Skip to main content
SpringerLink
Log in

Stereochemie der Umlagerungs- und Reduktionsprodukte von Epoxyfencholenderivaten

Stereochemistry of Products Obtained by Rearrangement and Reduction of Fencholenic Epoxides

  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 Starting with fencholenic epoxides 8a,b and 11, investigations of the rearrangement to the corresponding ketones were carried out. Reduction of the isomeric ketones 12a,b and 13a,b afforded each diastereomeric alcohols 14, 16/17 and 15, 18/19. Diastereomeric alcohols could be obtained by reduction of 8a,b and 11 and by hydroboration/oxidation of the fencholenic compounds 7 and 22. The stereochemistry of the new compounds is described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Author information

Authors and Affiliations

  1. Institut für Organische Chemie der Universität Leipzig, D-04103 Leipzig, Germany, DE

    Ines Sprung, Katrin Anhalt, Uwe Wahren & Klaus Schulze

Authors
  1. Ines Sprung
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Katrin Anhalt
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Uwe Wahren
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Klaus Schulze
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Received August 3, 1998. Accepted September 19, 1998

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sprung, I., Anhalt, K., Wahren, U. et al. Stereochemie der Umlagerungs- und Reduktionsprodukte von Epoxyfencholenderivaten. Monatshefte fuer Chemie 130, 341–354 (1999). https://doi.org/10.1007/PL00010216

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/PL00010216

Search

Navigation