Abstract
A series of UV-curable waterborne fluorinated polyurethane (UV-WFPU) were prepared successfully based on novel fluorinated side chain extender (F-TMP). The structure of F-TMP and particle size of UV-WFPU dispersions, contact angle (CA) and surface free energy, morphology, and damping property of UV-WFPU films were characterized through Fourier transform infrared spectroscopy, nanoparticle size analysis, contact angle test, scanning electron microscope and dynamic mechanical analysis (DMA), respectively. The results indicated that UV-WFPU dispersions had a particle size between 49.01 and 61.52 nm. The latex particle size and tan δ value of UV-WFPU films increased with the increase in F-TMP contents. The studies of surface properties confirmed that UV-WFPU films based on F-TMP had outstanding hydrophobicity properties. The highest CA of water and lowest surface free energy of UV-WFPU films reached 96.2° and 21.17 mJ/m2, respectively. Meanwhile, the DMA results showed UV-WFPU films possessed great damping property which had the broad temperature range enhanced by F-TMP, with a maximum value at 190.4 °C. The results of mechanical properties showed that the addition of fluorine increased in the tensile strength of the film. And these films have potential application values in the technical fields of damping, anti-corrosion and dust prevention.
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References
Li Y, Yang Z, Qiu H, Dai Y, Zheng Q, Li J, Yang J (2014) Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings. J Mater Chem A 2(34):14139–14145
Bao L, Fan H, Chen Y, Yan J, Yang T, Guo Y (2016) Effect of surface free energy and wettability on the adhesion property of waterborne polyurethane adhesive. RSC Adv 6(101):99346–99352
Garcia-Pacios V, Costa V, Colera M, Miguel Martin-Martinez J (2011) Waterborne polyurethane dispersions obtained with polycarbonate of hexanediol intended for use as coatings. Prog Org Coat 71(2):136–146
Fu C, Zheng Z, Yang Z, Chen Y, Shen L (2014) A fully bio-based waterborne polyurethane dispersion from vegetable oils: from synthesis of precursors by thiol-ene reaction to study of final material. Prog Org Coat 77(1):53–60
Mao H, Qiang S, Xu Y, Wang C (2017) Synthesis of polymeric dyes based on UV curable multifunctional waterborne polyurethane for textile coating. New J Chem 41(2):619–627
Baradie B, Shoichet MS (2005) Novel fluoro-terpolymers for coatings applications. Macromolecules 38(13):5560–5568
Park IJ, Lee SB, Choi CK (1998) Surface properties of the fluorine-containing graft copolymer of poly((perfluoroalkyl)ethyl methacrylate)-G-poly(methyl methacrylate). Macromolecules 31(21):7555–7558
Signori F, Lazzari M, Castelvetro V, Chiantore O (2006) Copolymers of isopropenyl alkyl ethers with fluorinated acrylates and fluoroacrylates: influence of fluorine on their thermal, photochemical, and hydrolytic stability. Macromolecules 39(5):1749–1758
Valade D, Boyer C, Ameduri B, Boutevin B (2006) Poly(vinylidene fluoride)-B-poly(styrene) block copolymers by iodine transfer polymerization (ITP): synthesis, characterization, and kinetics of ITP. Macromolecules 39(25):8639–8651
Yi L, Meng X, Tian X, Zhou W, Chen R (2014) Wettability of electrospun films of microphase-separated block copolymers with 3,3,3-trifluoropropyl substituted siloxane segments. J Phys Chem C 118(46):26671–26682
Shuaishuai Huang S, Liu G, Hu H (2018) Water-based anti-smudge NP-GLIDE polyurethane coatings. Chem Eng J 351:210–220
Rabnawaz M, Liu G (2015) Graft-copolymer-based approach to clear, durable, and anti-smudge polyurethane coatings. Angew Chem Int Ed 54(22):6516–6520
Rabnawaz M, Liu G, Hu H (2015) Fluorine-free anti-smudge polyurethane coatings. Angew Chem Int Ed 54(43):12722–12727
Wen J, Sun Z, Xiang J, Fan H, Chen Y, Yan J (2019) Preparation and characteristics of waterborne polyurethane with various lengths of fluorinated side chains. Appl Surf Sci 494:610–618
Zhao J, Zhou T, Zhang J, Chen H, Yuan C, Zhang W, Zhang A (2014) Synthesis of a waterborne polyurethane-fluorinated emulsion and its hydrophobic properties of coating films. Ind Eng Chem Res 53(49):19257–19264
Yu LZ, Wang YY, Qiu FX, Xu JC, Xu BB, Jiang Y, Yang DY, Li PL (2013) Preparation, characterisation and properties of waterborne fluorinated polyurethane acrylate/SiO2 hybrid. Plast, Rubber Compos 42(9):385–392
Zhang FA, Yu CL (2007) Application of a silicone-modified acrylic emulsion in two-component waterborne polyurethane coatings. J Coat Technol Res 4(3):289–294
Turri S, Levi M, Trombetta T (2004) Waterborne anionomeric polyurethane-ureas from functionalized fluorovolvethers. J Appl Polym Sci 93(1):136–144
Tonelli C, Ajroldi G (2003) New fluoro-modified thermoplastic polyurethanes. J Appl Polym Sci 87(14):2279–2294
Turri S, Levi M, Trombetta T (2004) Process design of fluorinated polyurethane-urea anionomer aqueous dispersions. Macromol Symp 218:29–38
Kim YS, Lee JS, Ji Q, McGrath JE (2002) Surface properties of fluorinated oxetane polyol modified polyurethane block copolymers. Polymer 43(25):7161–7170
Jiang M, Zhao XL, Ding XB, Zheng ZH, Peng YX (2005) A novel approach to fluorinated polyurethane by macromonomer copolymerization. Eur Polym J 41(8):1798–1803
Li GH, Li XR, Shen YD, Ren QH (2006) Effect of hydrophilic monomer on the surface properties of cationic polyurethane-fluorinated acrylate hybrid dispersions. J Appl Polym Sci 99(5):2721–2725
Jiang W, Huang Y, Gu GT, Meng W, Qing F (2006) A novel waterborne polyurethane containing short fluoroalkyl chains: synthesis, characterization and its application on cotton fabrics surface. Appl Surf Sci 253(4):2304–2309
Song M, Hourston DJ, Schafer FU (2001) Correlation between mechanical damping and interphase content in interpenetrating polymer networks. J Appl Polym Sci 81(10):2439–2442
Huang GS, Li Q, Jiang LX (2002) Structure and damping properties of polydimethylsiloxane and polymethacrylate sequential interpenetrating polymer networks. J Appl Polym Sci 85(3):545–551
Trakulsujaritchok T, Hourston DJ (2006) Damping characteristics and mechanical properties of silica filled PUR/PEMA simultaneous interpenetrating polymer networks. Eur Polym J 42(11):2968–2976
Guo X, Cheng Q, Yu G, Wang H, Tian Z, Shi Z, Cui Z, Zhu S (2020) The functions of hydrophobic elastic polyurethane combined with an antibacterial triclosan derivative in the dentin restoration interface. J. Mech Behav Biomed 102:103471
Zhang L, Li H, Lai X, Wu W, Zeng X (2018) Hindered phenol functionalized graphene oxide for natural rubber. Mater Lett 210:239–242
Nguyen LT, Hillewaere XKD, Teixeira RFA, van den Berg O, Du Prez FE (2015) Efficient microencapsulation of a liquid isocyanate with in situ shell functionalization. Polym Chem-Uk 6(7):1159–1170
Yang W, Cheng X, Wang H, Liu Y, Du Z (2017) Surface and mechanical properties of waterborne polyurethane films reinforced by hydroxyl-terminated poly(fluoroalkyl methacrylates). Polymer 133:68–77
Fu H, Yan C, Zhou W, Huang H (2014) Nano-SiO2/fluorinated waterborne polyurethane nanocomposite adhesive for laminated films. J Ind Eng Chem 20(4):1623–1632
Fowkes FM (1964) Attractive forces at interfaces. Ind Eng Chem 56(12):40
Xu W, An Q, Hao L, Zhang D, Zhang M (2013) Synthesis and characterization of self-crosslinking fluorinated polyacrylate soap-free latices with core-shell structure. Appl Surf Sci 268:373–380
Xu W, An Q, Hao L, Huang L (2012) Synthesis, film morphology, and performance of cationic fluorinated polyacrylate emulsion with core-shell structure. J Appl Polym Sci 125(3):2376–2383
Shi Y, Yan H, Wen R, Wan L (2017) Direct visualization of nucleation and growth processes of solid electrolyte interphase film using in situ atomic force microscopy. ACS Appl Mater Interfaces 9(26):22063–22067
Wang Q, Aubry C, Chen Y, Song H, Zou L (2017) Insights on tuning the nanostructure of rGO laminate membranes for low pressure osmosis process. ACS Appl Mater Interfaces 9(27):22509–22517
Hao L, An Q, Xu W, Huang L (2012) Synthesis, film morphology and hydrophobicity of novel fluorinated polyacrylate emulsion and solution on silicon wafer. Colloid Surf A 396:83–89
Xu W, Zhao W, Hao L, Wang S, Pei M, Wang X (2018) Synthesis and characterization of novel fluoroalkyl-terminated hyperbranched polyurethane latex. Appl Surf Sci 436:1104–1112
Shi X, Shi H, Wu H, Shen H, Cao P (2018) Synthesis and properties of novel fluorinated polyurethane based on fluorinated gemini diol. Polym Adv Technol 29(7):1939–1952
Urayama K, Miki T, Takigawa T, Kohjiya S (2004) Damping elastomer based on model irregular networks of end-linked poly(dimethylsiloxane). Chem Mater 16(1):173–178
Zhu J, Zhao X, Liu L, Song M, Wu S (2018) Quantitative relationships between intermolecular interaction and damping parameters of irganox-1035/NBR hybrids: a combination of experiments, molecular dynamics simulations, and linear regression analyses. J Appl Polym Sci 135(17):46202
Deng YJ, Zhou C, Zhang MY, Zhang HX (2018) Effects of the reagent ratio on the properties of waterborne polyurethanes-acrylate for application in damping coating. Prog Org Coat 122:239–247
Shi G, Yin X, Wu G (2018) Thermodynamic phase analysis of acrylic polymer/hindered phenol hybrids: effects of hydrogen bonding strength. Polymer 153:317–324
Acknowledgments
This study was supported by the Association for the Promotion of Science/Education Foundation Program of Shanghai (LM201874, LM201626) and the Science and Technology Innovation Action Plan Project of Shanghai (15520503400).
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Shan, C., Ning, C., Lou, J. et al. Design and preparation of UV-curable waterborne polyurethane based on novel fluorinated chain extender. Polym. Bull. 78, 2067–2083 (2021). https://doi.org/10.1007/s00289-020-03202-7
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DOI: https://doi.org/10.1007/s00289-020-03202-7