Kinetics and Catalysis

, Volume 46, Issue 1, pp 52–55 | Cite as

Mechanism of One-Electron Reactions of Copper(I) Chloride Complexes with Chlorohydrocarbons

  • D. N. Kharitonov
  • E. N. Golubeva


The reactivity of chlorohydrocarbons with different electron affinities (Ae) and C-Cl bond dissociation energies (EC-Cl) in the oxidation of copper(I) chloride complexes was studied. The rate of oxidation depends only on Ae. Chain initiation, involving Cu(I), occurs by an electron-transfer mechanism.


Oxidation Copper Chloride Physical Chemistry Catalysis 
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© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • D. N. Kharitonov
    • 1
  • E. N. Golubeva
    • 1
  1. 1.Department of ChemistryMoscow State UniversityMoscowRussia

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