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Attempt to protect wood using copper(II) complex with 1,7-diphenyl-1,6-heptadiene-3,5-dione, a non-phenolic curcuminoid

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Abstract

For the first time, curcuminoids known for their antioxidant and sunscreen properties were used for photoprotection of lignocellulosics. It was shown that complex between copper(II) and non-substituted curcumin 2, displaying remarkable photostability in ethyl acetate/ethanol solution, is able to photostabilize in some extend α-carbonyl β-O-4 lignin model and more efficiently spruce wood.

Zusammenfassung

Zum ersten Mal wurde Curcumin, das für seine antioxidante und sonnenschützende Wirkung bekannt ist, für den Lichtschutz von Lignin-Cellulosen eingesetzt. Es wurde gezeigt, dass der Kupfer(II)-Komplex mit einem unsubstituierten Curcumin 2, das in einer Lösung aus Ethylacetat/Ethanol über eine bemerkenswerte Photostabilität verfügt, die Fähigkeit besitzt, α-Carbonyl β-O-4 Lignin-Moleküle und noch effizienter Fichtenholz gegen Lichtabbau zu stabilisieren.

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Scheme 1. Schema 1.
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Authors and Affiliations

  1. Laboratoire de Chimie des Substances Végétales, UPRES EA-494, Université Bordeaux 1, 351 cours de la Libération, 33405, Talence, France

    A. Sundaryono, A. Nourmamode, C. Gardrat, S. Grelier, O. Despeyroux & A. Castellan

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  1. A. Sundaryono
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  2. A. Nourmamode
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  3. C. Gardrat
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  4. S. Grelier
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  5. O. Despeyroux
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  6. A. Castellan
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Correspondence to A. Castellan.

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Sundaryono, A., Nourmamode, A., Gardrat, C. et al. Attempt to protect wood using copper(II) complex with 1,7-diphenyl-1,6-heptadiene-3,5-dione, a non-phenolic curcuminoid. Holz Roh Werkst 61, 377–381 (2003). https://doi.org/10.1007/s00107-003-0401-x

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