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The adsorption performance of magnetic gelatin nanofiber for Orange G removal

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Abstract

In this work, the usability of magnetic gelatin nanofiber (MGNF) for anionic dye removal was investigated in the aqueous solution. For this aim, the MGNF was prepared using the electrospinning technique with the addition of Fe3O4 nanopowders. After the characterization of MGNF with Fourier transform infrared spectroscopy, swelling test, scanning electron microscope, and energy-dispersive X-ray analysis, the adsorption performance of MGNF against the dye molecule, Orange G, was examined by changing the pH of the media, the dye concentration, and the ionic strength. The experimental results showed that the maximum adsorbed amount of Orange G was found as 15.6 mg/g at pH 3 value and the Orange G adsorption behavior was endothermic, physical, and suited to the Langmuir adsorption isotherm model. The adsorption kinetic of Orange G was evaluated with the pseudo-first-order, the pseudo-second-order, and the Elovich kinetic models and the pseudo-second-order model results fitted the experimental findings as compared to the other models. The affordable magnetic adsorbent was capable of maintaining its stability after five consecutive adsorption, desorption, and regeneration cycles without significant loss of adsorption capacity.

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References

  1. Osagie C, Othmani A, Ghosh S, Malloum A, Esfahani KZ, Ahmadi S (2021) Dyes adsorption from aqueous media through the nanotechnology: A review. J Mater Res Technol 14:2195–2218

    CAS  Google Scholar 

  2. Gusain D, Dubey S, Upadhyay SN, Weng CH, Sharma YC (2016) Studies on optimization of removal of orange G from aqueous solutions by a novel nano adsorbent, nano zirconia. Ind Eng Chem Res 33:42–50

    CAS  Google Scholar 

  3. Dev VV, Wilson B, Nair KK, Antony S, Krishnan KA (2021) Response surface modeling of Orange-G adsorption onto surface tuned ragi husk. Colloids Interface Sci Commun 41:100363

    CAS  Google Scholar 

  4. Mondal MK, Singh S, Umareddy M, Dasgupta B (2010) Removal of Orange G from aqueous solution by hematite: isotherm and mass transfer studies. Korean J Chem Eng 27(6):1811–1815

    CAS  Google Scholar 

  5. Chung KT (2016) Azo dyes and human health: a review. J Environ Sci Health C Toxicol Carcinog 34(4):233–261

    CAS  Google Scholar 

  6. Yang W, Deng Z, Wang Y, Ma L, Zhou K, Liu L, Wei Q (2022) Porous boron-doped diamond for efficient electrocatalytic elimination of azo dye Orange G. Sep Purif Technol 293:121100

    CAS  Google Scholar 

  7. Katheresan V, Kansedo J, Lau SY (2018) Efficiency of various recent wastewater dye removal methods: a review. J Environ Chem Eng 6(4):4776–4697

    Google Scholar 

  8. Tang L, Yu J, Pang Y et al (2018) Sustainable efficient adsorbent: Alkali-acid modified magnetic biochar derived from sewage sludge for aqueous organic contaminant removal. Chem Eng J 336:160–169

    CAS  Google Scholar 

  9. Pandian CJ, Palanivel R, Dhananasekaran S (2015) Green synthesis of nickel nanoparticles using Ocimum sanctum and their application in dye and pollutant adsorption. Chin J Chem Eng 23(8):1307–1315

    CAS  Google Scholar 

  10. Ramesh AV, Devi DR, Botsa SM, Basavaiah K (2018) Facile green synthesis of Fe3O4 nanoparticles using aqueous leaf extract of Zanthoxylum armatum DC for efficient adsorption of methylene blue. J Asian Ceram Soc 6(2):145–155

    Google Scholar 

  11. Salam MA, Kosa SA, Beladi A (2017) Application of nanoclay for the adsorptive removal of Orange G dye from aqueous solution. J Mol Liq 241:469–477

    Google Scholar 

  12. Kumar S, Bhanjana G, Jangra K, Dilbaghi N, Umar A (2014) Utilization of carbon nanotubes for the removal of rhodamine B dye from aqueous solutions. J Nanosci Nanotechnol 14(6):4331–4336

    CAS  Google Scholar 

  13. Jawad AH, Abdulhameed AS et al (2022) Cross-linked chitosan-glyoxal/kaolin clay composite: parametric optimization for color removal and cod reduction of remazol brilliant blue r dye. J Polym Environ 30:164–178

    CAS  Google Scholar 

  14. Cheng J, Zhan C, Wu J et al (2020) Highly efficient removal of methylene blue dye from an aqueous solution using cellulose acetate nanofibrous membranes modified by polydopamine. ACS Omega 5(10):5489–5400

    Google Scholar 

  15. Thamer BM, El-Hamshay H, Al-Deyab SS, El-Newehy MH (2019) Functionalized electrospun carbon nanofibers for removal of cationic dye. Arab J Chem 12:747–759

    CAS  Google Scholar 

  16. Jawad AH, Selvasembian R, Abdulhameed AS, Hassan SSA, Alothman ZA, Wilson LD (2022) Process optimization and adsorptive mechanism for reactive blue 19 dye by magnetic crosslinked chitosan/MgO/Fe3O4 biocomposite. J Polym Environ 30:2759–2773

    CAS  Google Scholar 

  17. Jawad AH, Hameed BH, Abulhameed AS (2022) Synthesis of biohybrid magnetic chitosan-polyvinyl alcohol/MgO nanocomposite blend for remazol brilliant blue R dye adsorption: solo and collective parametric optimization. Polym Bull. https://doi.org/10.1007/s00289-022-04294-z

    Article  Google Scholar 

  18. Reddy DHK, Lee SM (2013) Application of magnetic chitosan composites for the removal of toxic metal and dyes from aqueous solutions. Adv Colloid Interface Sci 201:68–93

    Google Scholar 

  19. Makarchuk OV, Dotsova TA, Astrelin IM (2016) Magnetic nanocomposites as efficient sorption materials for removing dyes from aqueous solution. Nanoscale Res Lett 11(161):1–7

    CAS  Google Scholar 

  20. Jawad AH, Abulhammed AS, Selvasembian R, Alothman ZA, Wilson LD (2022) Magnetic biohybrid chitosan-ethylene glycol diglycidyl ether/ magnesium oxide/Fe3O4 nanocomposite for textile dye removal: Box-Behnken design optimization and mechanism study. J Polym Res 29(207):1–15

    Google Scholar 

  21. Samandari SS, Samandar SS, Yekta HJ, Mohseni M (2017) Adsorption of anionic and cationic dyes from aqueous solution using gelatin-based magnetic nanocomposite beads comprising carboxylic acid functionalized carbon nanotube. Chem Eng J 308:1133–1144

    Google Scholar 

  22. Rigueto CVT, Nazari MT, Massuda LÂ, Ostwald BEP, Piccin JS, Dettmer A (2021) Production and environmental applications of gelatin-based composite adsorbents for contaminants removal: a review. Environ Chem Lett 19:2465–2486

    CAS  Google Scholar 

  23. Mir AA, Amooey AA, Ghasem S (2018) Adsorption of direct yellow 12 from aqueous solutions by an iron oxide-gelatin nanoadsorbent; kinetic, isotherm and mechanism analysis. J Clean Prod 170:570–580

    CAS  Google Scholar 

  24. Li W, Ma Q, Bai Y, Xu D, Wu M, Ma H (2018) Facile fabrication of gelatin/bentonite composite beads for tunable removal of anionic and cationic dyes. Chem Eng Res Des 134:336–346

    CAS  Google Scholar 

  25. Ma Y, Qi P, Ju J et al (2019) Gelatin/alginate composite nanofiber membranes for effective and even adsorption of cationic dyes. Compos B Eng 162:671–677

    CAS  Google Scholar 

  26. Chen Y, Ma Y, Lu W, Guo Y, Zhu Y, Lu J, Sonh Y (2018) Environmentally friendly gelatin/β-cyclodextrin composite fiber adsorbents for the efficient removal of dyes from wastewater. Macromolecules 23(2473):1–17

    Google Scholar 

  27. Luo M, Huang C, Chen F, Chen C, Li H (2021) Removal of aqueous cr(VI) using magnetic-gelatin supported on Brassica-straw biochar. J Dispers Sci Technol 42(11):1710–1722

    CAS  Google Scholar 

  28. Dolgormaa A, Lv CJ, Li Y, Yang J, Yang JX, Chen P, Wang HP, Huang J (2018) Adsorption of cu(II) and zn(II) ions from aqueous solution by gel/pva-modified super-paramagnetic iron oxide nanoparticles. Molecules 23(2982):1–15

    Google Scholar 

  29. Gulsun T, Inal M, Akdag Y, Izat N, Oner L, Sahin S (2022) The development and characterization of electrospun gelatin nanofibers containing indomethacin and curcumin for accelerated wound healing. J Drug Deliv Sci Technol 67:103000

    CAS  Google Scholar 

  30. Ko JH, Yin HY, An J et al (2010) Characterization cross-linked gelatin nanofibers through electrospinning. Macromol Res 16(2):137–143

    Google Scholar 

  31. Cebi N, Durak MZ, Toker OS, Sagdıc O, Arici M (2016) An evaluation of Fourier transforms infrared spectroscopy method for the classification and discrimination of bovine, porcine and fish gelatins. Food Chem 190:1109–1115

    CAS  Google Scholar 

  32. Samal KS, Goranov V, Dask M et al (2015) Multilayered magnetic gelatin membrane scaffolds. ACS Appl Mater Interfaces 7:23098–23109

    CAS  Google Scholar 

  33. Wang T, Zhao P, Lu N, Chen H, Zhang C, Hou X (2016) Facile fabrication of Fe3O4/MIL-101(Cr) for effective removal of acid red 1 and Orange G from aqueous solution. Chem Eng J 295:403–413

    CAS  Google Scholar 

  34. Cai Mi SuJ, Zhu Y et al (2016) Decolorization of azo dyes Orange G using hydrodynamic cavitation coupled with heterogeneous Fenton process. Ultrason Sonochem 128:302–310

    Google Scholar 

  35. Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. Chem Eng J 156(1):2–10

    CAS  Google Scholar 

  36. Gündüz F, Bayrak B (2017) Biosorption of malachite green from an aqueous solution using pomegranate peel: equilibrium modeling, kinetic and thermodynamic studies. J Mol Liq 243:790–798

    Google Scholar 

  37. Dada AO, Olakan AP, Olatunya AM, Dada O (2012) Langmuir, freundlich, temkin and dubinin-radushkevich isotherms studies of equilibrium sorption of zn2+ unto phosphoric acid modified rice husk. J Appl Chem 3:38–45

    Google Scholar 

  38. Yılmaz E, Özgür E, Bereli N, Türkmen D, Denizli A (2017) Plastic antibody based surface plasmon resonance nanosensors for selective atrazine detection. Mater Sci Eng C 73:603–610

    Google Scholar 

  39. Ahmad MA, Ahmad N, Bello OS (2015) Modified durian seed as adsorbent for the removal of methyl red dye from aqueous solutions. Appl Water Sci 5:407–423

    CAS  Google Scholar 

  40. Cui L, Xiong Z, Guo Y, Liu Y, Zhao J, Zhang C, Zhu P (2015) Fabrication of interpenetrating polymer network chitosan/gelatin porous materials and study on dye adsorption properties. Carbohydr Polym 132:330–337

    CAS  Google Scholar 

  41. Hsini A, Esseleri A, Aarab N et al (2020) Elaboration of novel polyaniline@Almond shell biocomposite for effective removal of hexavalent chromium ions and Orange G dye from aqueous solutions. Environ Sci Pollut Res 27:15245–15258

    CAS  Google Scholar 

  42. Arulkumar M, Sathishkumar P, Palvannan T (2011) Optimization of Orange G dye adsorption by activated carbon of Thespesia populnea pods using response surface methodology. J Hazard Mater 186:827–834

    CAS  Google Scholar 

  43. Banerjee S, Dubey S, Gautam RK, Chattopadhyaya MC, Sharma Y (2019) Adsorption characteristics of alumina nanoparticles for the removal of hazardous dye, Orange G from aqueous solutions. Arab J Chem 12:5339–5354

    CAS  Google Scholar 

  44. Sutirman ZA, Sanagi MM, Karim KJA, Naim AA, Ibrahim WAW (2019) Enhanced removal of Orange G from aqueous solutions by modified chitosan beads: performance and mechanism. Int J Biol Macromol 133:1260–1267

    CAS  Google Scholar 

  45. Singh J, UMA, Banerjee S, Gusain D, Sharma YC (2011) Equilibrium modelling and thermodynamics of removal of orange g from its aqueous solutions. J Appl Phytotechnol Environ Sanit 6(3):317–326

    CAS  Google Scholar 

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Acknowledgements

I would like to thank Prof. Dr. Adil Denizli for his kind help and support.

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  1. Medical Laboratory Program, Vocational School of Health Services, Aksaray University, Aksaray, Turkey

    Aykut Arif Topçu

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Topçu, A.A. The adsorption performance of magnetic gelatin nanofiber for Orange G removal. Polym. Bull. 80, 1017–1029 (2023). https://doi.org/10.1007/s00289-022-04464-z

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