Skip to main content
Log in

Exponential Localization of Hydrogen-like Atoms in Relativistic Quantum Electrodynamics

  • Published:
Communications in Mathematical Physics Aims and scope Submit manuscript

Abstract

We consider two different models of a hydrogenic atom in a quantized electromagnetic field that treat the electron relativistically. The first one is a no-pair model in the free picture, the second one is given by the semi-relativistic Pauli-Fierz Hamiltonian. We prove that the no-pair operator is semi-bounded below and that its spectral subspaces corresponding to energies below the ionization threshold are exponentially localized. Both results hold true, for arbitrary values of the fine-structure constant, e 2, and the ultra-violet cut-off, Λ, and for all nuclear charges less than the critical charge without radiation field, Z c  = e −22/(2/π + π/2). We obtain similar results for the semi-relativistic Pauli-Fierz operator, again for all values of e 2 and Λ and for nuclear charges less than e −22/π.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Amrein, W.O., Boutet de Monvel, A., Georgescu, V.: C 0 -groups, commutator methods and spectral theory of N-body Hamiltonians. Progress in Mathematics, Vol. 135. Basel: Birkhäuser, 1996

  2. Arai A.: A particle-field Hamiltonian in relativistic quantum electrodynamics. J. Math. Phys. 41, 4271–4283 (2000)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  3. Avron J., Herbst I., Simon B.: Schrödinger operators with magnetic fields. I. General interactions. Duke Math. J. 45, 847–883 (1978)

    Article  MathSciNet  MATH  Google Scholar 

  4. Bach V., Chen T., Fröhlich J., Sigal I.M.: Smooth Feshbach map and operator-theoretic renormalization group methods. J. Funct. Anal. 203, 44–92 (2003)

    Article  MathSciNet  MATH  Google Scholar 

  5. Bach V., Fröhlich J., Pizzo A.: Infrared-finite algorithms in QED: the groundstate of an atom interacting with the quantized radiation field. Commun. Math. Phys. 264, 145–165 (2006)

    Article  ADS  MATH  Google Scholar 

  6. Bach V., Fröhlich J., Sigal I.M.: Quantum electrodynamics of confined nonrelativistic particles. Adv. Math. 137, 299–395 (1998)

    Article  MathSciNet  MATH  Google Scholar 

  7. Bach V., Fröhlich J., Sigal I.M.: Renormalization group analysis of spectral problems in quantum field theory. Adv. Math. 137, 205–298 (1998)

    Article  MathSciNet  MATH  Google Scholar 

  8. Bach V., Fröhlich J., Sigal I.M.: Spectral analysis for systems of atoms and molecules coupled to the quantized radiation field. Commun. Math. Phys. 207, 249–290 (1999)

    Article  ADS  MATH  Google Scholar 

  9. Bach V., Könenberg M.: Construction of the ground state in nonrelativistic QED by continuous flows. J. Diffl. Eqs. 231, 693–713 (2006)

    Article  MATH  Google Scholar 

  10. Barbaroux J.-M., Chen T., Vugalter S.: Binding conditions for atomic N-electron systems in non- relativistic QED. Ann. Henri Poincaré 4, 1101–1136 (2003)

    Article  MathSciNet  Google Scholar 

  11. Barbaroux, J.-M., Dimassi, M., Guillot, J.-C.: Quantum electrodynamics of relativistic bound states with cutoffs. II. In: Mathematical Results in Quantum Mechanics. Taxco, 2001. Exner, P., Grébert, B., Weder, R., eds., Contemp. Math., Vol. 307, Providence, RI: Amer. Math. Soc., 2002, pp. 9–14

  12. Barbaroux J.-M., Dimassi M., Guillot J.-C.: Quantum electrodynamics of relativistic bound states with cutoffs. J. Hyper. Diff. Eq. 1, 271–314 (2004)

    Article  MathSciNet  MATH  Google Scholar 

  13. Berthier A., Georgescu V.: On the point spectrum of Dirac operators. J. Funct. Anal. 71, 309–338 (1987)

    Article  MathSciNet  MATH  Google Scholar 

  14. Evans W.D., Perry P., Siedentop H.: The spectrum of relativistic one-electron atoms according to Bethe and Salpeter. Commun. Math. Phys. 178, 733–746 (1996)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  15. Fröhlich J., Griesemer M., Schlein B.: Asymptotic electromagnetic fields in models of quantum-mechanical matter interacting with the quantized radiation field. Adv. Math. 164, 349–398 (2001)

    Article  MathSciNet  MATH  Google Scholar 

  16. Fröhlich J., Griesemer M., Sigal I.M.: On spectral renormalization group. Rev. Math. Phys. 21, 511–548 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  17. Griesemer M.: Exponential decay and ionization thresholds in non-relativistic quantum electrodynamics. J. Funct. Anal. 210, 321–340 (2004)

    Article  MathSciNet  MATH  Google Scholar 

  18. Griesemer M., Lieb E.H., Loss M.: Ground states in non-relativistic quantum electrodynamics. Invent. Math. 145, 557–595 (2001)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  19. Griesemer M., Tix C.: Instability of a pseudo-relativistic model of matter with self-generated magnetic field. J. Math. Phys. 40, 1780–1791 (1999)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  20. Hiroshima F.: Diamagnetic inequalities for systems of nonrelativistic particles with a quantized field. Rev. Math. Phys. 8, 185–203 (1996)

    Article  MathSciNet  MATH  Google Scholar 

  21. Hiroshima F.: Functional integral representation of a model in quantum electrodynamics. Rev. Math. Phys. 9, 489–530 (1997)

    Article  MathSciNet  MATH  Google Scholar 

  22. Kato, T.: Perturbation Theory for Linear Operators. Classics in Mathematics. Berlin: Springer, 1995. (reprint of the 1980 edition)

  23. Könenberg, M.: Nichtexistenz von Grundzuständen für minimal an das quantisierte Strahlungsfeld gekoppelte, pseudorelativistische Modelle. Diploma Thesis, Universität Mainz, 2004

  24. Könenberg, M., Matte, O., Stockmeyer, E.: Existence of ground states of hydrogen-like atoms in relativistic quantum electrodynamics, I: The semi-relativistic Pauli-Fierz operator, II: The no-pair operator. In preparation

  25. Lieb E.H., Loss M.: A bound on binding energies and mass renormalization in models of quantum electrodynamics. J. Stat. Phys. 108, 1057–1069 (2002)

    Article  MathSciNet  MATH  Google Scholar 

  26. Lieb E.H., Loss M.: Stability of a model of relativistic quantum electrodynamics. Commun. Math. Phys. 228, 561–588 (2002)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  27. Lieb E.H., Loss M.: Existence of atoms and molecules in non-relativistic quantum electrodynamics. Adv. Theor. Math. Phys. 7, 667–710 (2003)

    MathSciNet  MATH  Google Scholar 

  28. Lieb E.H., Loss M.: A note on polarization vectors in quantum electrodynamics. Commun. Math. Phys. 252, 477–483 (2004)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  29. Lieb E.H., Siedentop H., Solovej J.P.: Stability and instability of relativistic electrons in classical electromagnetic fields. J. Stat. Phys. 89, 37–59 (1997)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  30. Matte, O.: Existence of ground states for a relativistic hydrogen atom coupled to the quantized electromagnetic field. Diploma Thesis, Universität Mainz, 2000

  31. Matte O., Stockmeyer E.: On the eigenfunctions of no-pair operators in classical magnetic fields. Integr. Equ. Oper. Theory 65, 255–283 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  32. Matte, O., Stockmeyer, E.: Spectral theory of no-pair Hamiltonians. Rev. Math. Phys. (to appear) Preprint, http://arxiv.org/abs/0803.1652v1[math-ph], 2008

  33. Miyao T., Spohn H.: Spectral analysis of the semi-relativistic Pauli-Fierz Hamiltonian. J. Funct. Anal. 256, 2123–2156 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  34. Thaller, B.: The Dirac Equation. Texts and Monographs in Physics. Berlin: Springer, 1992

  35. Tix C.: Strict positivity of a relativistic Hamiltonian due to Brown and Ravenhall. Bull. Lond. Math. Soc. 30, 283–290 (1998)

    Article  MathSciNet  MATH  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Oliver Matte.

Additional information

Communicated by I.M. Sigal

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matte, O., Stockmeyer, E. Exponential Localization of Hydrogen-like Atoms in Relativistic Quantum Electrodynamics. Commun. Math. Phys. 295, 551–583 (2010). https://doi.org/10.1007/s00220-009-0946-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00220-009-0946-6

Keywords

Navigation