Skip to main content

Advertisement

SpringerLink
Log in

Determination of lead and cadmium using a polycyclodextrin-modified carbon paste electrode with anodic stripping voltammetry

  • Original Paper
  • Published:
Analytical and Bioanalytical Chemistry Aims and scope Submit manuscript

Abstract

This work reports the use of α and β-cyclodextrin-modified carbon paste electrodes (CPEα-CD and CPEβ-CD) to determine simultaneously Pb(II) and Cd(II) by means of the electrochemical technique known as anodic stripping voltammetry (ASV). Both modified electrodes displayed good resolution of the oxidation peaks of the said metals. Statistic analysis of the results strongly suggests that the CPEβ-CD exhibited a better analytical response that the CPEα-CD, while the detection limits obtained for Pb(II) were 6.3×10−7 M for the CPEα-CD and 7.14×10−7 M for the CPEβ-CD, whereas for Cd(II) they were 2.51×10−6 M for the CPEα-CD and 2.03×10−6 M for the CPEβ-CD.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1a,b.
Fig. 2.
Fig. 3a,b.
Fig. 4.
Fig. 5a,b.
Fig. 6.

Similar content being viewed by others

References

  1. Bard A, Faulkner L (2001) Electrochemical methods. Fundamentals and applications, 2nd edn. Wiley

  2. Kissinger T, Heineman W (1984) Laboratory techniques in electroanalytical chemistry. Marcel Dekker

  3. Richeter P, Toral MI, Abbott B (2002) Electroanalysis 14:1288–1293

    Article  Google Scholar 

  4. Prabhu VS, Baldwin PR, Kryger L (1987) Anal Chem 59:1074–1078

    CAS  Google Scholar 

  5. Baldwin RP, Christensen JK, Kryger L (1986) Anal Chem 58:1790–1798

    CAS  Google Scholar 

  6. Mojtaba S, Abdollah S, Seled MG, Hashem S, Mir F (2001) J Solid State 5:68–73

    Google Scholar 

  7. Cai X, Ogorevc B, Tavčar G, Kalcher K (1995) Electroanalysis 7:639

    CAS  Google Scholar 

  8. Cai X, Kalcher K, Lintschinger J, Neuhold C, Tykarski J, Ogorevc B (1995) Electroanalysis 7:556

    CAS  Google Scholar 

  9. Stadlober M, Kalcher K, Raber G (1997) Electroanalysis 9:225

    CAS  Google Scholar 

  10. Komersova A, Bartos M, Kalcher K, Vytras K ( 1998) Electroanalysis 10:442

    Google Scholar 

  11. Downard AJ (2000) Electroanalysis 12:1085–1096

    CAS  Google Scholar 

  12. Jyh MZ, Hsieh HC, Govindasamy I (1999) Electroanalysis 11:108

    Article  Google Scholar 

  13. Soo BK, Si XG (2002) Electroanalysis 14:813

    Article  Google Scholar 

  14. Taewon L, Koo-Chun C, Jongman P (2002) Electroanalysis 14:833

    Article  Google Scholar 

  15. Da Silva SM (1998) Electroanalysis 10:722

    Article  Google Scholar 

  16. Tesfaye HD, Bhagwan S, Chandravansshi, Hailemichael A (1999) Electroanalysis 11:305

    Google Scholar 

  17. Prabhu SV, Baldwin RP, Kryger L (1989) Electroanalysis 1:13

    CAS  Google Scholar 

  18. Connor M, Dempscy E, Smyth MR, Richardson DH (1991) Electroanalysis 3:331

    CAS  Google Scholar 

  19. Hu Z, Seliskar CJ, Heineman WR (1998) Anal Chim Acta 369:93

    Article  CAS  Google Scholar 

  20. Ben Ali M, Kalfat R, Sfihi H, Ben Quada H, Chovelon JM, Jaffrezic-Renault N (1998) Mater Sci Eng C C6:53

    Google Scholar 

  21. Roa MG, Ramírez SMT, Galicia L (2002) J Solid State Electrochem

  22. Szejtli J (1998) Chem Rev 98:1743

    Article  CAS  PubMed  Google Scholar 

  23. Odashima K, Kotato M, Sugawara M, Umezawa Y (1993) Anal Chem 65:927

    CAS  Google Scholar 

  24. Godinez LA, Lin J, Muñoz M, Coleman W, Rubin S, Parikh A, Zawodzinski TA, Loveday D, Ferraris JP, Kaifer EA (1998) Langmuir 14:137

    CAS  Google Scholar 

  25. Ferancová A, Labuda J (2001) Fresenius J Anal Chem 370:1

    Article  PubMed  Google Scholar 

  26. Schaschke N, Fiori S, Weyher E, Escrieut C, Fourmy D, Müller G, Moroder L (1998) J Am Chem Soc 120:7030

    Article  CAS  Google Scholar 

  27. Clarke JR, Coates HJ, Lincoln FS (1988) Adv Carbohydr Chem Biochem 46:05

    Google Scholar 

  28. Retna C, Ramaraj R (1999) Electrochim Acta 44:2685

    Article  Google Scholar 

  29. Harata K (1998) Chem Rev 98:1803

    Article  CAS  PubMed  Google Scholar 

  30. Roa MG, Ramírez SMT, Galicia L (2002) J Incl Phenom (submitted)

  31. Miller JC, Miller JN (2002) Statistics and chemometrics for analytical chemistry. Pearson Education, 4th edn

  32. Rubinson A, Rubinson KJ (2001) Análisis Instrumental. Prentice Hall

Download references

Acknowledgements

The authors wish to thank the support from CONACyT through project no. 400200–5-32576-E for financing this research work. G.R.M. acknowledges the studentship granted by CONACyT.

Author information

Authors and Affiliations

  1. Depto. de Química, Universidad Autónoma Metropolitana-Iztapalapa, Apdo. Postal 55–532, 09340 México, D.F. Méxiko

    Gabriela Roa, M. T. Ramírez-Silva & Laura Galicia

  2. Depto. de Materiales, Universidad Autónoma Metropolitana—Azcapotzalco, Apdo. Postal 55–532, 09340 México, D.F. México

    M. A. Romero-Romo

Authors
  1. Gabriela Roa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. T. Ramírez-Silva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Romero-Romo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Laura Galicia
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Laura Galicia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Roa, G., Ramírez-Silva, M.T., Romero-Romo, M.A. et al. Determination of lead and cadmium using a polycyclodextrin-modified carbon paste electrode with anodic stripping voltammetry. Anal Bioanal Chem 377, 763–769 (2003). https://doi.org/10.1007/s00216-003-2126-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00216-003-2126-4

Keywords

Search

Navigation