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Heat transfer during production of carbon nanotubes by the electric-arc process

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Abstract

The electric-arc process for production of single-wall carbon nanotubes is traditionally conducted in horizontal configuration. Recently, we modified the electric-arc process by placing the cathode above the anode and obtained a significant reduction in nanotube diameters. In this paper, the temperature distribution in the electrodes and the arc, and the temperature and velocity fields in the reactor chamber are characterized through measurement and modeling. The data and the model reveal that the bundles of 0.8 nm single-wall carbon nanotubes (SWCNTs) grew on the cathode side surface at about 900°C. The 1.4 nm multi-wall nanotubes grew on the cathode base, at about 1500°C. These results concur with the hypothesis that high temperature prevents growth of smaller diameter SWCNTs.

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References

  1. Journet C, Maser WK, Bernier P, Loiseau A, Lamy de la Chapelle M, Lefrant S, Deniard P, Lee R, Fischer JE (1997) Large-scale production of single walled carbon nanotubes by the electric arc technique. Nature 388:756–758

    Article  Google Scholar 

  2. Bernier P, Maser WK, Journet C, Loiseau A, Lamy de la Chapelle M, Lefrant S, Lee R, Fischer JE (1998) Carbon single wall nanotubes:elabora-tion and properties. Carbon 36:675–680

    Article  Google Scholar 

  3. Yakobson BI, Smalley RE (1997) Fullerene nanotubes: C1,000,000 and Beyond. Am Sci 85:324–337

    Google Scholar 

  4. Nikolaev P, Bronikowski MJ, Bradley RK, Rohmund F, Colbert DT, Smith KA, Smalley RE (1999) Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide. Chem Phys Lett 313:91–97

    Article  Google Scholar 

  5. Thess A, Lee R, Nikolaev P, Dai H, Petit P, Robert J, Xu C, Lee YH, Kim SG, Colbert DT, Scuseria G, Tománek D, Fischer JE, Smalley RE (1996) Crystalline ropes of metallic carbon nanotubes. Science 273:483

    Article  Google Scholar 

  6. IIjima S (1991) Helical microtubes of graphitic carbon. Nature 354:56–58

    Article  Google Scholar 

  7. IIjima S, Ichihashi T (1993) Single shell carbon nanotubes of 1 nm diameter. Nature 363:603–605

    Article  Google Scholar 

  8. Liu C, Cong HT, Li F, Tan PH, Cheng HM, Lu K, Zhou BL (1999) Carbon 37:1865–1868

    Article  Google Scholar 

  9. Marin C, Serrano MD, Yao N, Ostrogorsky AG (2002) Convection assisted synthesis of small diameter single-walled carbon nanotubes by the electric arc technique, in vertical configuration. Nanotechnology 13:218–221

    Article  Google Scholar 

  10. Marin C (2002) PhD Thesis, Rensselaer Polytechnic Institute, Troy, NY

  11. Marin C, Serrano MD, Yao N, Ostrogorsky AG (2003) Evidence for a bundle of 4 Å single-walled carbon nanotubes. Nanotechnology 14:L1–L4

    Article  Google Scholar 

  12. NEKTON 2.85 Users Manual (1994)

  13. Properties and Characteristics of Graphite for the Semiconductor Industry (2001) Fifth printing, POCO Graphite Inc., Decatur, TX

  14. Nestor OH (1966) Heat intensity and current density distribution at the anode of high current inert gas arcs. In: Physics of arc welding. Unwin Brothers Ltd., Working and London 571B, pp 50–61

  15. Siegel R, Howell JR (1981) Thermal radiation heat transfer, 2nd edn. Hemisphere

  16. Boulos MI, Fauchais P, Pfender E (1994) Thermal plasmas, fundamentals and applications. Plenum Press, New York

    Google Scholar 

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Correspondence to A. G. Ostrogorsky.

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Ostrogorsky, A.G., Marin, C. Heat transfer during production of carbon nanotubes by the electric-arc process. Heat Mass Transfer 42, 470–477 (2006). https://doi.org/10.1007/s00231-005-0644-7

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