Abstract
In brazing, the interfacial conditions between the molten filler material and the solid workpiece are important, yet they cannot be observed experimentally. A two-dimensional axisymmetric simulation was conducted to analyze the behavior of a single droplet of molten aluminum on zinc-coated steel sheet as a simplified brazing process. The simulation models were verified through a comparison with experimental results in terms of bead shape, zinc distribution, and molten metal behavior. The results show that Young’s equation was not valid in explaining the wetting behavior because of the instant solidification. In this respect, the effects of the workpiece thickness and wetting angle on the bead width were negligible. Two periods of time, namely, the times for the temperature difference and solidification and their ratio (interface number), were defined to analyze the temperature behavior at the interface over time as well as the effects of workpiece thickness. The interfacial temperature behaviors tended to be divided into three regions: linear (or inversely proportional), singular, and convergence. The interface number converged to a value of one with the increase in the thickness.
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1 Introduction
Due to environmental issues, high strength steels, aluminum alloys, magnesium alloys, glass fiber reinforced thermoplastics, and their hybrid structures have received much attention in the automotive industry for the light-weight construction of car bodies [1]. Most European car manufacturers use ultra-high-strength hot-stamped boron steels (UHSS) because these can significantly reduce the car body weight for a relatively low price. For additional weight reduction, floor, roof, hood, and door parts made of steel can be replaced with aluminum alloys [2]. To do this, it is necessary to secure welding and joining technologies for the dissimilar materials of steel and aluminum alloy. The methods can be typically divided into mechanical and thermal processes. Unlike mechanical processes, such as riveting and clinching, thermal processes have the advantage of direct material connection, relatively high process speeds, and low process costs. However, thermal processes must overcome the differences in the thermophysical material properties and the limited solubility of dissimilar materials [3]. In particular, the latter creates intermetallic compounds that degrade the metallurgical, mechanical, and electrical properties of joints. It is impossible to create a joint with the acceptable properties using conventional welding processes that involve the excessive melting and mixing of dissimilar metals. For this reason, brazing, in which the joint is formed by melting only the filler material and not the base material with which it is to be joined, has been proposed as an alternative. The filler melts at a relatively low temperature and wets the surface of the base material, filling the gap through capillary action. Due to the relatively low process temperature, the formation of intermetallic compounds is reduced, meaning the method can be successfully applied to the welding and joining of dissimilar metals [4]. In addition, brazing can obtain a smoother surface than conventional welding processes. Therefore, it is actively applied to the automotive industry where sheet metal joining is required, especially for car parts such as tailgates, roof joints, and C columns, for which visual seam quality is important because they are externally visible. Various brazing processes exist, but the automotive industry requires processes that minimize the thermal effect for aesthetic reasons as well as high mechanical properties. For this reason, laser brazing, which can minimize the size of a heat source and facilitate easy energy control, is being applied in the automobile industry. Laser brazing is known to offer good joint properties for dissimilar materials as it has a faster processing speed and a small heat affected area [5].
The most important condition in the brazing process is the ability of the molten filler material to spread well over the base material. However, naturally grown oxide layers on the aluminum surface interfere with this wetting [6]. Flux can be applied to solve this problem but, since most flux is toxic and corrosive, it has a disadvantage in that it must be removed after brazing. On the other hand, in the case of zinc-coated steels, molten aluminum can be easily wetted on the surface without flux [7]. The improved wetting due to zinc coating is also observed in other molten metals [8,9,10]. Also, in the laser-MIG hybrid process, zinc coating showed favorable results in relation to wetting [11]. An experimental model system was designed to observe the behavior of an AlSi12 droplet on the surface of a zinc-coated steel sheet [12]. The results showed that the galvanization types (electro and hot-dip) did not affect the wetting, and the zinc accumulated at the side end of the bead. The zinc accumulation is also reported for other metals, and it is may be caused by the molten zinc being pushed laterally by the kinetic energy of the fallen droplet [13]. Similar results were also expected based on numerical simulation [14]. Computational fluid dynamics (CFD) simulation results showed that molten zinc was laterally pushed as the molten metal propagated to the side. However, the simulation result had a problem of overestimating the bead size.
In the actual laser brazing process, the filler metal melted by the laser heat source is continuously supplied to the surface of the base material. Therefore, the complexity of the problem increases because brazing speed, wire feeding speed, and laser heat source conditions must also be considered for the analysis of the results. Also, the state of the interface between the filler metal and the base material cannot be observed in real time through the experiment. In this regard, in this study, the problem was simplified by fixing the heat source with a single molten drop and changing only the thickness of the base material. In addition, the state of the interface was observed in real time using the simulation method verified by comparison with the experiment. For the simulation, this study attempts to improve on the previous numerical study [14]. Conditions similar to the experiment are applied in a simulation. Hereby, the height at which droplet begins to fall and the convective and radiative heat losses are considered. In addition, in order to improve the accuracy of the bead shape estimation, the measured weight of the droplet is used to calculate the droplet size set in the simulation. The model used in the simulation is verified by comparing it with the experimental results for the bead shape, zinc distribution, and molten metal behavior. Using the verified model, the effects of workpiece thickness are elucidated by using the interfacial temperature behavior, and for this purpose, two periods of time and their ratio are defined and used to characterize the process.
2 Methodology
Figure 1a shows the experimental model system (in-house developed system, BIAS GmbH, Germany) used in this study. This device generates a single droplet by melting a wire with a laser and allowing it to freefall onto the workpiece. The experiment was performed in a process chamber filled with argon at room temperature. AlSi12 aluminum filler wire, which chemical composition is listed in Table 1, was fed vertically through a nozzle with a speed of 25 mm/s, and a laser beam (TruDisk8002, Trumpf GmbH, Germany) with a wavelength of 1030 nm was irradiated horizontally through a window with a constant power of 900 W to keep a drop grow constantly. The wire melted by the laser produced a droplet at a height of 22 mm, freefalling onto a zinc-coated steel sheet (0.8 mm, DX56 + Z140) at room temperature (23 °C). The characteristic of the steel sheet is shown in Table 2. A high-speed camera (Phantom V5.1, Vision Research Inc., USA) was used to observe the behavior of the droplet colliding with and wetting the workpiece at 2000 fps. A two-color pyrometer system (IGAR-12 LO, IMPAC Infrared GmbH, Germany) was used to measure the temperature, and the droplet temperature was about 1400 °C. The weight of the measured droplet was 110 mg on average.
The CFD simulation was conducted to calculate the heat and mass transfer, in which the two-dimensional axisymmetric computational domain was as shown in Fig. 1b. The cell size was 0.1 mm, and the total number of cells was 27,000 for the domain. Based on the experimental data, a droplet with a diameter of 4.4 mm (\(2\times \sqrt[3]{3\times (110 \times {10}^{-3}\mathrm{g})/(4\times\uppi \times (2499\times {10}^{-6}\mathrm{ g}/{\mathrm{mm}}^{3})}=4.4\mathrm{ mm}\)) and a temperature of 1400 °C was set to freely fall from a height of 22 mm. Convective and radiative heat losses on the surface of the droplet and workpiece to the environment at room temperature (23 °C) were considered. The thickness of the zinc layer was set as 10 µm on the workpiece surface, corresponding to the Z140 specification. Table 3 shows the boundary conditions for the computational domain, and Table 4 shows the material properties used. A single-phase, incompressible laminar flow with Newtonian viscosity was assumed for simplicity. The governing equations for the CFD simulation are as follows. The mass, momentum, and energy conservation equations were solved to obtain the temperature, velocity, and pressure distributions. The volume-of-fluid (VOF) equation was used to track the free surface boundary of the molten metal. A scalar conservation equation was used to calculate the zinc distribution in the molten metal.
- Mass conservation equation:
where \(\overrightarrow{v}\) is the velocity vector.
- Momentum conservation equation:
where \(\rho\) is the density, \(p\) is the pressure, \(\nu\) is the dynamic viscosity, \(K\) is the drag coefficient for a porous media model in the mushy zone, and \(G\) is the body acceleration due to body force.
- Energy conservation equation:
where \(h\) is the specific enthalpy, \(k\) is the thermal conductivity, and \(T\) is the temperature.
- VOF equation:
where \(F\) is the volume fraction occupied by the fluid and has a value between 0 and 1.
- Scalar conservation equation:
where \(\Phi\) is the scalar value for the zinc coated. If a cell is occupied entirely by the zinc, \(\Phi\) is 1.0, and it changes between 0 and 1 according to the volume fraction of the zinc. A diffusion of the zinc was not considered.
The following energy and pressure boundary conditions were applied on the free surface.
- Energy balance:
where \(\overrightarrow{n}\) is the vector normal to the local free surface, \({h}_{c}\) is the convective heat transfer coefficient, \({T}_{0}\) is the ambient temperature, \(\varepsilon\) is the surface radiation emissivity, and σ is the Stefan-Boltzmann constant.
- Pressure balance:
where \(\gamma\) is the surface tension and \(R\) is the effective radius of the surface curvature.
The governing equations and boundary conditions were discretized and solved using the commercial CFD code (FLOW-3D) by Flow Science, Inc. [15]. The calculation of the entire process (from freefall to solidification) for the case with a workpiece thickness of 0.8 mm required a wall clock time of about 22.4 min with the AMD Ryzen Threadripper 2950X Processor and 32 GB RAM.
Figure 2 presents a schematic description of the analysis method for the interfacial temperature behavior between the metal droplet and the workpiece. Using a period of time with the temperature difference between the droplet and the workpiece, \({t}_{\mathrm{dif}}\), and a period of time for completing the solidification of the droplet, \({t}_{\mathrm{sol}}\), a dimensionless number was defined, as shown in Eq. (8), here called the interface number. It was also utilized to analyze the temperature behavior at the interface.
In the brazing process, it is predicted that \({t}_{\mathrm{dif}}\) should be increased and \({t}_{\mathrm{sol}}\) should be decreased to reduce the heat effect, such as the melting of the base material. In this respect, the optimal condition is when the interface number has the maximum value. In this study, the influence of the thickness change (0.5–1.4 mm) of the workpiece on the interfacial temperature behaviors was elucidated by simulation.
3 Results
Figure 3 shows the comparison of the experimental (according to [14]) and simulation results for the case with a workpiece thickness of 0.8 mm. The simulation results with a droplet diameter of 4.4 mm predicted the bead shape well. Using the scalar conservation equation in Eq. (5), it was possible to show the zinc accumulation at the side end of the bead.
Figure 4 shows the wetting behavior after the freefalling droplet collides with the workpiece surface. The simulation results for the molten metal behavior were in a good agreement with the experimental ones derived from the high-speed camera. The bead width was determined to be within 5 ms, which was an extremely short period of time after the droplet impingement. In addition, the sideways jet and central jet phenomena were observed together with the large fluctuation of the molten metal surface.
Figure 5 shows the interface temperature behavior derived from the simulation result. As shown in Fig. 2, it was found that there is a time period in which the temperature difference occurs due to the differences in the material properties of the droplet and workpiece at the interface. It was also found that the time required for the droplet to solidify was greater than the time period in which the temperature difference occurred.
Based on the model verified for a workpiece thickness of 0.8 mm, simulations were performed for various workpiece thicknesses (0.5–1.4 mm). Figure 6 shows the simulated bead widths for the workpiece thicknesses. Even with the change in thickness, the bead width remained almost constant, meaning the thickness had a negligible effect on the bead width.
Figure 7 shows the change of tsol and tdif according to the workpiece thickness. tsol decreased with the increase of the thickness, whereas tdif increased. In particular, the difference between them was large when the workpiece was thin, but as the thickness increased, they converged and became similar. The characteristics of the graphs can be divided into three sections, namely inverse (tsol) or proportional (tdif), singular, and convergence sections.
Figure 8 presents the change of the interface number, which is the ratio of the time periods in Fig. 7, according to the workpiece thickness. As the workpiece thickness increased, the interface number increased and converged to a value of 1.0. Figure 8 also shows the three characterized sections. The number increased linearly when the thickness was thin, and then there was a singular Sect. (1.0–1.2 mm) in which the number increased rapidly. Finally, it converged.
4 Discussion
Based on the comparison of the experimental and simulation results in Figs. 3 and 4, the simulation model was accurate enough to simulate the process behavior. As the bead width was determined almost instantly after the droplet impinged, the kinetic energy of the droplet and the initial temperature of the droplet and workpiece acted as important parameters to determine the behavior. In Fig. 6, the workpiece thickness had little effect on determining the bead width. It was considered that the effect of the thickness appears over a relatively long period of time.
As shown in Fig. 4, a central jet phenomenon was observed in the molten metal after the impingement. It was reported that this phenomenon does not appear when water droplets collide with solid surfaces, yet it does appear when they collide with liquid surfaces [17]. In the case of water, only the sideways jet was observed without the central jet because the droplet was able to spread sufficiently over the solid surface. On the other hand, in the case of the molten aluminum droplet used in this study, the spread width was small due to the fast solidification. For this reason, the molten metal fluctuation was severe, and the sideways and central jets occurred by turns. Spatter could be generated in that the velocity of the jets was larger than the droplet impingement velocity.
In this study, since the amount of the zinc layer was insignificant compared to that of the droplet and base metal, neither the different physical properties nor the vaporization of zinc was considered in the simulation. As shown in Eq. (5), the zinc behavior was calculated by considering a 10-µm-thick zinc layer on the workpiece as a scalar value. As a result, like the experimental results, it was observed that most zinc accumulated at the side end of the bead. In previous studies [13, 14], the zinc accumulation phenomenon was explained by the lateral movement of the liquid zinc by the kinetic energy of the droplet. Since the bead width was determined very quickly after the droplet impingement, it was thought that the zinc accumulation was also determined in a very short period. However, there was a difference in the shape and the zinc accumulation value at the side end of the bead. This is thought to be because the cell size used in the simulation was 0.1 mm, which was relatively large to simulate the side part precisely. Of course, more accurate simulation could be possible using a smaller cell size, but it could not affect the final result except for more accurately predicting the specific small region. Rather, it will increase the computing time.
It is stressed that the bead width was determined within a very short time after the droplet collided with the workpiece. The kinetic energy of the droplet was used to push the molten metal to the side, but it solidified immediately at the interface due to the initial temperature difference between the droplet and workpiece. In this case, Young’s equation, which is traditionally used to describe the wetting shape of a liquid on a solid surface, was not valid. Figure 9 shows the simulation results for the solid fraction at the interface. It was observed that the bead width grew due to the strong radial velocity. However, it was also seen that the outermost cell, which determines the wetting behavior, was always in a solidified state. Hence, the contact angle (0°, 30°, 90°) had no significant effect on wetting behavior.
In Fig. 7, \({t}_{\mathrm{sol}}\) decreased as the thickness of the base material increased, which is thought to be because the cooling effect increased as the base material became thicker, whereas \({t}_{\mathrm{dif}}\) increased as the thickness of the base material increased. This is thought to be because the difference in heat capacity between the drop and the base material increased as the base material became thicker, and more time was required for the two objects to reach the thermal equilibrium state. Figures 7 and 8 show that the interfacial temperature behaviors were divided into three characterized sections, although the boundaries are vague to separate by specific numbers. Before the singular section, the heating effect by the droplet was more effective than the workpiece, whereas after the singular section, the cooling effect from the workpiece was considered to be more significant. Therefore, in order to minimize the thermal effect of the workpiece, a condition in which the interface number converges to a value of 1.0 would be ideal.
In this study, the heat source is simplified to a single drop, but in the actual laser brazing process, the filler wire melt by a laser beam is continuously supplied to the base material. Therefore, heat capacity of a single drop was considered in this study, whereas heat capacity per unit length should be considered in the continuous process as a new variable. It is expected that the interfacial temperature characteristics similar to those observed in this study can be predicted as a function of heat capacity per unit length in the continuous process. In particular, if the three characterized sections observed in this study can be expressed not only as a function of the thickness of the base material but also as a function of the amount of heat capacity, it can be used to optimize heat source condition for a specific thickness of the base material.
5 Conclusion
The behavior of a single aluminum droplet falling onto zinc-coated steel was studied using CFD simulation. The simulation model was verified through a comparison with experimental results. Two time periods and their ratios were used to analyze the interfacial temperature behavior. The following conclusions can be drawn:
-
1.
In a single metal droplet condition, the workpiece thickness was a negligible parameter in determining the bead width. As the bead width was determined almost instantaneously after the droplet had collided on the workpiece, the kinetic energy of the droplet and the initial temperature of the droplet and workpiece acted as important parameters.
-
2.
Young’s equation was not valid in explaining the wetting behavior of the process in this study due to the rapid solidification of the molten metal, meaning the effects of the thickness and contact angle were negligible, as shown in the simulation. The rapid solidification resulted in sideway and central jets and the zinc accumulation in terms of the molten metal behavior.
-
3.
The interfacial temperature behavior could be divided into three characterized sections, namely, inverse (tsol) or proportional (tdif, Nin), singular, and convergence. In order to minimize the thermal effect of the workpiece, a condition in which the interface number converges to a value of 1.0 would be ideal.
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Funding
Open Access funding enabled and organized by Projekt DEAL. The study received funding from the Deutsche Forschungsgemeinschaft (DFG, Project No. 424307320, “Understanding the effect of interlayers on the interfacial temperature during laser brazing for the use of higher melting braze materials”). The “BIAS ID” numbers are part of the figures and allow the traceability of the results with respect to the mandatory documentation required by the funding organization.
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Won-Ik Cho: conceptualization, methodology, software, validation, formal analysis, investigation, data curation, writing — original draft, writing — review and editing. Peer Woizeschke: conceptualization, supervision, writing — review and editing, funding acquisition.
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Cho, WI., Woizeschke, P. Numerical study of the effect of workpiece thickness on the interfacial behavior of a molten aluminum droplet on a zinc-coated steel sheet. Int J Adv Manuf Technol 119, 6245–6254 (2022). https://doi.org/10.1007/s00170-022-08719-x
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DOI: https://doi.org/10.1007/s00170-022-08719-x