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Synthesis of oxyquinolyl end-functional PMMA by atom transfer radical polymerization

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Abstract:

Oxyquinolyl end group functionalized PMMA was prepared by a new initiator 5-chloromethyl-8-hydroxyquinoline via atom transfer radical polymerization. Studying this polymer, we find it possesses stronger fluorescence and larger nonlinear third-order optical (NLO) coefficient than the PMMA initiated by ethyl α-bromoisobutyrate, and the polymer could be easily processed into film. The NLO coefficient of the polymer tested in the film is better than that in the solution.

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Authors and Affiliations

  1. Department of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, China

    Hua Li, Xuewei Xia, Shechun Yao & Xiulin Zhu

  2. Jiangsu Polytechnic University, Changzhou 213016, China

    Jianmei Lu

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  1. Jianmei Lu
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  2. Hua Li
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  3. Xuewei Xia
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  4. Shechun Yao
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  5. Xiulin Zhu
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Lu, J., Li, H., Xia, X. et al. Synthesis of oxyquinolyl end-functional PMMA by atom transfer radical polymerization. Polymer Bulletin 51, 327–332 (2004). https://doi.org/10.1007/s00289-004-0240-x

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  • DOI: https://doi.org/10.1007/s00289-004-0240-x

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