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Flotation of a low-grade bauxite ore using an organosilicon cationic collector

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Abstract

The flotation behaviors of diaspore and three kinds of silicate minerals — kaolinite, illite and pyrophyllite — using an organosilicon cationic surfactant as collector were investigated as functions of reagent concentration and pulp pH. The results show that the organosilicon cationic collector QAS122 is a suitable collector for the flotation of aluminosilicate minerals but has weak collecting ability with regard to diaspore, enabling the flotation separation of diaspore from silicate minerals using QAS122 as collector. The flotation of a bauxite ore was then studied in detail. Finally, a reverse flotation separation process was used to process a low-grade bauxite ore. It was concluded that use of the organosilicon cationic collector is effective. A concentrate with aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, of 9.67 was obtained from natural bauxite ore with A/S of 6.07 at pH of around 11. The Al2O3 recovery rate was 81.72 percent.

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References

  • Cao, X., Hu, Y., and Xu, J., 2004, “Synthesis of γ-alkoxy-propylamines and their collecting properties on aluminosilicate mineral,” J. Cent. South. Univ. T, Vol. 11, No. 3, pp. 280–286.

    Article  Google Scholar 

  • Du, P., Cao, X., Hu, Y., Jiang, Y., and Li, H., 2003, “Study of structure and property of amine collectors,” Light Metal, Vol. 1, pp. 27–31 (in Chinese).

    Google Scholar 

  • Guan, F., Zhong, H., and Liu, G., 2009, “Flotation of aluminosilicate minerals using alkylguanidine collectors,” Trans. Nonferrous Met. Soc. China, Vol. 19, No. 1, pp. 228–234.

    Article  Google Scholar 

  • Hu, Y., 2003, “Progress in flotation de-silica,” Trans. Nonferrous Met. Soc. China, Vol. 13, No. 3, pp. 656–662.

    Google Scholar 

  • Hu, Y., Jiang, H., and Wang, D., 2003, “Electrokinetic behavior and flotation of kaolinite in CTAB solution,” Miner. Eng., Vol. 16, No. 11, pp. 1221–1223.

    Article  Google Scholar 

  • Liu, C., Hu, Y., and Cao, X., 2009, “Substituent effects in kaolinite flotation using dodecyl tertiary amines,” Miner. Eng., Vol. 22, No. 9–10, pp. 849–852.

    Article  Google Scholar 

  • Liu, G., Zhong, H., Hu, Y., Zhao, S., and Xia, J., 2007, “The role of cationic polyacrylamide in the reverse flotation of diasporic bauxite,” Miner. Eng., Vol. 20, No. 13, pp. 1191–1199.

    Article  Google Scholar 

  • Liu, G., Zhong, H., Lu, Y., and Feng, Q., 2003, “Reverse flotation separation on diaspore and kaolinite in the presence of cationic polyacrylamide polymers,” Trans. Nonferrous Met. Soc. China, Vol. 13, No. 5, pp. 1231–1234.

    Google Scholar 

  • Luo, Z., Hu, Y., Wang, Y., and Qiu, G., 2001, “Mechanism of dispersion and aggregation in reverse flotation for bauxite,” The Chinese Journal of Nonferrous Metals, Vol. 11, No. 4, pp. 680–683 (in Chinese).

    Google Scholar 

  • Ma, C., Tian, X., Liu, R., and Yang, X., 1996, “Selection of Bayer digestion technology and equipment for Chinese bauxite,” Light Metals: Proceedings of TMS Annual Meeting, TMS, pp. 187–191.

  • Papanastassiou, D., Csoke, B., and Solymar, K., 2002, “Improved preparation of the Greek diasporic bauxite for Bayer-process,” Light Metals: Proceedings of TMS Annual Meeting, TMS, pp. 67–74.

  • Wang, Y., Hu, Y., and Gu, G., 2004, “Reverse flotation for removal of silicates from diasporic-bauxite,” Miner. Eng., Vol. 17, No. 1, pp. 63–68.

    Article  Google Scholar 

  • Xia, L., Zhong, H., and Liu, G., 2009, “Flotation separation of the aluminosilicates from diaspore by a Gemini cationic collector,” Int. J. Miner. Process., Vol. 92, No. 1–2, pp. 74–83.

    Article  Google Scholar 

  • Xia, L., Zhong, H., and Liu, G., 2010, “Flotation techniques for separation of diaspore from bauxite using Gemini collector and starch depressant,” Trans. Nonferrous Met. Soc. China, Vol. 20, No. 3, pp. 495–501.

    Article  Google Scholar 

  • Xu, Z., Plitt, V., and Liu, Q., 2004, “Recent advances in reverse flotation of diasporic ores—A Chinese experience,” Miner. Eng., Vol. 17, No. 9, pp. 1007–1015.

    Article  Google Scholar 

  • Zhao, S., Wang, D., Hu, Y., and Xu, J., 2003a, “Flotation of aluminosilicates using N-(2-aminoethyl)-1-naphthaleneacetamide,” Miner. Eng., Vol. 16, No. 10, pp. 1031–1033.

    Article  Google Scholar 

  • Zhao, S., Wang, D., Hu, Y., and Xu, J., 2003b, “The flotation behaviour of N-(3-aminopropyl)-dodecanamide on three aluminosilicates,” Miner. Eng., Vol. 16, No. 12, pp. 1391–1395.

    Article  Google Scholar 

  • Zhao, S., Wang, D., Hu, Y., and Xu, J., 2003c, “Flotation of aluminosilicates using N-(3-aminopropyl)-dodecanamide,” Chinese Journal of Nonferrous Metals, Vol. 13, No. 5, pp. 1273–1277 (in Chinese).

    Google Scholar 

  • Zhao, S., Zhong, H., and Liu, G., 2007, “Effect of quaternary ammonium salts on flotation behavior of aluminosilicate minerals,” J. Cent. South. Univ. T, Vol. 14, No. 4, pp. 500–503.

    Article  Google Scholar 

  • Zong, H., Liu, G., Xia, J., Lu, Y., Hu, Y., Zhao, S., and Yu, X., 2008, “Flotation separation of diaspore from kaolinite, pyrophyllite and illite using three cationic collectors,” Miner. Eng., Vol. 21, No. 12–14, pp. 1055–1061.

    Article  Google Scholar 

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Correspondence to B. Feng.

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Paper number MMP-14-087.

Discussion of this peer-reviewed and approved paper is invited and must be submitted to SME Publications Dept. prior to May 31, 2016.

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Yu, X.Y., Wei, X.A., Zeng, A. et al. Flotation of a low-grade bauxite ore using an organosilicon cationic collector. Mining, Metallurgy & Exploration 32, 209–214 (2015). https://doi.org/10.1007/BF03402477

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  • DOI: https://doi.org/10.1007/BF03402477

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