Summary
This paper presents a methodology of encapsulation of TiO2 (Titanium dioxide) by emulsion polymerization on the proposal to modify the physical-chemical properties of the pigment surface. In the proposed methodology the TiO2 was previously modified by isopropoxy-titanium-tri-isostearate, before being encapsulated by emulsion polymerization using Methyl Methacrylate as monomer.
The effects of the polymerization process, type of initiator and monomer concentration in the efficiency of encapsulation were studied. The encapsulated pigment was characterized by Thermogravimetric Analysis (TGA), Light Scattering (LS) and Transmission Electron Microscopy (TEM).
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References
Mark J E, Lee C Y C, Bianconi P A, (1995) Americam Chemical Society Symposium Series 585 Washington
Caris C H M, vaan Elven L P M, van Herk A M, German A L, (1988) 19th FATIPEC Conference book 3: 341-354
Janssen R Q F, Phd thesis (1995) Eindhoven University of Technology Eindhoven The Netherlands
Caris C H M, Kuijpers R P M, van Herk A M, German A L, (1990) Makramol Chem Makromol Symp 35/36: 335-348
Haga Y, Watanabe T, Yosomiya R, (1991) Angew Makromol Chem 189:23-24
Caris C H M, Phd thesis (1990) Eindhoven University of Technology Eindhoven The Netherlands
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de Oliveira, A., da Silva, M., Alves, G. et al. Encapsulation of TiO2 by emulsion polymerization with methyl metacrylate (MMA). Polym. Bull. 55, 477–484 (2005). https://doi.org/10.1007/s00289-005-0457-3
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DOI: https://doi.org/10.1007/s00289-005-0457-3