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Preparation and coating properties of alkyd polyol-based autoxidizable waterborne polyurethane dispersions with high fatty acid content, long storage stability, and low viscosity

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Abstract

In order to increase the concentrations of bio-based alkyd polyols (or fatty acids) in self-crosslinking polyurethane dispersions, herein, a series of novel alkyd polyol-based autoxidizable waterborne polyurethane dispersions (AWPUDs) with different fatty acid contents, long storage stability, and low viscosity were successfully prepared by adding dimethylol propionic acid (DMPA) self-emulsifier in the late stage of their synthesis. They and their corresponding curing films were characterized by Fourier transform infrared spectroscopy (FTIR), particle size analysis, rheology measurement, storage stability evaluation, thermogravimetric analysis, dynamic thermomechanical analysis (DMA), etc. The results showed that the addition process of DMPA played a critical role for the excellent features of AWPUDs. Additionally, the crosslinking density, gel contents, and water contact angles of AWPUD films increased with the enlarged fatty acid contents, whereas their water uptake capability decreased. Moreover, a series of AWPUD coatings were prepared, and their properties like drying times, hardness development, pencil hardness, adhesion capability, impact resistance, flexibility, and water resistances were all effectively improved with the increased fatty acid contents, significantly superior to those of waterborne alkyd coatings and waterborne polyurethane coatings without fatty acids.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 51963010) and the Research Fund of Jiangxi Provincial Department of Education (No. GJJ211126).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang, 330013, Jiangxi, People’s Republic of China

    Zecheng Lin, Qingyuan Zeng, Yucheng Zhang, Yongbo Ding, Shuai Chen & Liang Shen

  2. Jiangxi Provincial Engineering Research Center for Waterborne Coatings, Nanchang, 330013, Jiangxi, People’s Republic of China

    Yongbo Ding, Shuai Chen & Liang Shen

  3. Jiangxi Key Laboratory of Organic Chemistry, Nanchang, 330013, Jiangxi, People’s Republic of China

    Yongluo Qiao

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  1. Zecheng Lin
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Contributions

YB Ding and L Shen supervised and designed this research. ZC Lin, QY Zeng and YC Zhang did the experiment. YB Ding and ZC Lin collected and analyzed the data. YB Ding, ZC Lin, and L Shen interpreted the results and wrote the manuscript. S Chen and QY Luo discussed and revised the manuscript. All authors declare that they have no competing financial interests and gave final approval for publication.

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Lin, Z., Zeng, Q., Zhang, Y. et al. Preparation and coating properties of alkyd polyol-based autoxidizable waterborne polyurethane dispersions with high fatty acid content, long storage stability, and low viscosity. J Coat Technol Res (2024). https://doi.org/10.1007/s11998-024-00928-1

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