carbohydr Res 164: 117.
Kuo MS, Mort AJ (1986) Carbohydr Res 156:173.
Chandrasekaran R, Radha A, Thailambal VG (1992) Carbohydr Res 224: 1.
Stankowski JD, Zeller SG (1992) Carbohydr Res 224: 337.
Crescenzi V, Dentini M, Dea IMC (1987) Carbohydr Res 160: 283.
Grasdalen H, Smidsrod O (1987) Carbohydr Polym 7: 371.
Tako M, Sakae A, Nakamura S (1989) Agric Biol Chem 53(3): 771.
Shi X (1990) Thesis, Université Joseph Fourrier / Grenoble-France.
Sandford PA, Cotrell IW, Pettitt DJ (1984) Pure Appl Chem 56: 879.
Cairns P, Miles MJ, Morris VJ (1991) Carbohydr Polym 14: 367.
Lee EJ, Chandrasekaran R (1991) Carbohydr Res 214: 11.
Urbani R, Brant DA (1989) Carbohydr Polym 11: 169.
Campana S, Andrade C, Milas M, Rinaudo M (1990) Int J Biol Macromol 12: 379.
Campana S, Ganter J, Milas M, Rinaudo M (1991) Carbohydr Res 252: 183.
Hember MWN, Richardson RK, Morris ER (1994) Carbohydr Res 252: 209.
Talashek T, Brant DA (1989) Carbohydr Res 160: 303.
Tako M, Kiriaki M (1990) Agric Biol Chem 54: 3079.
Smidsrod O, Haug A (1971) Biopolymers 10: 1213.
Lopes L, Milas M, Rinaudo M (1994) Int J Biol Macromol 16(5): 253.
Rinaudo M, Milas M (1978) Biopolymers 17: 2663.
Frollini E, Reed WF, Milas M, Rianudo M (1995) Carbohydr.Polym. 27: 129.
Urbani R, Brandt DA (1989) Carbohydr.Polym. 11: 169.
Yamakawa H, Fujii M (1974) Macromolecules 7: 128.
Campana S.(1990) Thesis. Universidade de São Paulo-São Paulo/Brasil.
Goring DAI, Rezanowich A (1960) J.Coll.Sci. 15: 472.
Hodgson DF, Amis EJ (1993) Polyelectrolytes: Science and Technology. Marcel Dekker Inc. New York.
Davis RM, Russel WB (1987) Macromolecules 20: 518.
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Campana Filho, S.P., Regiani, A. & Frollini, E. On the stiffness of the welan chain. Polymer Bulletin 38, 81–85 (1997). https://doi.org/10.1007/s002890050022
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DOI: https://doi.org/10.1007/s002890050022