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Adsorption of lead and tetracycline in aqueous solution by magnetic biomimetic bone composite

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Abstract

Heavy metals and antibiotics wastewater are toxic, harmful, and have become a serious threat to human health. Here, we designed and synthesized novel biomimetic bone composites PMCH and FS@PMCH for the removal of heavy metals and antibiotics from wastewater. The pseudo-second-order and Langmuir models fitted well with the kinetic and isothermal adsorption data, respectively. Under the optimal experimental conditions (the pH of 5 and the temperature of 298.15 K), the theoretical saturated adsorption capacities for Pb (II) and TC were 377.01 mg g−1 and 99.54 mg g−1. The XPS results confirmed that the adsorption mechanism of PMCH and FS@PMCH on Pb (II) and TC was mainly electrostatic interaction and H-bond, followed by ion exchange, complexation, and pore filling. Therefore, the FS@PMCH is a potential adsorbent and purifier for Pb (II)- and TC-contaminated water.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China [No.2019YFC1711300]; the Natural Science Foundation of Anhui Province [No.1808085QH289]; the Key Project of Natural Science Research of Anhui Universities [No. KJ2020A0432]; and the Quality Project of Higher Education in Anhui Province [No. 2020xfxm35].

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  1. Department of Medicinal Chemistry, School of Pharmacy, Anhui University of Chinese Medicine, Hefei, 230012, Anhui, People’s Republic of China

    Zheng Ji, Yansong Zhang, Haiyang Yan, Bo Wu, Bangchang Wei, Yanyan Guo, Huchuan Wang & Chuanrun Li

  2. Anhui Province Key Laboratory of Pharmaceutical Preparation Technology and Application, Anhui University of Chinese Medicine, Hefei, 230012, Anhui, People’s Republic of China

    Chuanrun Li

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Ji, Z., Zhang, Y., Yan, H. et al. Adsorption of lead and tetracycline in aqueous solution by magnetic biomimetic bone composite. Polym. Bull. 81, 297–315 (2024). https://doi.org/10.1007/s00289-023-04715-7

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