Abstract
A novel in-needle sample preparation device has been developed for the determination of volatile aldehydes in gaseous samples. The needle device is designed for the gas chromatographic (GC) analysis of aldehydes and ketones commonly found in typical in-house environments. In order to prepare the extraction device, a bundle of polymer-coated filaments was longitudinally packed into a specially designed needle. Derivatization reactions were prompted by 2,4-dinitrophenylhydrazine (NDPH) included in the needle, and so the aldehydes and ketones were derivatized to the corresponding hydrazones and extracted with the extraction needle. A reproducible extraction needle preparation process was established, along with a repeatable derivatization/extraction process that ensures the successful determination of aldehydes. The storage performance of the extraction needle was also evaluated at room temperature for three days. The results demonstrate the successful application of the fiber-packed extraction device to the preparation of a gaseous sample of aldehydes, and the future possibility of applying the extraction device to the analysis of in-house environments.
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Jönsson JÅ, Mathiasson L (2001) J Sep Sci 24:495–507
Fritz JS, Masso JJ (2001) J Chromatogr A 909:79–85
Saito Y, Jinno K (2002) J Chromatogr A 1000:53–67
Pedersen-Bjergaard S, Rasumussen KE (1999) Anal Chem 71:2650–2656
Saito Y, Kawazoe M, Hayashida M, Jinno K (2000) Analyst 125:807–809
Eisert R, Pawliszyn J (1997) Anal Chem 69:3140–3147
Kataoka H, Narimatsu S, Lord HL, Pawliszyn J (1999) Anal Chem 71:4237–4244
Kataoka H (2002) Anal Bioanal Chem 373:31–45
Saito Y, Jinno K (2002) Anal Bioanal Chem 373:325–331
Saito Y, Jinno K, Greibrokk T (2004) J Sep Sci 27:1379–1390
Arthur C, Pawliszyn J (1990) Anal Chem 62:2145–2148
Pawliszyn J (1997) Solid-phase microextraction: theory and practice. Wiley-VCH, New York
Baltussen E, Cramers C, Sandra P (2002) Anal Bioanal Chem 373:3–22
Lipinski J (2001) Fresenius J Anal Chem 369:57–62
Koziel JA, Odziemkowski M, Pawliszyn J (2001) Anal Chem 73:47–54
Musshoff F, Lachenmeier DW, Kroener L, Madea B (2002) J Chromatogr A 958:231–238
Wang A, Fang F, Pawliszyn J (2005) J Chromatogr A 1072:127–135
Berezkin VG, Makarov ED, Stolyarov BV (2003) J Chromatogr A 985:63–65
Saito Y, Ueta I, Kotera K, Ogawa M, Wada H, Jinno K (2006) J Chromatogr A 1106:190–195
Saito Y, Nakao Y, Imaizumi M, Takeichi T, Kiso Y, Jinno K (2000) Fresenius J Anal Chem 368:641–643
Saito Y, Nojiri M, Imaizumi M, Nakao Y, Morishima Y, Kanehara H, Matsuura H, Kotera K, Wada H, Jinno K (2002) J Chromatogr A 975:105–112
Saito Y, Imaizumi M, Takeichi T, Jinno K (2002) Anal Bioanal Chem 372:164–168
Saito Y, Nakao Y, Imaizumi M, Morishima Y, Kiso Y, Jinno K (2002) Anal Bioanal Chem 373:81–86
Saito Y, Imaizumi M, Ban K, Tahara A, Wada H, Jinno K (2004) J Chromatogr A 1025:27–32
Saito Y, Hayashida M, Jinno K (2004) Sample preparation for the analysis of drugs in biological fluids. In: Hempel G (ed) Drug monitoring and clinical chemistry (Handbook of Analytical Separations, Vol. 5). Elsevier, Amsterdam, pp 1–14
Jinno K, Kawazoe M, Saito Y, Takeichi T, Hayashida M (2001) Electrophoresis 22:3785–3790
Saito Y, Imaizumi M, Nakata K, Takeichi T, Kotera K, Wada H, Jinno K (2001) J Microcol Sep 13:259–264
Saito Y, Tahara A, Imaizumi M, Takeichi T, Wada H, Jinno K (2003) Anal Chem 75:5525–5531
Saito Y, Tahara A, Ogawa M, Imaizumi M, Ban K, Wada H, Jinno K (2004) Anal Sci 20:335–339
Saito Y, Ogawa M, Imaizumi M, Ban K, Abe A, Takeichi T, Wada H, Jinno K (2005) Anal Bioanal Chem 382:825–829
Saito Y, Ogawa M, Imaizumi M, Ban K, Abe A, Takeichi T, Wada H, Jinno K (2005) J Chromatogr Sci 43:536–541
Ogawa M, Saito Y, Imaizumi M, Wada H, Jinno K (2006) Chromatographia 63:459–463
Arnts RR, Tajada SB (1989) Environ Sci Technol 23:1428–1430
Rodier DR, Nondek L, Birks JW (1993) Environ Sci Technol 27:2814–2820
Uchiyama S, Hasegawa S (1999) Atoms Environ 33:1999–2005
Uralets VP, Rijks JA, Leclercq PA (1980) J Chromatogr 194:135–144
Kuwata K, Uebori M, Yamasaki H, Kuge Y, Kiso Y (1983) Anal Chem 55:2013–2016
Levin JO, Andersson K, Lindahl R, Nilsson CA (1985) Anal Chem 57:1032–1035
Tayyari SF, Speakman JL, Arnold MB, Cai W, Behforouz M (1998) J Chem Soc Perkin Trans 2:2195–2200
Smith DF, Kleindienst TE, Hudgens ED (1989) J Chromatogr 483:431–436
Uchiyama S, Ando M, Aoyagi S (2003) J Chromatogr A 996:95–102
Abe A, Saito Y, Imaizumi M, Ogawa M, Takeichi T, Jinno K (2005) J Sep Sci 28:2413–2418
Acknowledgements
The authors would like thank the Hibi Science Foundation for financial support, and Mr. K. Kotera and Dr. H. Wada of Shinwa Chemical Industries for technical support. Part of this research was also supported by a Grant-in-Aid for Scientific Research B (#17350035) and a Grant-in-Aid for Scientific Research C (#17550078) from The Japan Society for the Promotion of Science (JSPS), and a Grant-in-Aid for Exploratory Research (#17651027) from The Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan.
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Saito, Y., Ueta, I., Ogawa, M. et al. Simultaneous derivatization/preconcentration of volatile aldehydes with a miniaturized fiber-packed sample preparation device designed for gas chromatographic analysis. Anal Bioanal Chem 386, 725–732 (2006). https://doi.org/10.1007/s00216-006-0509-z
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DOI: https://doi.org/10.1007/s00216-006-0509-z