Abstract
The reduction in the torque consumed during the preparation of thermoplastic starch to the minimum value was achieved by reaching equilibrium state of the premixing suspension of starch–glycerol–water before melt-blending process. The study was conducted on two kinds of cereal starches, wheat and corn. Microscope, FT-IR and XRD analytical methods were employed to follow the change in starch structure during soaking time (aging time) until reaching the equilibrium. Microscope photomicrographs exhibited a relative and partial swelling of the starch granules simultaneously with progressive breaking down of the granules with soaking time until 10 days. Thereafter, no additional breaking down was observed in starch granules. FT-IR analysis showed that shifting of –OH group, which refers to the formation of H-bonds between starch and plasticizers, started from the first day of soaking and continuously increased until the suspension reached the equilibrium state after 10 days of aging. XRD analysis shows that the A-type, which cereals starch characterized by, still be conservative during the soaking. Nevertheless, the absence of some peaks and the progressive growth of new other peaks, which refer to the VH-type and B-type, were recognized. As microscope and FT-IR, XRD results show, after 10 days of soaking, no measurable change happened in diffractograms that means the equilibrium state was reached. This study demonstrated that higher amylose-content wheat starch compared with lower amylose-content corn starch showed greater torque requirement to get plasticized, formed stronger H-bonds with plasticizers and presented higher crystallization degree when soaking in plasticizers mixture.
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11 March 2020
A Correction to this paper has been published: https://doi.org/10.1007/s00289-020-03159-7
References
Okechukwu PE, Rao MA (1995) Influence of granule size on viscosity of corn starch suspension. J Texture Stud 26(5):501–516
Jobling S (2004) Improving starch for food and industrial applications. Curr Opin Plant Biol 7(2):210–218
Yoon S-Y, Deng Y (2006) Clay–starch composites and their application in papermaking. J Appl Polym Sci 100(2):1032–1038
Gregorová E, Pabst W, Bohačenko I (2006) Characterization of different starch types for their application in ceramic processing. J Eur Ceram Soc 26(8):1301–1309
Kaseem M, Hamad K, Deri F (2012) Thermoplastic starch blends. A review of recent works. Polym Sci Ser A 54(2):165–176
van Soest Jeroen JG, Hulleman SHD, de Wit D, Vliegenthart JFG (1996) Crystallinity in starch bioplastics. Ind Crops Prod 5(1):11–22
Su B, Xie F, Li M, Corrigan PA, Yu L, Li X, Chen L (2009) Extrusion processing of starch film. Int J Food Eng 5(1):14
González-Seligra P, Guz L, Ochoa-Yepes O, Goyanes S, Famá L (2017) Influence of extrusion process conditions on starch film morphology. LWT 84:520–528
Willett JL, Jasberg BK, Swanson CL (1995) Rheology of thermoplastic starch. Effects of temperature, moisture content, and additives on melt viscosity. Polym Eng Sci 35(2):202–210
Kaseem M, Hamad K, Deri F (2013) Slit die rheology of thermoplastic starch during extrusion process. Int J Plast Technol 17(1):51–60
Liu P, Xie F, Li M, Liu X, Yu L, Halley PJ, Chen L (2011) Phase transitions of maize starches with different amylose contents in glycerol–water systems. Carbohydr Polym 85(1):180–187
Smits ALM, Kruiskamp PH, van Soest JJG, Vliegenthart JFG (2003) Interaction between dry starch and plasticisers glycerol or ethylene glycol, measured by differential scanning calorimetry and solid state NMR spectroscopy. Carbohydr Polym 53(4):409–416
Perry PA, Donald AM (2000) The role of plasticization in starch granule assembly. Biomacromolecules 1(3):424–432
Duan DX, Donner E, Liu Q, Smith DC, Ravenelle F (2012) Potentiometric titration for determination of amylose content of starch—a comparison with colorimetric method. Food Chem 130(4):1142–1145
Thomas JS (1964) Iodimetric determination of amylose potentiometric titration: standard method. Methods Carbohydr Chem Starch 4:157–160
Altayan MM, Al Darouich T, Karabet F (2017) On the plasticization process of potato starch: preparation and characterization. Food Biophys 12:397–403
Jane J-L, Kasemsuwan T, Leas S, Zobel H, Robyt JF (1994) Anthology of starch granule morphology by scanning electron microscopy. Starch/Stärke 46(4):121–129
Alvarez-Ramírez J, Vernon-Carter EJ, Carrillo-Navas H, Meraz M (2018) Impact of soaking time at room temperature on the physicochemical properties of maize and potato starch granules. Starch/Stärke 35:215
Démé F, Peuvrel-Disdier E, Vergnes B (2015) Loss of crystalline structure and swelling kinetics of maize starch and flour granules in glycerol excess. The role of the envelope structure. Ind Crops Prod 70:149–157
El-Sheikh MA (2017) New technique in starch nanoparticles synthesis. Carbohydr Polym 176:214–219
Wang C-z, Li F-y, Wang L-m, Li J-f, Guo A-f, Zhang C-w, Liu P (2015) Research on thermoplastic starch and different fiber reinforced biomass composites. RSC Adv 5(62):49824–49830
Ahmed J, Tiwari BK, Imam SH, Rao MA (2016) Starch-based polymeric materials and nanocomposites. Chemistry, processing, and applications. CRC Press, Boca Raton
Teixeira EM, de Campos A, Marconcini JM, Bondancia TJ, Wood D, Klamczynski A et al (2014) Starch/fiber/poly(lactic acid) foam and compressed foam composites. RSC Adv 4(13):6616–6623
Van Soest JJG, Essers P (1997) Influence of amylose-amylopectin ratio on properties of extruded starch plastic sheets. J Macromol Sci Part A 34(9):1665–1689
Xie F, Luckman P, Milne J, McDonald L, Young C, Tu CY et al (2014) Thermoplastic starch. J Renew Mater 2(2):95–106
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Altayan, M.M., Ayaso, M., Al Darouich, T. et al. The effect of increasing soaking time on the properties of premixing starch–glycerol–water suspension before melt-blending process: comparative study on the behavior of wheat and corn starches. Polym. Bull. 77, 1695–1706 (2020). https://doi.org/10.1007/s00289-019-02826-8
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DOI: https://doi.org/10.1007/s00289-019-02826-8