Alcohol Determination in Distilled Alcoholic Beverages by Liquid Phase Fourier Transform Mid-Infrared and Near-Infrared Spectrophotometries

Abstract

Fourier transform mid-infrared spectrophotometry (FT-MIR), 1180–950 cm⁻¹, and near-infrared spectrophotometry (NIR), 1720–1660 nm, have been used complementarily for the direct determination of ethanol and methanol in distilled alcoholic beverages. In mid-infrared ethanol and methanol identified separately, hence, it has been used to confirm the absence or presence of methanol. In the absence of methanol, both were used to determine the alcoholic strength independently; however, near-infrared was used without diluting the samples. Ethanol and methanol contents were evaluated using the calibration curves established by a plot of peak height or peak area versus concentration % (w/w). The linearity range for ethanol was up to 15 and 50 % (w/w) for mid- and near-infrared, respectively. The developed methods are simple, fast, precise, and accurate. Moreover, the results obtained were in excellent agreement with the results obtained from gas chromatographic measurements. No sample preparation was required at all, and in all samples, methanol was not detected.