Abstract
We have interpreted a number of luminescence centers in natural tugtupite Na8Al2Be2Si8O24Cl2, sodalite Na8Al6Si6O24C2 and hackmanite Na8Al6Si6O24(Cl2,S) by use of laser-induced time-resolved luminescence spectroscopy. The main new results are the following: Fe3+, Mn2+, Eu2+, Ce3+, mercury type (potentially Pb2+, Tl+, Sn2+ and/or Sb3+), radiation induced luminescence centers; several types of S2 − centers. Spectral shift connected with the presence of luminescence centers, which are detected together with S2 − centers and impossible to resolve with continuous wave luminescence spectroscopy, is the possible reason for spectral diversity of S2 − luminescence centers presented in different publications.
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Constructive and careful reviews and comments on the manuscript by Dr. M. Kurosawa and an anonymous reviewer are gratefully acknowledged.
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Gaft, M., Panczer, G., Nagli, L. et al. Laser-induced time-resolved luminescence of tugtupite, sodalite and hackmanite. Phys Chem Minerals 36, 127–141 (2009). https://doi.org/10.1007/s00269-008-0263-1
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DOI: https://doi.org/10.1007/s00269-008-0263-1