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Hybrid nanocomposite based on poly-3-amine-7-methylamine-2-methylphenazine and single-walled carbon nanotubes

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Abstract

A polymer–carbon hybrid nanocomposite based on thermostable electroactive poly-3-amine-7-methylamine-2-methylphenazine (PAMMP) and single-walled carbon nanotubes (SWCNT) was synthesized for the first time via in situ oxidative polymerization. The SWCNT/PAMMP nanocomposite material was characterized by means of Fourier transform infrared spectroscopy, solid-state high-resolution magic angle spinning 13C NMR spectroscopy, X-ray diffraction, transmission and field emission scanning electron microscopy, differential scanning calorimetry and thermogravimetric analysis. The chemical structure of the synthesized SWCNT/PAMMP nanocomposite, as well as its thermal and electrical properties under different synthesis conditions, was studied.

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Acknowledgements

This work was done as part of TIPS RAS State Plan. The equipment from the collective exploitation center “New petrochemical processes, polymer composites and adhesives” was used.

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Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, Moscow, Russia, 119991

    Sveta Zhiraslanovna Ozkan & Galina Petrovna Karpacheva

  2. Department of Chemistry, Lomonosov Moscow State University, 1-3 Leninskie Gory, Moscow, Russia, 119991

    Yurii Gennadievich Kolyagin

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  1. Sveta Zhiraslanovna Ozkan
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  2. Galina Petrovna Karpacheva
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  3. Yurii Gennadievich Kolyagin
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Correspondence to Sveta Zhiraslanovna Ozkan.

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Ozkan, S.Z., Karpacheva, G.P. & Kolyagin, Y.G. Hybrid nanocomposite based on poly-3-amine-7-methylamine-2-methylphenazine and single-walled carbon nanotubes. Polym. Bull. 76, 5285–5300 (2019). https://doi.org/10.1007/s00289-018-2644-z

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  • DOI: https://doi.org/10.1007/s00289-018-2644-z

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