Skip to main content
Log in

Molybdenite Re–Os and muscovite 40Ar/39Ar dating of quartz vein-type W–Sn polymetallic deposits in Northern Guangdong, South China

  • Letter
  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

Northern Guangdong is an important part of Nanling tungsten–tin metallogenic belt, South China. The tungsten mineralization in this area consists of mainly quartz–wolframite vein-type mineralization, with W–Sn polymetallic deposits mostly distributed at the outer contact zone between concealed Late Jurassic granitic stocks and Cambrian–Ordovician low-metamorphosed sandstones and shales. Molybdenite Re–Os and muscovite 40Ar/39Ar isotopic dating of three typical tungsten vein-type deposits (Yaoling, Meiziwo, and Jubankeng) in northern Guangdong, show that two episodes of Late Jurassic W–Sn polymetallic mineralization occurred in this area: an early episode during the Late Jurassic (158–159 Ma) represented by the Yaoling, Hongling, and Meiziwo tungsten deposits, and a younger event during the Early Cretaceous (138 Ma) represented by the Jubankeng deposit. Analysis of available radiometric ages of several W–Sn deposits in the Nanling region indicate that these deposits formed at several intervals during the Mesozoic at 90–100, 134–140, 144–162, and 210–235 Ma, and that large-scale W–Sn mineralization in this region occurred mainly between 150 and 160 Ma.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Cai MH, Chen KX, Qu WJ, Liu GQ, Fu JM, Yin JP (2006) Geological characteristics and Re–Os dating of molybdenites in Hehuaping tin-polymetallic deposit, Southern Hunan Province. Miner Deposits 25:263–268 (in Chinese with English abstract)

    Google Scholar 

  • Chen GL (1983) Types and characteristics of tungsten ore deposits in northern Guangdong, China (in Chinese with English abstract). Acta Geologica Sinica 142–153

  • Chen ZH, Wang DH, Qu WJ, Chen YC, Wang PA, Xu JX, Zhang JJ, Xu ML (2006) Geological characteristics and mineralization age of the Taoxikeng tungsten deposit in Chongyi County, southern Jiangxi Province, China. Geol Bull China 25:496–501 (in Chinese with English abstract)

    Google Scholar 

  • Creaser R, Sannigarhi P, Chacko T, Selby D (2002) Further evaluation of the Re–Os geochronometer in organic-rich sedimentary rocks: a test of hydrothermal maturation effects in the Exshaw Formation, Western Canada sedimentary basin. Geochim Cosmochim Acta 66:3441–3452

    Article  Google Scholar 

  • Du AD, Wu SQ, Sun DZ, Wang SX, Qu WJ, Markey RJ, Stein HJ, Morgan JW, Malinovskiy D (2004) Preparation and certification of Re–Os dating reference materials: molybdenite HLP and JDC. Geostand Geoanalytical Res 28:41–52

    Article  Google Scholar 

  • Du AD, Qu WJ, Wang DH, Li HM, Feng CY, Liu H, Ren J, Zeng FG (2007) Subgrain-size decoupling of Re and 187Os within molybdenite. Miner Deposits 26:572–580 (in Chinese with English abstract)

    Google Scholar 

  • Editorial Committee of the discovery of mineral deposits of China -Volume of Guangdong Province (ECDMDCVGD) (1996) The discovery of mineral deposits of China—volume of Guangdong Province (in Chinese with English abstract). Geological Publishing House, Beijing, pp 116–136

    Google Scholar 

  • Editorial Committee of the discovery of mineral deposits of China -Volume of Guangxi Zhuang Autonomous Region (ECDMDCVGX) (1996) The discovery of mineral deposits of China—volume of Guangxi Zhuang Autonomous Region (in Chinese with English abstract). Geological Publishing House, Beijing, pp 116–136

    Google Scholar 

  • Editorial Committee of the discovery of mineral deposits of China -Volume of Jiangxi Province (ECDMDCVJX) (1996) The discovery of mineral deposits of China—volume of Jiangxi Province (in Chinese with English abstract). Geological Publishing House, Beijing, pp 80–112

    Google Scholar 

  • Feng CY, Feng YD, Xu JX, Zeng ZL, She HQ, Zhang DQ, Qu WJ, Du AD (2007a) Isotope chronological evidence for Upper Jurassic petrogenesis and mineralization of altered granite-type tungsten deposits in the Zhangtiantang area, Southern Jiangxi. Geol China 34:642–650 (in Chinese with English abstract)

    Google Scholar 

  • Feng CY, Xu JX, Zeng ZL, Zhang DQ, Qu WJ, She HQ, Li JW, Li DX, Du AD, Dong YJ (2007b) Zircon SHRIMP U-Pb and molybdenite Re–Os dating in Tianmenshan–Hongtaoling tungsten–tin Orefield, Southern Jiangxi Province, China, and its geological implication. Acta Geol Sin 81:952–963 (in Chinese with English abstract)

    Google Scholar 

  • Fraser GL, Hussey K, Compstond DM (2008) Timing of Palaeoproterozoic Au-Cu-Bi and W-mineralization in the Tennant Creek region, northern Australia: Improved constraints via intercalibration of 40Ar/39Ar and U-Pb ages. Precambrian Res 164:50–65

    Article  Google Scholar 

  • Fu JM, Li HQ, Qu WJ, Yang XJ, Wei JQ, Liu GQ, Ma LY (2007) Re-Os isotope dating of the Da’ao tungsten-tin deposit in the Jiuyi Mountains, southern Hunan Province. Geol China 34:651–656 (in Chinese with English abstract)

    Google Scholar 

  • Fu JM, Li HQ, Qu WJ, Ma LY, Yang XQ, Wei JQ, Liu GQ (2008) Determination of mineralization epoch of quartz-vein type tungsten deposits in Shixing region, Northern Guangdong and its geological significance. Geotecton Metallog 32:57–62 (in Chinese with English abstract)

    Google Scholar 

  • Fu JM, Li XN, Cheng SB, Xu DR, Ma LY, Chen XQ (2009) Metallogenic ages of tungsten–tin polymetallic deposits in Lianping area, northern Guangdong Province. Geol China 36:1331–1339 (in Chinese with English abstract)

    Google Scholar 

  • Guangdong Metallurgical and Geological Team 932 (1966) How do we use “five-story building” model to search, evaluate and prospect wolframite-quartz vein deposits. Geol Explor 5:15–19 (in Chinese)

    Google Scholar 

  • Guangdong Metallurgical and Geological Team 932 (1967) Adhere to “practice” and understanding of “five-story building” metallogenic regularity of vein tungsten deposits. Geol Explor 3:11–16 (in Chinese)

    Google Scholar 

  • Guangdong Metallurgical and Geological Team 932 (1976) Summary report on the exploration of the Shirenzhang tungsten deposit, Guangdong Province (in Chinese). Internal report pp 1–25

  • Guo CL, Lin ZY, Wang DH, Chen W, Zhang Y, Feng CY, Chen ZH, Zeng ZL, Cai RQ (2008) Petrologic characteristics of the granites and greisens and muscovite 40Ar/39Ar dating in the Taoxikeng tungsten polymetallic deposit, Southern Jiangxi province. Acta Geol Sin 82:1274–1284

    Google Scholar 

  • Hall CM, Walter RC, Westgater JA, York D (1984) Geochronology, stratigraphy and geochemistry of Cindery Tuff in Pliocene hominid-bearing sediments of the Middle Awash, Ethiopia. Nature 308:26–31

    Article  Google Scholar 

  • Huang GF, Zemg QW, Wei SL, Xu YM, Hou MS, Kang WQ (2001) Geological characteristics and ore-controlling factors of the Furong orefield, Qitianling, Hunan. Chinese Geol 28:30–34 (in Chinese with English abstract)

    Google Scholar 

  • Koppers AAP (2002) ArArCALC-software for 40Ar/39Ar age calculations. Comput Geosci 28:605–619

    Article  Google Scholar 

  • Lee JY, Marti K, Severinghaus JP, Kawamura K, Yoo HS, Lee JB, Kim JS (2006) A redetermination of the isotopic abundances of atmospheric Ar. Geochim Cosmochim Acta 70:4507–4512

    Article  Google Scholar 

  • Li HY, Mao JW, Sun YL, Zou XQ, He HL, Du AD (1996) Re–Os isotopic chronometry of molybdenite in the Shizhuyuan polymetallic tungsten deposit, Southern Hunan. Geol Rev 42:261–267 (in Chinese with English abstract)

    Google Scholar 

  • Li JW, Li XH, Pei RF, Mei YX, Wang YL, Qu WJ, Huang XB, Zhang WS (2007) Re-Os age of molybdenite from the southern ore zone of the Wushan copper deposit, Jiangxi Province, and its geological significance. Acta Geol Sin 81:801–807 (in Chinese with English abstract)

    Google Scholar 

  • Li SR, Wang DH, Liang T, Qu WJ, Ying LJ (2008) Metallogenic epochs of the Damingshan tungsten deposit in Guangxi and its prospecting potential. Acta Geol Sin 82:873–879 (in Chinese with English abstract)

    Google Scholar 

  • Li XH, Hu RZ, Rao B (1997) Geochronology and geochemistry of cretaceous mafic dikes from Northern Guangdong, SE China. Geochimica 26:14–31 (in Chinese with English abstract)

    Google Scholar 

  • Lin ZY, Wang DH, Li SR (2008) Re-Os isotopic age of molybdenite from the Wangshe copper–tungsten deposit in Guangxi province and their implications. Acta Geol Sin 82:1565–1571 (in Chinese with English abstract)

    Google Scholar 

  • Liu YJ, Ma DS (1993) Vein-type tungsten deposits of China and adjoining regions. Ore Geol Rev 8:233–246

    Article  Google Scholar 

  • Liu J, Ye HS, Xie GQ, Yang GQ, Zhang W (2008a) Re-Os dating of molybdenite from the Hukeng tungsten deposit in the Wugongshan area, Jiangxi Province, and its geological implications. Acta Geol Sin 82:1572–1579 (in Chinese with English abstract)

    Google Scholar 

  • Liu SB, Wang DH, Chen YC, Li JK, Ying LJ, Xu JX, Zeng ZL (2008b) 40Ar/39Ar ages of muscovite from different types tungsten-bearing quartz veins in the Chong-Yu-You concentrated mineral area in Gannan region and its geological significance. Acta Geol Sin 82:932–940

    Google Scholar 

  • Lu YF, Ma LY, Qu WJ, Mei YP, Chen XQ (2006) U-Pb and Re-Os isotope geochronology of Baoshan Cu–Mo polymetallic ore deposit in Hunan province. Acta Petrol Sin 22:2483–2492 (in Chinese with English abstract)

    Google Scholar 

  • Luck JM, Allègre CJ (1982) The study of molybdenites through the 187Re-187Os chronometer. Earth Planet Sci Lett 61:291–296

    Article  Google Scholar 

  • Ludwig KR (2004) Isoplot/Ex, version 3.0: a geochronological tool kit for Microsoft Excel. Berkeley Geochronology Center, Berkeley

    Google Scholar 

  • Luo HM, Xiao GM, Tang K (2006) Characteristics of tungsten poly-metal metallogenic belt and ore prospecting orientation in Chengkou–Jiulian area, Northern Guangdong Province. Resour Survey Environ 27:127–135 (in Chinese with English abstract)

    Google Scholar 

  • Ma LY, Fu JM, Wu SC, Xu DM, Yang XJ (2008) 40Ar/39Ar isotopic dating of the Longshang tin-polymetallic deposit, Xitian orefield, eastern Hunan. Geology In China 35:706–713 (in Chinese with English abstract)

    Google Scholar 

  • Ma LY, Lu YF, Qu WJ, Fu JM (2007) Re–Os isotopic chronology of molybdenites in Huangshaping lead–zinc deposit, southeast Hunan, and its geological implications. Miner Deposits 26:425–431 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Li HY, Pei RF (1995) Nd-Sr isotopic and petrogenetic studies of the Qianlishan granite stock, Hunan province. Miner Deposits 14:235–242 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Xie GQ, Li XF, Zhang CQ, Mei YX (2004) Mesozoic large scale mineralization and multiple lithospheric extension in South China. Earth Sci Front 11:45–55 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Xie GQ, Guo CL, Chen YC (2007) Large–scale tungsten-tin mineralization in the Nanling region, South China: Metallogenic ages and corresponding geodynamic processes. Acta Petrol Sin 23:2329–2338 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Xie GQ, Bierlein F, Qu WJ, Du AD, Ye HS, Pirajno F, Li HM, Guo BJ, Li YF, Yang ZQ (2009) Tectonic implications from Re–Os dating of Mesozoic molybdenum deposits in the East Qinling–Dabie orogenic belt. Geochim Cosmochim Acta 72:4607–4626

    Article  Google Scholar 

  • Nier AO (1937) The isotopic constitution of osmium. Phys Rev 52:885–892

    Article  Google Scholar 

  • Nier AO (1950) A redetermination of the relative abundances of the isotopes of carbon, nitrogen, oxygen, argon, and potassium. Phys Rev 77:789–793

    Article  Google Scholar 

  • Peng JT, Zhou MF, Hu RZ, Shen NP, Yuan SD, Bi XW, Du AD, Qu WJ (2006) Precise molybdenite Re–Os and mica Ar–Ar dating of the Mesozoic Yaogangxian tungsten deposit, central Nanling district, South China. Miner Deposita 41:661–669

    Article  Google Scholar 

  • Peng JT, Hu RZ, Bi XW, Dai TM, Li ZL, Li XM, Shuang Y, Yuan SD, Liu SR (2007) 40Ar/39Ar isotopic dating of tin mineralization in Furong deposit of Hunan province and its geological significance. Miner Deposits 26:237–248 (in Chinese with English abstract)

    Google Scholar 

  • Peng JT, Hu RZ, Yuan SD, Bi XW, Shen NP (2008) The time ranges of granitoid emplacement and related nonferrous metallic mineralization in southern Hunan. Geol Rev 54:617–625 (in Chinese with English abstract)

    Google Scholar 

  • Reynolds P, Ravenhurst C, Zentilli M, Lindsay D (1998) High-precision 40Ar-39Ar dating of two consecutive hydrothermal events in the Chuquicamata porphyry copper system, Chile. Chem Geol 148:45–60

    Article  Google Scholar 

  • RGNTD (Research Group for Nanling Tungsten Deposits, Chinese Ministry of Metallurgy) (1985) Tungsten deposits in South China (in Chinese with English abstract). Publishing House of Metallurgical Industry, Beijing, pp 1–496

    Google Scholar 

  • Selby D, Creaser RA (2001) Re-Os geochronology and systematics in molybdenite from the Endako porphyry molybdenum deposit, British Columbia, Canada. Econ Geol 96:197–204

    Article  Google Scholar 

  • Selby D, Creaser RA (2004) Macroscale NTIMS and microscale LA-MC-ICP-MS Re–Os isotopic analysis of molybdenite: testing spatial restrictions for reliable Re–Os age determinations, and implications for the decoupling of Re and Os within molybdenite. Geochim Cosmochim Acta 68:3897–3908

    Article  Google Scholar 

  • Smoliar MI, Walker RJ, Morgan JW (1996) Re–Os ages of group IIA, IIIB, IVA, IVB iron meteorites. Science 271:1099–1102

    Article  Google Scholar 

  • Steiger RH, Jäger E (1977) Subcommision on Geochronology: Convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36(359):362

    Google Scholar 

  • Stein HJ, Scherstén A, Hannah JL, Markey RJ (2003) Subgrain-scale decoupling of Re and 187Os and assessment of laser ablation ICP-MS spot dating in molybdenite. Geochim Cosmochim Acta 67:3673–3686

    Article  Google Scholar 

  • Suzuki K, Shimizu H, Masuda A (1996) Re-Os dating of molybdenites from ore deposits in Japan: implication for the closure temperature of the Re-Os system for molybdenite and the cooling history of molybdenum ore deposits. Geochim Cosmochim Acta 60:3151–3159

    Article  Google Scholar 

  • Takahashi Y, Uruga T, Suzuki K, Tanida H, Terada Y, Hattori KH (2007) An atomic level study of rhenium and radiogenic osmium in molybdenite. Geochim Cosmochim Acta 71:5180–5190

    Article  Google Scholar 

  • Wang Q, Zhao ZH, Jian P, Xiong XL, Bao ZW, Dai TM, Xu JF, Ma JL (2005) Geochronology of Cretaceous A-type granitoids or alkaline intrusive rocks in the hinterland, South China: Constraints for late-Mesozoic tectonic evolution. Acta Petrol Sinica 21:795–808 (in Chinese with English abstract)

    Google Scholar 

  • Wang Y, Chen MX, Li MG, Zeng YX (2006) Study on variety and rule of mineralization in Yaoling tunsten mine in Guangdong province, South China. Miner Res Geol 20:334–339 (in Chinese with English abstract)

    Google Scholar 

  • Wang YL, Pei RF, Li JW, Qu WJ, Li L, Wang HL, Du AD (2008a) Re–Os dating of molybdenite from the Yaogangxian Tungsten Deposit, South China, and its geological significance. Acta Geol Sin 82:820–825 (in Chinese with English abstract)

    Google Scholar 

  • Wang ZL, Yang ZM, Yang ZS, Tian SH, Liu YC, Ma YQ, Wang GR, Qu WJ (2008b) Narigongma porphyry molybdenite copper deposit, northern extension of Yulong copper belt: evidence from the age of Re–Os isotope. Acta Petrol Sin 24:503–510

    Google Scholar 

  • Wang XF, Qi HW, Hu RZ, Qu WJ, Peng JT, Bi XW (2010) Re–Os isotopic chronology of molybdenites from Hongling tungsten deposit of Guangdong province and its geological significance. Miner Deposits 29:415–427 (in Chinese with English abstract)

    Google Scholar 

  • Wu SN (2006) Geological characteristics of the Hehuaping tin polymetallic deposit in Chenzhou, Hunan province. Miner Res Geol 20:43–46 (in Chinese with English abstract)

    Google Scholar 

  • Xie GQ, Zhao HJ, Zhao CS, Li XQ, Hou KJ, Pan HJ (2009) Re-Os dating of molybdenite from Tongliishan ore district in southeastern Hubei Province, Middle–Lower Yangtze River belt and its geological significance. Miner Deposits 28:227–239 (in Chinese with English abstract)

    Google Scholar 

  • Yang F, Li XF, Feng ZH, Bai YP (2009) 40Ar/39Ar dating of muscovite from greisenized granite and geological significance in Limu tin deposit. J Guilin Univ Technol 29:21–24 (in Chinese with English abstract)

    Google Scholar 

  • Yao JM, Hua RM, Qu WJ, Qi HW, Lin JF, Du AD (2007) Re-Os isotope dating of molybdenites in the Huangshaping Pb-Zn-W-Mo polymetallic deposit, Hunan province, South China and its geological significance. Sci China Series D: Earth Sci 50:519–526

    Article  Google Scholar 

  • Yuan SD, Peng JT, Shen NP, Hu RZ, Dai TM (2007) 40Ar-39Ar isotopic dating of the Xianghualing Sn-polymetallic orefield in southern Hunan and its geological implications. Acta Geol Sin 81:278–286 (in Chinese with English abstract)

    Article  Google Scholar 

  • Zeng ZL, Zhang YZ, Zhu XP, Chen ZH, Wang CH, Qu WJ (2009) Re-Os isotopic dating of molybdenite from the Maopjng tungsten-tin deposit in Chongyi county of Southern Jiangxi province and its geological significance. Rock Miner Anal 28:209–214 (in Chinese with English abstract)

    Google Scholar 

  • Zhai W, Sun XM, Wu YS, Sun HY, Hua RM, Yang YQ, Li WQ, Li SH (2010) Zircon SHRIMP U-Pb dating of the buried granodiorite and muscovite 40Ar/39Ar dating of mineralization and geological implications of Meiziwo tungsten deposit, northern Guangdong province, China. Geol J China Univ 16:177–185 (in Chinese with English abstract)

    Article  Google Scholar 

  • Zhang WL, Hua RM, Wang RC, Chen PR, Li HM (2006) New dating of the Dajishan granite and related tungsten mineralization in Southern Jiangxi. Acta Geol Sin 80:956–962 (in Chinese with English abstract)

    Google Scholar 

  • Zhang JX, Chen ZH, Wang DH, Chen ZY, Liu SB, Wang CH (2008) Geological characteristics and metallogenic epoch of the Xingluokeng tungsten deposit, Fujian province. Geotecton Metallog 32:92–97 (in Chinese with English abstract)

    Google Scholar 

  • Zhang WL, Hua RM, Wang RC, Li HM, Qu WJ, Ji JQ (2009) New dating of the Piaotang granite and related tungsten mineralization in Southern Jiangxi. Acta Geol Sin 83:659–670 (in Chinese with English abstract)

    Google Scholar 

  • Zhou XM, Sun T, Shen WZ, Shu LS, Niu YL (2006) Petrogenesis of Mesozoic granitoids and volcanic rocks in South China: a response to tectonic evolution. Episodes 29:26–33

    Google Scholar 

  • Zou XW, Cui S, Qu WJ, Bai YS, Chen XQ (2009) Re-Os isotope dating of the Liguifu tungsten–tin polymetallic deposit in Dupangling area, Guangxi. Geol China 36:837–844 (in Chinese with English abstract)

    Google Scholar 

Download references

Acknowledgments

National Basic Research Program of China (2007CB411408) financially supported this research. We would like to thank Meiziwo, Yaoling, and Jubankeng tungsten mines and chief engineer Ba Zhu of the 290 Institute of Nuclear Industry for their support during field geological survey and sampling, Guangdong Metallurgical and Geological Team 932 for providing exploration reports of regional tungsten deposits. The useful suggestions and comments of Fernando Barra (Associate editor) and an anonymous reviewer improved the English and quality of this manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hua-Wen Qi.

Additional information

Editorial handling: F. Barra

Rights and permissions

Reprints and permissions

About this article

Cite this article

Qi, HW., Hu, RZ., Wang, XF. et al. Molybdenite Re–Os and muscovite 40Ar/39Ar dating of quartz vein-type W–Sn polymetallic deposits in Northern Guangdong, South China. Miner Deposita 47, 607–622 (2012). https://doi.org/10.1007/s00126-012-0406-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00126-012-0406-7

Keywords

Navigation