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Kinetics and Catalysis

, Volume 46, Issue 1, pp 52–55 | Cite as

Mechanism of One-Electron Reactions of Copper(I) Chloride Complexes with Chlorohydrocarbons

  • D. N. Kharitonov
  • E. N. Golubeva
Article
  • 37 Downloads

Abstract

The reactivity of chlorohydrocarbons with different electron affinities (Ae) and C-Cl bond dissociation energies (EC-Cl) in the oxidation of copper(I) chloride complexes was studied. The rate of oxidation depends only on Ae. Chain initiation, involving Cu(I), occurs by an electron-transfer mechanism.

Keywords

Oxidation Copper Chloride Physical Chemistry Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • D. N. Kharitonov
    • 1
  • E. N. Golubeva
    • 1
  1. 1.Department of ChemistryMoscow State UniversityMoscowRussia

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