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Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core–shell structure and its film properties

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Abstract

Polyvinyl chloride (PVDC) coatings require excellent adhesion to substrates. Herein, a series of self-cross-linking silylated polyvinylidene chloride (PVMBV) emulsions with core–shell structure were prepared by seed emulsion polymerization using vinylidene chloride (VDC), methyl acrylate (MA), butyl acrylate (BA), and acrylic acid (AA) as the raw materials. Vinyltrimethoxysilane (VTMO) as the cross-linker was employed to enhance the adhesive properties. The effects of various VTMO contents on the properties of PVMBV were investigated. The results showed that the adhesion performance and thermal stability of PVMBV films were enhanced significantly with the increasing VTMO content. More interestingly, the introduction of a small quantity of VTMO enhanced the toughness of PVMBV films. The water contact angle increased could prove that the hydrophobicity of PVMBV films was improved. Further, it is important to that barrier properties of PVMBV films were effectively improved when VTMO content was no more than 3 wt%. This work provides potential applications in multifunctional barrier coatings, such as vapor barrier, water barrier, weathering, and corrosion protection.

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Acknowledgements

This research was supported by grants from the Science and Technology Department of Jilin Province (No. 20220203078SF).

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Authors and Affiliations

  1. Engineering Research Center of Synthetic Resin and Special Fiber, Ministry of Education, and School of Chemical Engineering, Changchun University of Technology, Changchun, 130012, China

    Jiawei Li, Chengyu Hong, Hao Zhang, Ye Han, Xin Li, Ruonan Sun & Chao Zhou

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  1. Jiawei Li
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  3. Hao Zhang
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Correspondence to Chao Zhou.

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Li, J., Hong, C., Zhang, H. et al. Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core–shell structure and its film properties. Polym. Bull. 81, 1651–1673 (2024). https://doi.org/10.1007/s00289-023-04779-5

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