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Synthesis and structural properties of AgCl1 - xBrx (x = 0.5-0.8) solid solutions

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Abstract

The properties of AgCl1 - x Brx ( x = 0.5-0.8) solid solutions prepared by the Bridgman-Stockbarger method are studied using a variety of techniques (x-ray diffraction, microstructural examination, chemical analysis, and x-ray microanalysis). The lattice parameter of the solid solutions is found to exhibit a negative deviation from additivity. The effects of composition and preparation conditions on the structural properties of the solid solutions are discussed. The structural characteristics of abrasively polished surfaces of the samples are shown to be influenced by the preparation conditions.

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Authors and Affiliations

  1. A.R.T. Photonics GmbH, Schwarzchildstrasse 6, D-12489, Berlin, Germany

    V. G. Artjushenko

  2. All-Russia Research Institute of Chemical Technology, Kashirskoe sh. 33, 115230, Moscow, Russia

    P. B. Baskov & V. V. Sakharov

  3. State Research Institute for the Rare-Metals Industry, Bol’shoi Tolmachevskii per. 5, 109017, Moscow, Russia

    V. F. Golovanov, I. S. Lisitskii & G. V. Polyakova

  4. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, 119571, Moscow, Russia

    G. M. Kuz’micheva & T. V. Sakharova

  5. Prokhorov General Physics Institute, Russian Academy of Sciences, ul. Vavilova 38, 119991, Moscow, Russia

    M. D. Musina

Authors
  1. V. G. Artjushenko
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  2. P. B. Baskov
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  3. V. F. Golovanov
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  4. G. M. Kuz’micheva
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  5. I. S. Lisitskii
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  6. M. D. Musina
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  7. G. V. Polyakova
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  8. V. V. Sakharov
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  9. T. V. Sakharova
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Additional information

Translated from Neorganicheskie Materialy, Vol. 41, No. 1, 2005, pp. 78–87. Original Russian Text Copyright © 2005 by Artjushenko, Baskov, Golovanov, Kuz’micheva, Lisitskii, Musina, Polyakova, Sakharov, Sakharova.

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Artjushenko, V.G., Baskov, P.B., Golovanov, V.F. et al. Synthesis and structural properties of AgCl1 - xBrx (x = 0.5-0.8) solid solutions. Inorg Mater 41, 73–81 (2005). https://doi.org/10.1007/PL00021887

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