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Determination of alcohol content in beverages using short-wave near-infrared spectroscopy and temperature correction by transfer calibration procedures

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Abstract

This paper reports the utilization of short-wave near-infrared (SW-NIR) transmission spectroscopy for rapid and conclusive analysis of alcoholic content (% v/v) in beverages. This spectral region is interesting because common visible diode array spectrometers can be utilized, reducing time and costs in comparison with traditional near-infrared or mid-infrared instruments. A correction of external temperature influence is necessary, and for this purposes two calibration transfer procedures were compared: piecewise direct standardization (PDS) and orthogonal signal correction (OSC). The RMSEP found for the alcoholic content model at 20 °C was 0.13% v/v and, after application of transfer calibration procedures at other temperatures (15, 25, 30 and 35 °C) using the model built at 20 °C, errors of the same order of magnitude were obtained.

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Authors and Affiliations

  1. Instituto de Química, Universidade Estadual de Campinas-UNICAMP, CP 6154, 13083–970, Campinas, São Paulo, Brazil

    Fernando D. Barboza & Ronei J. Poppi

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  1. Fernando D. Barboza
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  2. Ronei J. Poppi
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Correspondence to Ronei J. Poppi.

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Barboza, F.D., Poppi, R.J. Determination of alcohol content in beverages using short-wave near-infrared spectroscopy and temperature correction by transfer calibration procedures. Anal Bioanal Chem 377, 695–701 (2003). https://doi.org/10.1007/s00216-003-2128-2

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  • DOI: https://doi.org/10.1007/s00216-003-2128-2

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