Skip to main content
Log in

Re-Os isotope dating of molybdenites in the Huangshaping Pb-Zn-W-Mo polymetallic deposit, Hunan Province, South China and its geological significance

  • Published:
Science in China Series D: Earth Sciences Aims and scope Submit manuscript

Abstract

The large-scale Huangshaping Pb-Zn-W-Mo polymetallic deposit is located in the central Nanling mineralization zone, South China. Six molybdenite samples from the Huangshaping deposit were selected for Re-Os isotope measurement in order to define the mineralization age of the deposit. It yields a Re-Os isochron age of 154.8±1.9 Ma (2σ), which is in accordance with the Re-Os model ages of 150.9–156.9 Ma. This age is about 7 Ma younger than their host granite porphyry, which was dated as 161.6±1.1 Ma by zircon U-Pb method using LA-ICPMS. All these ages demonstrate that the Huangshaping granite and related Pb-Zn-W-Mo deposit occurred in the middle Yanshanian period, when many other granitoid and related ore deposits emplaced and formed, e.g. the Qitianling granite and Furong tin deposit, the Qianlishan granite and giant Shizhuyuan W-Sn-Mo-Bi deposit and Jinchuantang Sn-Bi deposit in the nearby area. They constitute the main part of the magmatic-metallogenic belt of southern Hunan, and represent the large-scale metallogeny in middle Yanshanian in the area. The lower rhenium content in molybdenite of Huangshaping deposit suggests that the ore-forming material was mainly of crust origin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tong Q M, Li R Q, Zhang J X. Deposit metallogenetic series across the Chenzhou-Linwu deep-seated fault. Geol Miner Resour South China (in Chinese), 2000, (3): 34–41

  2. Hua R M, Chen P R, Zhang W L, et al. Metallogenic systems related to Mesozoic and Cenozoic granitoids in south China. Sci China Ser D-Earth Sci, 2003, 46(8): 816–829

    Article  Google Scholar 

  3. Yang S Y, Liu H Q, Zhang X L, et al. A study of two typies of porphyry in Baoping district, south Hunan and their mineralization. In: Institute of Mineral Deposits, Chinese Academy of Geological Sciences, eds. Nanling Geology and Deposit Thesis (in Chinese). Beijing: Geological Publishing House, 1986. 157–167

    Google Scholar 

  4. Zhong Z C. Magma rocks and their ore-controlling characteristics in the Huangshaping mining area. Miner Resour Geol (in Chinese), 1996, 10(6): 400–405

    Google Scholar 

  5. Mao J W, Li H Y, Pei R F. Sr and Nd isotope and its origin of Qianlishan rock body in Hunan province. Miner Depos (in Chinese), 1995, 14(3): 235–242

    Google Scholar 

  6. Shen W Z, Wang D Z, Xie Y L, et al. Geochemical characteristics and material sources of the Qianlishan composite granite body, Hunan Province. Acta Petrol Mineral (in Chinese), 1995, 14(3): 193–202

    Google Scholar 

  7. Liu Y M, Dai T M, Lu H Z, et al. 40Ar–39Ar and Sm-Nd isotopic ages of the lithogenesis and mineralization of the Qianlishan granite. Sci China Ser D-Earth Sci (in Chinese), 1997, 27(5): 425–430

    Google Scholar 

  8. Li H Y, Mao J W, Sun Y L, et al. Re-Os isotopic chronology of molybdenites in the Shizhuyuan polymetallic tungsten deposit, southern Hunan. Geol Rev (in Chinese), 1996, 12(3): 261–267

    Google Scholar 

  9. Huang G F. Discussion on emplacement time of Qitianling composite rock masses. Geol Prospect (in Chinese), 1992, 28(11): 7–11

    Google Scholar 

  10. Liu Y M, Xu J F, Dai T M, et al. 40Ar/39Ar isotopic age of Qitianling granite and its geological significance. Sci China Ser D-Earth Sci (in Chinese), 2002, 32(suppl.): 41–48

    Google Scholar 

  11. Huang G F, Zeng Q W, Wei S L, et al. Geological characteristics and ore-controlling factors of the Furong orefield, Qitianling, Hunan. Geol China (in Chinese), 2001, 28(10): 30–34

    Google Scholar 

  12. Wei S L, Zeng Q W, Xu Y M, et al. Characteristics and ore prospects of tin deposits in the Qitianling area, Hunan. Geol China (in Chinese), 2002, 29(1): 67–75

    Google Scholar 

  13. Wang X W, Wang X D, Liu J Q, et al. Relationship of Qitianling granite to Sn mineralization in Hunan province. Geol Sci Technol Inf (in Chinese), 2004, 23(2): 1–12

    Google Scholar 

  14. Deng X G, Li X H, Liu Y M, et al. Geochemical characteristics of Qitianling granites and their implications for mineralization. Acta Petrol Mineral (in Chinese), 2005, 24(2): 93–102

    Google Scholar 

  15. Zheng J J, Jia B H. Geological characteristics and related tin-polymetallic mineralization of the Qitianling granite complex in southern Hunan Province. Geol Miner Resour South China (in Chinese), 2001, (4): 50–57

  16. Yao J M, Hua R M, Lin J F. Zircon LA-ICPMS U-Pb dating and geochemical characteristics of Huangshaping granite in southeast Hunan Province, China. Acta Petrol Sin (in Chinese), 2005, 21(3): 688–696

    Google Scholar 

  17. Li X H, Liu D Y, Sun M, et al. Precise Sm-Nd and U-Pb isotopic dating of the supergiant Shizhuyuan polymetallic deposit and its host granite, SE China. Geol Mag, 2004, 141(2): 225–231

    Article  Google Scholar 

  18. Zhu J C, Huang G F, Zhang P H, et al. On the emplacement age and material sources for the granites of Cailing superunit, Qitianling pluton, south Hunan Province. Geol Rev (in Chinese), 2003, 49(3): 245–252

    Google Scholar 

  19. Fu J M, Ma C Q, Xie C F, et al. Zircon SHRIMP dating of the Cailing granite on the eastern margin of the Qitianling granite, Hunan, south China, and its significance. Geol China (in Chinese), 2004, 31(1): 96–100

    Google Scholar 

  20. Zhu J C, Zhang H, Xie C F, et al. Zircon SHRIMP U-Pb geochronology, petrology and geochemistry of the Zhujianshui granite, Qitianling pluton, southern Hunan Province. Geol J China Univ (in Chinese), 2005, 11(3): 335–342

    Google Scholar 

  21. Li J D, Bai D Y, Wu G Y, et al. Zircon SHRIMP dating of the Qitianling granite, Chenzhou, southern Hunan, and its geological significance. Geol Bull China (in Chinese), 2005, 24(5): 411–414

    Google Scholar 

  22. Mao J W, Li X F, Lehmann B, et al. Ar-Ar dating of tin ores and related granite in Furong tin orefield, Hunan province, and its geodynamic significance. Miner Depos (in Chinese), 2004, 22(2): 164–175

    Google Scholar 

  23. Tong Q M, Wu R H, Pen Q L, et al. Metallogeny of W, Sn, Pb-Zn, Au and Ag Deposits in the Chenxian-Guiyang Region, South Hunan, China (in Chinese). Beijing: Geological Publishing House, 1995. 1–98

    Google Scholar 

  24. Tong Q M, Jiang S Z, Li R Q, et al. A study of geological characteristics and ore forming process of the Huangshaping lead-zinc ore deposit, Hunan. Hunan Geol (in Chinese), 1986, (suppl): 1–42

  25. Wang J C, Yao Y, Wang K Y, et al. The mineralization characteristics study of the associated silver in the Huangshaping Pb-Zn ore field. Geol Prospect (in Chinese), 1993, 29(1): 20–27

    Google Scholar 

  26. Zhu E J, Wang J G, Qiu Y M. The distribution regularity and occurrence of the associated silver in the Huangshaping Pb-Zn ore field, Hunan Province. Geol Explor Non-ferrous Metals (in Chinese), 1995, 4(2): 89–95

    Google Scholar 

  27. Zhong Z C, Deng S F, Wang L H. Association of silver mineralization in the Huangshaping lead zinc deposit. Miner Resour Geol (in Chinese), 1997, 11(1): 46–52

    Google Scholar 

  28. Deng S F. Zoning regularity of mineral assemblages in the Huangshaping lead-zinc deposit. Miner Resour Geol (in Chinese), 1997, 11(5): 314–318

    Google Scholar 

  29. Song X Y, Zhang J H, Lin J H, et al. Mechanism of Fe2+ occupancy of the marmatite in the inner zone of the Huangshaping Pb-Zn deposit, Hunan. Geol Prospect (in Chinese), 1999, 35(2): 21–24

    Google Scholar 

  30. Li S J. A simple explanation to ore-controlling structure characteristics and ore-forming process analysis of Huangshaping Pb-Zn deposit in Hunan Province. Geotecton Metall (in Chinese), 1997, 21(2): 339–346

    Google Scholar 

  31. Shen S. Ore mineral composition and deposit factors-controlled of copper deposit in Huangshaping ore area. Hunan Geol (in Chinese), 1999, 18(2/3): 75–78

    Google Scholar 

  32. Gu L. On the Genesis of the lead-zinc polymetallic deposit in Huangshaping. Hunan Geol (in Chinese), 1997, 16(4): 232–235, 238

    Google Scholar 

  33. Zeng Z X. Geological characteristics and genesis of the copper deposit of the Huangshaping ore field. Huan Nonferrous Metals (in Chinese), 2001, 17(3): 8–9

    Google Scholar 

  34. Mao J W, Zhang Z C, Zhang Z H, et al. Re-Os isotopic dating of molybdenites in the Xiaoliugou W (Mo) deposit in the northern Qilian mountains and its geological significance. Geochim Cosmochim Acta, 1999, 63(11/12): 1815–1818

    Google Scholar 

  35. Raith J, Stein H. Re-Os dating and sulfur isotope composition of molybdenite from tungsten deposits in western Namaqualand, South Africa: implications for ore genesis and the timing of metamorphism. Miner Deposita, 2000, 35: 741–753

    Article  Google Scholar 

  36. Zhang L C, Xiao W J, Qin K Z, et al. Re-Os isotopic dating of molybdenite and pyrite in the Baishan Mo-Re deposit, eastern Tianshan, NW China, and its geological significance. Miner Deposita, 2005, 39: 960–969

    Article  Google Scholar 

  37. Du A D, He H L, Yin N W, et al. A study on the rhenium-osmium geochronometry of molybdenites. Acta Geol Sin (in Chinese), 1994, 68(4): 339–347

    Google Scholar 

  38. Shirey S, Walker R. Carius tube digestion for low-blank rhenium-osmium analysis. Anal Chem, 1995, 67: 2136–2141

    Article  Google Scholar 

  39. Du A D, Wu S Q, Sun D Z, et al. Preparation and Certification of Re-Os Dating Reference Materials: Molybdenite HLP and JDC. Geostandard Newslett, 2004, 28(04/05): 41–52

    Google Scholar 

  40. Qu W J, Du A D. Highly precise Re-Os dating of molybdenite by ICP-MS with carius tube sample digestion. Rock Miner Anal (in Chinese), 2003, 22(4): 254–257

    Google Scholar 

  41. Stein H, Markey R, Morgan J, et al. The remarkable Re-Os chronometer in molybdenite: how and why it works. Terra Nova, 2001, 13(6): 479–486

    Article  Google Scholar 

  42. Ludwig K. Isoplot/Ex 3.0. A geochronogical toolkit for Microsoft Excel. Berkeley Geochronology Center, Berkeley, CA, USA, Special Publication No. 4, 2003

  43. Hua R M, Chen P R, Zhang W L, et al. Three major metallogenic events in Mesozoic in south China. Miner Deposita (in Chinese), 2005, 24(2): 99–107

    Google Scholar 

  44. Hua R M, Chen P R, Zhang W L, et al. Metallogeneses related to Mesozoic granitoids in the Nanling Range, and their geodynamic settings. Acta Geol Sin Engl Ed, 2005b, 79(6): 801–811

    Google Scholar 

  45. Mao J W, Xie G Q, Li X F, et al. Mesozoic large scale mineralization and multiple lithospheric extension in south china. Earth Sci Front (in Chinese), 2004, 11(1): 45–55

    Google Scholar 

  46. Xiao H Q, Zhao K D, Jiang S Y, et al. Lead isotope geochemistry and ore-forming age of Jinchuantang Sn-Bi deposit in Dongpo ore field, Hunan Province. Miner Deposita (in Chinese), 2003, 22(3): 264–270

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hua RenMin.

Additional information

Supported by the State Key Fundamental Research Project (Grant No. G1999CB403209) and the National Natural Science Foundation of China (Grant No. 40572057)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yao, J., Hua, R., Qu, W. et al. Re-Os isotope dating of molybdenites in the Huangshaping Pb-Zn-W-Mo polymetallic deposit, Hunan Province, South China and its geological significance. SCI CHINA SER D 50, 519–526 (2007). https://doi.org/10.1007/s11430-007-2052-y

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11430-007-2052-y

Keywords

Navigation