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Synthesis and Characterization of Poly(dimethylsilylene ethynylenephenyleneethynylene) Terminated with Phenylacetylene

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Summary

A novel easily processable resin, poly(dimethylsilylene ethynylenephenyleneethynylene) [-Si(CH3)2-C≡C-C6H4-C≡C-]n terminated with phenylacetylene, was developed. And the properties of the resulting resin were investigated. The resin was a viscous liquid and soluble in a variety of solvents. The cured resin showed high heat-resistant stability and high char yield. The cured resin was sintered at 1450 °C and obtained sintered product was analyzed by FTIR, SEM and X-ray diffraction techniques and the results showed β-SiC were formed in the product.

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Authors and Affiliations

  1. Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science & Technology, 130 Meilong Road, Shanghai, 200237, P.R. China

    Fan Wang, Jian Zhang, Jianxiang Huang, Hao Yan, Farong Huang & Lei Du

Authors
  1. Fan Wang
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  2. Jian Zhang
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  3. Jianxiang Huang
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  4. Hao Yan
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  5. Farong Huang
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  6. Lei Du
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Correspondence to Farong Huang.

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Wang, F., Zhang, J., Huang, J. et al. Synthesis and Characterization of Poly(dimethylsilylene ethynylenephenyleneethynylene) Terminated with Phenylacetylene. Polym. Bull. 56, 19–26 (2006). https://doi.org/10.1007/s00289-005-0464-4

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  • DOI: https://doi.org/10.1007/s00289-005-0464-4

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