Abstract
The Upper Jurassic Mantos Blancos copper deposit (500 Mt at 1.0% Cu), located in the Coastal Range of northern Chile, displays two superimposed hydrothermal events. An older phyllic alteration probably related to felsic magmatic–hydrothermal brecciation at ∼155 Ma, and younger (141–142 Ma) potassic, propylitic, and sodic alterations, coeval with dioritic and granodioritic stocks and sills, and dioritic dikes. Main ore formation is genetically related to the second hydrothermal event, and consists of hydrothermal breccias, disseminations and stockwork-style mineralization, associated with sodic alteration. Hypogene sulfide assemblages show distinctive vertical and lateral zoning, centered on magmatic and hydrothermal breccia bodies, which constitute the feeders to mineralization. A barren pyrite root zone is overlain by pyrite-chalcopyrite, and followed upwards and laterally by chalcopyrite-digenite or chalcopyrite-bornite. The assemblage digenite–supergene chalcocite characterizes the central portions of high-grade mineralization in the breccia bodies. Fluid inclusions show evidence of boiling during the potassic and sodic alteration events, which occurred at temperatures around 450–460°C and 350–410°C, and salinities between 3–53 and 13–45 wt% NaCl eq., respectively. The hydrothermal events occurred during episodic decompression due to fluid overpressuring, hydrofracturing, and sharp changes from lithostatic to hydrostatic conditions. Sulfur isotope results of hypogene sulfide minerals fall in a narrow range around 0 per mil, suggesting a dominance of magmatic sulfur. Carbon and oxygen isotopic data of calcites from propylitic alteration suggest a mantle-derived carbon and oxygen isotope fractionation due to low-temperature alteration.
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References
Bodnar RJ, Vityk MO (1994) Interpretation of microthermometric data for H2O–NaCl fluid inclusions. In: De Vivo B, Frezzotty ML (eds) Fluid inclusion in minerals: methods and applications. VPI, Blackburg, Virginia, pp 117–130
Camus F (2003) Geología de los sistemas porfíricos en los Andes de Chile. SERNAGEOMIN, Chile, p 267
Cartigny P, Harris JW, Javoy M (1998) Eclogitic diamond formation at Jwaneng: no room for a recycled component. Science 280:1421–1424
Chávez W (1985) Geological setting and the nature and distribution of disseminated copper mineralization of the Mantos Blancos district, Antofagasta Province, Chile. Ph.D Thesis, University at California, Berkeley, USA, p 142
Deines P (1989) Stable isotope variations in carbonatites. In: Bell K (ed) Carbonatites—genesis and evolution. Unwin Hyman, London, pp 301–359
Dallmeyer RD, Brown M, Grocott J, Taylor GK, Treolar PJ (1996) Mesozoic magmatic and tectonic events within the Andean plate boundary zone, 26°–27°30′ S, North Chile: Constraints from 40Ar/39Ar mineral ages. J Geol 104:19–40
Espinoza S, Véliz H, Esquivel J, Arias J, Moraga A (1996) The cupriferous province of the Coastal Range, Northern Chile. In: Camus F, Sillitoe RH, Petersen R (eds) Andean copper deposits: new discoveries, mineralization, styles and metallogeny. Econ Geol, Spec Publ 5:19–32
Fournier RO (1991) The transition from hydrostatic to greater than hydrostatic fluid pressure in present active continental hydrothermal systems in crystalline rock. Geophys Res Lett 18:955–958
Fournier RO (1999) Hydrothermal processes related to movement of fluid from plastic into brittle rock in the magmatic–epithermal environment. Econ Geol 94:1193–1212
Fournier RO, Thompson JM (1993) Composition of steam in the system NaCl–KCl–H2O–quartz at 600°C. Geochim Cosmochim Acta 57:4365–4375
Gelcich S, Davis DW, Spooner ET (2004) Onset of Early Jurassic magmatism in northern Chile: precise U–Pb zircon ages for the La Negra Formation and the Flamenco Pluton in the Coastal Cordillera of Chañaral. Proc. IAVCEI General Assembly, Pucón, Chile (Electronic version)
Hezarkhani A, Williams-Jones AE, Gammons CH (1999) Factors controlling copper solubility and chalcopyrite deposition in the Sungun porphyry copper deposit, Iran. Miner Depos 34:770–783
Keller J, Hoefs J (1995) Stable isotope characteristics of recent carbonatites. In: Bell K, Keller J (eds) Carbonatite volcanism. Proc Volc 4:113–123
Kramer W, Siebel W, Romer R L, Haase G, Zimmer M, Ehrlichmann R (2005) Geochemical and isotopic characteristics and evolution of the Jurassic volcanic arc between Arica (18°30′ S) and Tocopilla (22° S), North Chilean coastal range. Chemie der Erde. Geochemistry 65:47–78
Maksaev V, Zentilli M (2002) Chilean stratabound Cu–(Ag) deposits: an overview. In: Porter TM (ed) Hydrothermal iron oxide copper–gold and related deposits: a global perspective 2. PCG, pp 185–205
Munizaga F, Ramírez R, Drake R, Tassinari C, Zentilli M (1991) Nuevos antecedentes geocronológicos del yacimiento Manos Blancos, Región de Antofagasta, Chile. In: Proceedings of the 6th congress on geology, vol. 1. Chile, pp 221–224
Nash JT (1976) Fluid-inclusion petrology. Data from porphyry copper deposits and applications to exploration. USGS Prof Paper 907D, p 16
Oliveros V (2005) Les formations magmatiques jurassiques et mineralisation du nord Chili, origine, mise en place, alteration, metamorphisme: etude geochronologique et geochemie. Ph.D Thesis. Universite de Nice-Sophia Antipolis, France, p 285
Palacios C (1984) Considerations about the plate tectonic models, volcanism, and continental crust in the southern part of the Central Andes. Tectonophysics 108:205–214
Palacios C (1990) Geology of the Buena Esperanza copper–silver deposit, northern Chile. In: Fontbote L, Amstutz GC, Cardozo M, Cedillo E, Frutos J (eds) Stratabound ore deposits in the Andes. Springer, Berlin Heidelberg New York, pp 313–318
Parada M, Palacios C, Lahsen A (1997) Jurassic extensional tectono-magmatism and associated mineralization of the El Faldeo polymetallic district, Chilean Patagonia: geochemical and isotopic evidence of crustal contribution. Miner Depos 32:547–554
Pichowiak S, Buchelt M, Damm KW (1990) Magmatic activity and tectonic setting of early stages of Andean cycle in northern Chile. Geol Soc Am(Specl Paper) 241:127–144
Rogers G, Hawkesworth CJ (1989) A geochemical traverse across the North Chilean Andes: evidence for crust generation from the mantle wedge. Earth Planet Sci Lett 91:271–285
Sasaki A, Ulriksen C, Sato K, Ishihara S (1984) Sulphur isotope reconnaissance of porphyry copper and Manto type deposits in Chile and the Philippines. Bull Geol Surv Jpn 35:615–622
Scheuber E, Gonzalez G (1999) Tectonics of the Jurassic–Early Cretaceous magmatic arc of the North Chilean Coastal Cordillera (22–26° S): a story of crustal deformation along a convergent plate boundary. Tectonics 18:895–910
Simmons SF, Browne PR (2000) Hydrothermal minerals and precious metals in the Broadlands–Ohaaki geothermal system: implications for understanding low-sulfidation epithermal environments. Econ Geol 95:971–1000
Tassinari C, Munizaga F, Ramírez R (1993) Edad y geoquímica isotópica Rb–Sr del yacimiento de cobre Mantos Blancos: relación temporal con el magmatismo jurásico. Rev Geol Chile 20:193–205
Taylor HP, Frechen J, Degens ET (1967) Oxygen carbon isotope studies of carbonatites from the Laachersee district West Germany and Alno district, Sweden. Geochim Cosmochim Acta 31:407–430
Vivallo W, Henriquez F (1998) Genesis comun de los yacimientos estratoligados y vetiformes de cobre del Jurásico Medio a Superior en la Cordillera de la Costa, Region de Antofagasta, Chile. Rev Geol Chile 25:199–228
Wolf FB, Fontboté L, Amstutz GC (1990) The Susana copper (–silver) deposit in northern Chile, hydrothermal mineralization associated with a Jurassic volcanic arc. In: Fontbote L, Amstutz GC, Cardozo M, Cedillo E, Frutos J (eds) Stratabound ore deposits in the Andes. Springer, Berlin Heidelberg New York, pp 319–338
Acknowledgements
This study was funded by a FONDEF (CONICYT, Chile), grant DO1-1012, awarded to the authors and the Mantos Blancos division of Anglo American Chile. Permission for publication was granted by the University of Chile, the Chilean Government, and AngloAmerican Chile. We thank the Mantos Blancos mine geology staff, especially to Jorge Pizarro, with whom we had the pleasure of working. Special acknowledgement to Jens Wittenbrink for his constructive comments to the manuscript. Finally, this paper was improved through the valuable reviews of Shoji Kojima, Robert King and Larry Meinert.
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Ramírez, L.E., Palacios, C., Townley, B. et al. The Mantos Blancos copper deposit: an upper Jurassic breccia-style hydrothermal system in the Coastal Range of Northern Chile. Miner Deposita 41, 246–258 (2006). https://doi.org/10.1007/s00126-006-0055-9
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DOI: https://doi.org/10.1007/s00126-006-0055-9