Summary
Well-defined polybutylacrylate (PBA) was prepared by atom transfer radical polymerization (ATRP). A novel end-functionalized PBA (macromolecular ligand) was synthesized via PBA bonded with thiocarbamide. Since thiocarbamide possesses strong chelating ability, end-functionalized PBA possesses some new properties such as coordination with metallic ions. After metallic ions were introduced into it, two kinds of end-functionalized PBA metal complexes were got. The structure and property of PBA, end-functionalized PBA and its metal complexes were characterized by 1H NMR, UV, GPC, Atomic Emission Spectrometry (AES), Cyclic Voltammogram (CV) and Dielectric Constant. The results indicate that the properties of end-functionalized PBA with well-defined structure were improved greatly by introducing a small quantity of transitional metallic ions into it. The novel end-functionalized PBA metal complexes exhibit stable electrochemical activity, dielectric property and have a good prospect in many fields as functional polymer.
Similar content being viewed by others
References
Rivas BL, Seguel GV, Ancatripai C (2000) Polymer Bulletin 44:445
Rivas BL and Seguel GV (1998) Polymer Bulletin 40:431
Pan YX, Su Q, Xu HF, Chen TH, Ge WK, Yang CL, Wu MM (2003) J Solid State Electrochem 174:69
Pronab D, Erik MI and Laurence AB (1997) Polymer Engineering and Science 37:1909
Fukashi M, Noriyoshi M, Yoshiki C (2001) Polymer Bulletin 46:257
Allcock HR and Sukky K (1989) Macromolecules 22:75
Richard AG, Jean KB and Lisa AH (1989) Adv Mater 10:1100
Kenneth AG, Jean KB and Lisa AH (1989) Polyhedron 8:113
Pierluigi B, Claudio B, Gisacarlo S, Dante M and Piero Z (1994) Inorg Chem 33:3180
Ciardelli F, Tsuchida E and Wohrle D (1996) Macromolecule-Metal Complexes, German, Springer 53
Agnew NH (1976) J Polym Sci Part A: Polym Chem 14:2819
Friend RH, Gymer RW, Holmes AB, Burroughes JH, Marks RN, Taliani C, etc. (1999) Nature 397:121
Economopoulos SP, Andreopoulou AK, Gregoriou VG and Kallitsis JK (2005) Chem Mater 17:1063
Matyjaszewski K, Xia JH (2001) Chem Rev 101:2921
Wang JS, Matyjaszewski K (1995) J Am. Chem Soc 117:5614
Coessens V, Pintauer T, Matyjaszewski K (2001) Prog Polym Sci 26:337
Yu XQ, Gao G, Wang JY, Li F, Tang XY (1999) Polym Int 48:805
Teodorecu M, Matyjaszewski K. (1999) Macromolecules 32:4826
Reyes M, Xiang Y, Shipp D (2001) Macromol Chem Phys 202:3268
Gaynor S, Qiu J, Matyjaszewski K (1998) Macromolecules 31:5951
Donzel C, Carrot G, Garamszegi L, Hilborn JG (2001) Polymeric Materials Science Engineering 84:369
Pook SB, Kim HS (1993) Macromolecules 26:7
Jiang YS (2002) The process of electron in function molecular, Jilin University Publishing Co. China
Reddinger JL and Reynolds JR (1998) Chem Mater 10:1236
Zhang HW, Ma HY, Li HT, Wang JY (2002) Polym Int 51:1129
Wang CZ, Liu HT (2001) Material Performance, Theory Beijing University of Technology Publishing Co. China
Dong HK, Won HJ (2001) Macromol Chem Phys 202:306
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, H., Jiang, Y., Zhang, K. et al. Synthesis and properties of novel end-functionalized polybutylacrylate and its metal complexes. Polym. Bull. 55, 447–456 (2005). https://doi.org/10.1007/s00289-005-0448-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00289-005-0448-4