Abstract
4D printing has been evolving from traditional 3D printing in the past years as an enabling technology imparting additive manufacturing with unprecedented functionality of creating time-dependent geometries. However, the current development status presents both cost and technical barriers, keeping 4D printing from being accessible to the general 3D printer users, in particular those who already have traditional 3D printing machines. This paper reported the development and kinetic evaluation of a low-cost temperature-sensitive shape memory polymer for 4D printing. The shape memory polymer is made of polylactic acid (PLA)-thermoplastic polyurethane (TPU) composite in the form of filaments under different weight concentration ratios through extrusion processes. The filaments were tested in an FDM process to make 4D printed structures. The experiment study reveals the relationship between the material concentration ratio, recovery rate of sample workpieces, and the number of repeating recovery cycles. In addition, dynamic characteristics such as recovery velocity, acceleration, angular velocity, and angular acceleration were also investigated to characterize the behavior of the shape memory polymer. At the end of the paper, examples are provided to demonstrate the capability of the shape memory polymer in FDM-based 4D printing applications.
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References
Zarek M, Layani M, Cooperstein I, Sachyani E, Cohn D, Magdassi S (2016) 3D printing of shape memory polymers for flexible electronic devices. J Adv Mater 28:4449–4454
Choi J, Kwon O-C, Jo W, Lee HJ, Moon M-W (2015) 4D printing technology: a review. 3D Print Addit Manufact 2(4):159–167
Mantovani D, El Feniant F, Laroche G, Fiset M (2002) Shape memory materials for biomedical applications. Adv Eng Mater 4(3):91–104
Choong YYC, Maleksaeedi S, Eng H, Wei J, Su P-C (2017) 4D printing of high performance shape memory polymer using stereolithography. J Mat Design 126:219–225
Yang Y, Chen Y, Wei Y, Li Y (2016) 3D printing of shape memory polymer for functional part fabrication. Int J Adv Manuf Technol 84:2079–2095
Bakarich, Shannon E.; Gorkin, Robert; Panhuis, Marc In Het; Spinks, Geoffrey M, “4D printing with mechanically robust, thermally actuating hydrogels”, Macromol Rapid Commun, v 36, n 12, p 1211–1217, 2015
Zolfagharian, Ali; Kaynak, Akif; Khoo, Sui Yang; Kouzani, Abbas, “Pattern-driven 4D printing”, Sensors Actuators A Phys, v 274, p 231–243, 2018
Naficy, Sina; Gately, Reece; Gorkin, Robert; Xin, Hai; Spinks, Geoffrey M, “4D printing of reversible shape morphing hydrogel structures”, Macromol Mater Eng, v 302, n 1, 1600212 2017
Guo, Jinhua; Zhang, Rongrong; Zhang, Lina; Cao, Xiaodong, “4D printing of robust hydrogels consisted of agarose nanofibers and polyacrylamide”, ACS Macro Lett, v 7, n 4, p 442–446, 2018
Bakarich, Shannon E.; Gorkin, Robert; Naficy, Sina; Gately, Reece; Panhuis, Marc In Het; Spinks, Geoffrey M., “3D/4D printing hydrogel composites: a pathway to functional devices”, MRS Adv, v 1, n 8, p 521–526, 2016
McCracken JM, Rauzan BM, Kjellman JCE, Su H, Rogers SA, Nuzzo RG (2019) Ionic hydrogels with biomimetic 4D-printed mechanical gradients: models for soft-bodied aquatic organisms. Advanced Functional Materials
Roach, Devin J; Kuang, Xiao; Yuan, Chao; Chen, Kaijuan; Qi, H Jerry, “Novel ink for ambient condition printing of liquid crystal elastomers for 4D printing”, Smart Mater Struct, v 27, n 12, 2018
Kuang, Xiao; Chen, Kaijuan; Dunn, Conner K.; Wu, Jiangtao; Li, Vincent C. F.; Qi, H. Jerry, “3D printing of highly stretchable, shape-memory, and self-healing elastomer toward novel 4D printing”, ACS Appl Mater Interfaces, v 10, n 8, p 7381–7388, 2018
Saed, Mohand O.; Ambulo, Cedric P.; Kim, Hyun; De, Rohit; Raval, Vyom; Searles, Kyle; Siddiqui, Danyal A.; Cue, John Michael O.; Stefan, Mihaela C.; Shankar, M. Ravi; Ware, Taylor H., “Molecularly-engineered, 4D-printed liquid crystal elastomer actuators”, Adv Funct Mater, v 29, n 3, 1806412, 2019
Mu, Quanyi, Dunn, Conner K.; Wang, Lei, Dunn, Martin L; Qi, H Jerry, Wang, Tiejun (2017), “Thermal cure effects on electromechanical properties of conductive wires by direct ink write for 4D printing and soft machines”, Smart Mater Struct, v 26, n 4:045008
Zhu, Pengfei; Yang, Weiyi; Wang, Rong; Gao, Shuang; Li, Bo; Li, Qi, “4D printing of complex structures with a fast response time to magnetic stimulus”, ACS Appl Mater Interfaces, v 10, n 42, p 36435–36442, 2018
Momeni, Farhang; M.Mehdi Hassani.N, Seyed; Liu, Xun; Ni, Jun, “A review of 4D printing”, Mater Des, v 122, p 42–79, 2017
Zhang Z, Demir KG, Gu GX (2019) Developments in 4D-printing: a review on current smart materials, technologies, and applications. International Journal of Smart and Nano Materials
Lee, Amelia Yilin; An, Jia; Chua, Chee Kai, “Two-way 4D printing: a review on the reversibility of 3D-printed shape memory materials”, Engineering, v 3, n 5, p 663–674, 2017
Mitchell A, Lafont U, Hołyńska M, Semprimoschnig C (December 2018) Additive manufacturing—a review of 4D printing and future applications. Additive Manufact 24:606–626
Ge Q, Sakhaei AH, Lee H, Dunn CK, Fang NX, Dunn ML (2016) Multimaterial 4D printing with tailorable shape memory polymers. Sci Rep 6:31110. https://doi.org/10.1038/srep31110
Cai J (2016) 4D printing dielectric elastomer actuator based soft robots. In: Theses and Dissertations. 1680. University of Arkansas, Fayetteville. https://scholarworks.uark.edu/etd/1680
Rosset S, Araromi OA, Schlatter S, Shea HR (2016) Fabrication process of silicone-based dielectric elastomer actuators. J Vis Exp 108:e53423. https://doi.org/10.33791/53423
Naficy S, Spinks GM, Wallace GG (2014) Thin, tough, pH-sensitive hydrogel films with rapid load recovery. ACS Appl Mater Interfaces 6(6):4109–4114
Ge Q, Dunn CK, Qi HJ, Dunn ML (2014) Active origami by 4D printing. Smart Mater Struct 23:1–15
Meng Y, Jiang J, Anthamatten M (2016) Body temperature triggered shape-memory polymers with high elastic energy storage capacity. J Polym Sci 54:1397–1404
Zhang W, Chen L, Zhang Y (2009) Surprising shape-memory effect of polylactide resulted from toughening by polyamide elastomer. Polymer 50(5):1311–1315
Zhang, Quan; Yan, Dong; Zhang, Kai; Hu, Genkai. “Pattern transformation of heat-shrinkable polymer by three-dimensional (3D) printing technique”. Sci Rep. Vol. 5, 2015. 8936, DOI: https://doi.org/10.1038/srep/08936
Jing X, Mi H-Y, Peng X-F, Turng L-S (2015) The morphology, properties, and shape memory behavior of polylactic acid/thermoplastic polyurethane blends. Polym Eng Sci 55(1):70–80
Sodergard A, Stolt M (2002) Properties of lactic acid based polymers and their correlation with composition. Prog Polym Sci 27(6):1123–1163
Buj-Corral I, Domínguez-Fernández A, Durán-Llucià R (2019) Influence of print orientation on surface roughness in fused deposition modeling (FDM) processes. Materials 12(23):3834
Pérez M, Medina-Sánchez G, García-Collado A, Gupta M, Carou D (2018) Surface quality enhancement of fused deposition modeling (FDM) printed samples based on the selection of critical printing parameters. Materials 11:1382
Raju M, Gupta MK, Bhanot N, Sharma VS (2019) A hybrid PSO–BFO evolutionary algorithm for optimization of fused deposition modelling process parameters. J Intell Manuf 30(7):2743–2758
Williams ML, Landel RF, Ferry JD (1955) The temperature dependence of relaxation mechanisms in amorphous polymers and other glass-forming liquids. J Am Chem Soc 77(14):3701–3707
NinjaTek Technical Specifications. NinjaFlex 3D printing filament—flexible polyurethane material for FDM printers material data sheets. URL: https://ninjatek.com/wp-content/uploads/2016/05/NinjaFlex-TDS.pdf
Blaber, Justin; Antoniou, Antonia. Ncorr DIC Instruction Manual. URL: http://ncorr.com/download/ncorrmanual_v1_1.pdf
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Carlson, M., Li, Y. Development and kinetic evaluation of a low-cost temperature-sensitive shape memory polymer for 4-dimensional printing. Int J Adv Manuf Technol 106, 4263–4279 (2020). https://doi.org/10.1007/s00170-020-04927-5
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DOI: https://doi.org/10.1007/s00170-020-04927-5